Process for making an electrode active material

{
  "publication_number": "US12176514B2",
  "country": "US",
  "kind": "B2",
  "title": "Process for making an electrode active material",
  "abstract": "Disclosed herein is a process for making an electrode active material, including: (a) forming a mixture, (b) transferring the mixture into saggars, crucibles or open cups, (c) calcining the mixture at a temperature in the range of from 700 to 1000° C., (d) cooling down the resultant electrode active material, (e) applying a robot to take at least two samples of 10 mg to 10 g of every saggar, crucible or open cup to be analyzed, or per defined period of time, respectively, (f) transferring the samples to another robot or to another part of the same robot, where the robot makes an electrode material mix from samples of the same saggar, crucible or open cup, and (g) transferring the electrode material mix to a test unit to perform electrochemical tests, where the robot performs steps (f) to (g) with several samples in parallel.",
  "claims": [
    "1. A process for making an electrode active material comprising the steps of: (a) mixing a composite oxide, (oxy) hydroxide, hydroxide or carbonate of nickel and one or more of cobalt and manganese and, optionally, one or more of Mg, Al and Y or a transition metal chosen from Ti, Zr, Nb, Ta, Fe, Mo, and W, with one or more source of lithium chosen from lithium carbonate, lithium oxide and lithium hydroxide and, optionally, with one or more dopant chosen from oxides, hydroxides and oxyhydroxides of Mg, Al, Y, Ti, Zr, Nb, Ta, Fe, Mo, and W, and from fluorides, (b) transferring the mixture into saggars, crucibles or open cups, (c) calcining the mixture in a pusher kiln, roller hearth kiln, or in a rotary kiln at a temperature ranging from 700° C. to 1000° C., (d) cooling down the resultant electrode active material, (e) applying a robot to take two or more samples of 10 mg to 10 g per saggar, crucible, or open cup to be analyzed, or per defined period of time, respectively, (f) transferring the samples to another robot or to another part of the same robot, wherein the respective robot makes an electrode material mix from electrode material samples of the same saggar, crucible, or open cup, and (g) transferring the electrode material mix to a test unit to perform electrochemical tests, wherein the robot performs steps (f) to (g) with several samples in parallel.",
    "2. The process according to claim 1 wherein step (d) is performed to a maximum temperature of 150° C.",
    "3. The process according to claim 1, wherein step (f) comprises mixing the electrode active material with conductive carbon, a binder polymer, and NMP.",
    "4. The process according to claim 1, wherein step (f) is performed in a forming die with a plurality of recesses arranged in rows, or in wells of a microtiter plate.",
    "5. The process according to claim 1, wherein the transfer in step (g) is made with the help of an electronic pipette or an overhead gravimetric dispersing unit.",
    "6. The process according to claim 1, wherein in step (e), samples are taken from one out of every 5 to 12 saggars, crucible, or open cup per production run.",
    "7. The process according to claim 1, wherein step (g) further comprises the sub-steps of: (g1) placing each electrode material mix on a current collector, (g2) removing any volatile material from the electrode material mix on the current collectors, thereby obtaining cathodes, (g3) attaching the obtained cathodes to separators that are each combined with an anode and with an electrolyte, thereby obtaining coin-type cells, and (g4) performing electrochemical tests with the coin-type cells from (g3).",
    "8. The process according to claim 1, wherein an entire documentation of steps (e) to (g) is performed by a processing device, and the results of electrochemical tests are compared to desired results by a processing device.",
    "9. The process according to claim 8, wherein the processing device collects data as input through an input channel and provides an electronic signal via an output channel to a production control function, wherein two or more consecutive samples show a negative deviation from desired results."
  ],
  "description_excerpt": "Lithium ion secondary batteries are modern devices for storing energy. Many application fields have been and are contemplated, from small devices such as mobile phones and laptop computers through car batteries and other batteries for e-mobility. Various components of the batteries have a decisive role with respect to the performance of the battery such as the electrolyte, the electrode materials, and the separator. Particular attention has been paid to the cathode materials. Several materials have been suggested, such as lithium iron phosphates, lithium cobalt oxides, and lithium nickel cobalt manganese oxides. Although extensive research has been performed the solutions found so far still leave room for improvement.\n\nCathode active materials are generally manufactured by using a two-stage process. In a first stage, a sparingly soluble compound of the transition metal(s) is made by precipitating it from a solution, for example a carbonate or a hydroxide. Said sparingly soluble salts are in many cases also referred to as precursors. In a second stage, a precursor is mixed with a lithium compound, for example Li 2 CO 3, LiOH or Li 2 O, and calcined at high temperatures, for example at 600 to 1100° C.\n\nSeveral technical fields are still to be solved. Volumetric energy density, capacity fade, cycling stability are still fields of research and development. However, in production additional problems have been detected. Although a constant product quality is desired