Patent · US9771209B2 · B2 · US
Slip agent for protecting glass
- (11) Publication number
- US9771209B2
- (21) Application number
- 14/450,764
- (22) Filing date
- 2014-08-04
- (30) Priority date
- 2009-05-22
- (43) Publication date
- 2017-09-26
- (45) Date of grant
- 2017-09-26
- (51) IPC
- B32B 17/06; B65D 85/48; B65G 49/06; C03C 17/00; C03C 17/28; C03C 19/00
- (52) CPC
- B65D Containers for storage or transport of articles or materials, e.g. bags, barrels, bottles, boxes, cans, cartons, crates, drums, jars, tanks, hoppers, forwarding containers; accessories, closures, or fittings therefor; packaging elements; packages: 85/48
- B32B Layered products, i.e. products built-up of strata of flat or non-flat, e.g. cellular or honeycomb, form: 17/065, 2255/12
- B65G Transport or storage devices, e.g. conveyors for loading or tipping, shop conveyor systems or pneumatic tube conveyors: 49/069
- C03C Chemical composition of glasses, glazes or vitreous enamels; surface treatment of glass; surface treatment of fibres or filaments made from glass, minerals or slags; joining glass to glass or other materials: 17/002, 17/006, 17/28, 19/00, 2217/20, 2217/40, 2217/775, 2217/78, 2218/10, 2218/11, 2218/30, 2218/355, 2218/365
- Y10T Technical subjects covered by former us classification: 428/24355, 428/24926, 428/273
- (73) Assignee
- CORNING INC
- (72) Inventors
- Chen yao-sheng; GROSS TIMOTHY MICHAEL; TAMMARO DAVID ALAN; WANG LIMING
- (54) Title
- Slip agent for protecting glass
- (57) Abstract
This disclosure features use of a paper or polymer film that includes a slip agent that can transfer to its surfaces. Once the paper or film is pressed against a glass sheet, this will leave a thin surface roughness of slip agent that can prevent or reduce glass surface scratches from other surfaces or particles during shipping or finishing (e.g., cutting to size, conveyance of glass), thereby improving the yield of glass shipments between glass forming plants and customers. The thin discontinuous layer of slip agent remaining on the glass surface can be washed off easily in subsequent washing processes. The paper or film can have the slip agent imbibed within the paper or coated on it as a surface member.
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Claims (17)
- A method of protecting glass sheets from scratching comprising applying a slip agent to a surface of a glass sheet before a finishing operation, wherein said slip agent is applied to said glass sheet by transferring said slip agent from a carrier membrane including said slip agent, and wherein said slip agent is a long chain fatty ester or long chain fatty amide present on said glass sheet in an amount ranging from 1 to 10,000 nanograms per centimeter 2, and inhibiting scratching of said glass sheet during said finishing operation using said slip agent.
- The method of claim 1 wherein said slip agent is formed as a discontinuous layer on said glass sheet.
- The method of claim 1 wherein said application of said slip agent to said surface of said glass sheet forms surface roughness on said glass sheet comprising said slip agent.
- The method of claim 1 wherein said long chain fatty amide is erucamide.
- The method of claim 1, wherein the carrier membrane is a paper or film.
- The method of claim 5, wherein said slip agent is applied to said glass sheet using a process selected from the group consisting of a pressure wall process, a laminated film process, and a stacked glass with interleaf compression process.
- The method of claim 5, comprising the steps of: a) positioning said paper or film on one of said glass sheets such that said slip agent included on said paper or film is in contact with said glass sheet; b) pressing said paper or film against said glass sheet; c) transferring at least a portion of said slip agent from the paper or film onto said glass sheet; and d) removing said paper or film from said glass sheet, while leaving said slip agent on the glass sheet.
- The method of claim 7 further comprising the steps of: e) placing an additional said glass sheet against an interleaf paper including said slip agent such that said slip agent is presented on said interleaf paper is in contact with said additional said glass sheet; f) repeating said steps a) and e) until a stack of said glass sheets is arranged with said interleaf paper between adjacent said glass sheets; g) wherein said steps b) and c) occur when said interleaf paper located between said glass sheets is compressed as a result of a weight of said stack; and h) resisting scratching from glass or other particles on the glass sheets when the glass sheets move relative each other with the interleaf paper.
- The method of claim 8 comprising separating said glass sheets of said stack and then conducting step d).
- The method of claim 8 wherein said interleaf paper comprises one interleaf paper including said slip agent presented on both sides of said interleaf paper.
- The method of claim 8 wherein said interleaf paper comprises two interleaf papers each coated on one side with said slip agent and arranged such that said slip agent faces outwardly away from the other interleaf paper in contact with one of said glass sheets.
- The method of claim 8 wherein said interleaf paper comprises two interleaf papers each coated on one side with said slip agent and arranged such that said slip agent faces inwardly toward the other interleaf paper, and adjacent said papers move relative to one another due to movement of said slip agent of said facing interleaf papers but do not move relative to an adjacent said glass sheet to protect said glass sheets from scratching.
- The method of claim 7 comprising: providing paper or film wound on a feed roll; providing a take-up roll; providing a pressure roll pair, with one pressure roll adjacent each side of said glass sheet; feeding the paper or film from the feed roll, between one of the pressure rolls and said glass sheet, and to the take-up roll; carrying out said steps b) and c) by compressing said paper or film and said glass sheet between the pressure rolls on either side of said glass sheet; and carrying out said step d) by winding up said paper or film on said take-up roll once said glass sheet passes through said pressure rolls.
- The method of claim 13 wherein said feed roll and said take-up roll are disposed on both sides of said glass sheet, comprising carrying out said steps b)-d) to apply said slip agent to both sides of said glass sheet.
- The method of claim 7 comprising applying said film as a laminate film on said glass sheet as said steps a)-c) and then stripping said laminate film from said glass sheet as said step d) to result in said transferred slip agent on said glass sheet.
- The method of claim 1, wherein said slip agent is present on said glass sheet in an amount ranging from 1 to 3,000 nanograms per centimeter 2.
- The method of claim 1, wherein said slip agent is present on said glass sheet in an amount ranging from 1 to 500 nanograms per centimeter 2.
Description
The field is slip agents for protecting glass sheets from scratching.
The shipment of display glass has employed surface protection of both substrate sides using a combination of laminated films with paper interleaf or more recently, a very clean single layer paper-only interleaf material. Referring to FIG. 1 (Prior art) in the former process, three sheets were used between adjacent glass sheets 10, 12 and 12, 14. Two outer layers of polymer film 16, 18 were coated onto facing surfaces 20, 22 of the glass, which sandwiched a sheet of paper 24 between them. The laminated film protection method requires a polymer film coater, films and a film peeler. This three layer interleaf adds extra process steps and sheets of material and increases manufacturing costs. It is highly desirable to use a single layer interleaf material to pack glass sheets at the bottom of the draw (BOD) in a fusion draw process, and to pack finished goods. At the bottom of the draw the glass is unfinished and has sharp edges that chip easily during subsequent handling and finishing operations. This leads to an increased level of glass chips and other particles on the glass that can cause scratching of the glass during subsequent handling, finishing and shipping of the glass. The surface of the glass may also be scratched by the handling and finishing equipment itself, or by dirt and glass particles on or from the handling and finishing equipment and from other sources. It is desirable to protect the surface of the glass from scratching during handling, finishing and shipping operations downstream of the BOD.
Citations (42)
- DE1011597B
- DE1906027A1
- DE2161379A1
- DE2207008A1
- DE4103283A1
- GB1253464A
- JP2008021803A
- JP2008132490A
- JP6122474B2
- JPH06122474A
- US2002176988A1
- US2004089433A1
- US2005194279A1
- US2006246299A1
- US2006246302A1
- US2008020300A1
- US3349900A
- US3723312A
- US4481038A
- US4892774A
- US4929073A
- US5151804A
- US5695876A
- US5743949A
- US5748827A
- US6025015A
- US6096380A
- US6174990B1
- US6325351B1
- US6379746B1
- US6517664B1
- US6545082B2
- US6715316B2
- US6729589B2
- US6896928B2
- US7189308B2
- US7390099B2
- US7491437B1
- US8586188B1
- US8821970B2
- WO2007010276A1
- WO2008002584A1
Record as JSON
{
"publication_number": "US9771209B2",
"country": "US",
"kind": "B2",
"title": "Slip agent for protecting glass",
"abstract": "This disclosure features use of a paper or polymer film that includes a slip agent that can transfer to its surfaces. Once the paper or film is pressed against a glass sheet, this will leave a thin surface roughness of slip agent that can prevent or reduce glass surface scratches from other surfaces or particles during shipping or finishing (e.g., cutting to size, conveyance of glass), thereby improving the yield of glass shipments between glass forming plants and customers. The thin discontinuous layer of slip agent remaining on the glass surface can be washed off easily in subsequent washing processes. The paper or film can have the slip agent imbibed within the paper or coated on it as a surface member.",
"claims": [
"1. A method of protecting glass sheets from scratching comprising applying a slip agent to a surface of a glass sheet before a finishing operation, wherein said slip agent is applied to said glass sheet by transferring said slip agent from a carrier membrane including said slip agent, and wherein said slip agent is a long chain fatty ester or long chain fatty amide present on said glass sheet in an amount ranging from 1 to 10,000 nanograms per centimeter 2, and inhibiting scratching of said glass sheet during said finishing operation using said slip agent.",
"2. The method of claim 1 wherein said slip agent is formed as a discontinuous layer on said glass sheet.",
"3. The method of claim 1 wherein said application of said slip agent to said surface of said glass sheet forms surface roughness on said glass sheet comprising said slip agent.",
"4. The method of claim 1 wherein said long chain fatty amide is erucamide.",
"5. The method of claim 1, wherein the carrier membrane is a paper or film.",
"6. The method of claim 5, wherein said slip agent is applied to said glass sheet using a process selected from the group consisting of a pressure wall process, a laminated film process, and a stacked glass with interleaf compression process.",
"7. The method of claim 5, comprising the steps of: a) positioning said paper or film on one of said glass sheets such that said slip agent included on said paper or film is in contact with said glass sheet; b) pressing said paper or film against said glass sheet; c) transferring at least a portion of said slip agent from the paper or film onto said glass sheet; and d) removing said paper or film from said glass sheet, while leaving said slip agent on the glass sheet.",
"8. The method of claim 7 further comprising the steps of: e) placing an additional said glass sheet against an interleaf paper including said slip agent such that said slip agent is presented on said interleaf paper is in contact with said additional said glass sheet; f) repeating said steps a) and e) until a stack of said glass sheets is arranged with said interleaf paper between adjacent said glass sheets; g) wherein said steps b) and c) occur when said interleaf paper located between said glass sheets is compressed as a result of a weight of said stack; and h) resisting scratching from glass or other particles on the glass sheets when the glass sheets move relative each other with the interleaf paper.",
"9. The method of claim 8 comprising separating said glass sheets of said stack and then conducting step d).",
"10. The method of claim 8 wherein said interleaf paper comprises one interleaf paper including said slip agent presented on both sides of said interleaf paper.",
"11. The method of claim 8 wherein said interleaf paper comprises two interleaf papers each coated on one side with said slip agent and arranged such that said slip agent faces outwardly away from the other interleaf paper in contact with one of said glass sheets.",
"12. The method of claim 8 wherein said interleaf paper comprises two interleaf papers each coated on one side with said slip agent and arranged such that said slip agent faces inwardly toward the other interleaf paper, and adjacent said papers move relative to one another due to movement of said slip agent of said facing interleaf papers but do not move relative to an adjacent said glass sheet to protect said glass sheets from scratching.",
"13. The method of claim 7 comprising: providing paper or film wound on a feed roll; providing a take-up roll; providing a pressure roll pair, with one pressure roll adjacent each side of said glass sheet; feeding the paper or film from the feed roll, between one of the pressure rolls and said glass sheet, and to the take-up roll; carrying out said steps b) and c) by compressing said paper or film and said glass sheet between the pressure rolls on either side of said glass sheet; and carrying out said step d) by winding up said paper or film on said take-up roll once said glass sheet passes through said pressure rolls.",
"14. The method of claim 13 wherein said feed roll and said take-up roll are disposed on both sides of said glass sheet, comprising carrying out said steps b)-d) to apply said slip agent to both sides of said glass sheet.",
"15. The method of claim 7 comprising applying said film as a laminate film on said glass sheet as said steps a)-c) and then stripping said laminate film from said glass sheet as said step d) to result in said transferred slip agent on said glass sheet.",
"16. The method of claim 1, wherein said slip agent is present on said glass sheet in an amount ranging from 1 to 3,000 nanograms per centimeter 2.",
"17. The method of claim 1, wherein said slip agent is present on said glass sheet in an amount ranging from 1 to 500 nanograms per centimeter 2."
],
"description_excerpt": "The field is slip agents for protecting glass sheets from scratching.\n\nThe shipment of display glass has employed surface protection of both substrate sides using a combination of laminated films with paper interleaf or more recently, a very clean single layer paper-only interleaf material. Referring to FIG. 1 (Prior art) in the former process, three sheets were used between adjacent glass sheets 10, 12 and 12, 14. Two outer layers of polymer film 16, 18 were coated onto facing surfaces 20, 22 of the glass, which sandwiched a sheet of paper 24 between them. The laminated film protection method requires a polymer film coater, films and a film peeler. This three layer interleaf adds extra process steps and sheets of material and increases manufacturing costs. It is highly desirable to use a single layer interleaf material to pack glass sheets at the bottom of the draw (BOD) in a fusion draw process, and to pack finished goods. At the bottom of the draw the glass is unfinished and has sharp edges that chip easily during subsequent handling and finishing operations. This leads to an increased level of glass chips and other particles on the glass that can cause scratching of the glass during subsequent handling, finishing and shipping of the glass. The surface of the glass may also be scratched by the handling and finishing equipment itself, or by dirt and glass particles on or from the handling and finishing equipment and from other sources. It is desirable to protect the surface of the glass from scratching during handling, finishing and shipping operations downstream of the BOD.",
"cpc": [
"B65D 85/48",
"B32B 17/065",
"B32B 2255/12",
"B65G 49/069",
"C03C 17/002",
"C03C 17/006",
"C03C 17/28",
"C03C 19/00",
"C03C 2217/20",
"C03C 2217/40",
"C03C 2217/775",
"C03C 2217/78",
"C03C 2218/10",
"C03C 2218/11",
"C03C 2218/30",
"C03C 2218/355",
"C03C 2218/365",
"Y10T 428/24355",
"Y10T 428/24926",
"Y10T 428/273"
],
"ipc": [
"B32B 17/06",
"B65D 85/48",
"B65G 49/06",
"C03C 17/00",
"C03C 17/28",
"C03C 19/00"
],
"assignees": [
"CORNING INC"
],
"inventors": [
"Chen yao-sheng",
"GROSS TIMOTHY MICHAEL",
"TAMMARO DAVID ALAN",
"WANG LIMING"
],
"filing_date": "2014-08-04",
"publication_date": "2017-09-26",
"grant_date": "2017-09-26",
"priority_date": "2009-05-22",
"application_number": "US-201414450764-A",
"family_id": "42711145",
"citations": [
"DE1011597B",
"DE1906027A1",
"DE2161379A1",
"DE2207008A1",
"DE4103283A1",
"GB1253464A",
"JP2008021803A",
"JP2008132490A",
"JP6122474B2",
"JPH06122474A",
"US2002176988A1",
"US2004089433A1",
"US2005194279A1",
"US2006246299A1",
"US2006246302A1",
"US2008020300A1",
"US3349900A",
"US3723312A",
"US4481038A",
"US4892774A",
"US4929073A",
"US5151804A",
"US5695876A",
"US5743949A",
"US5748827A",
"US6025015A",
"US6096380A",
"US6174990B1",
"US6325351B1",
"US6379746B1",
"US6517664B1",
"US6545082B2",
"US6715316B2",
"US6729589B2",
"US6896928B2",
"US7189308B2",
"US7390099B2",
"US7491437B1",
"US8586188B1",
"US8821970B2",
"WO2007010276A1",
"WO2008002584A1"
]
}
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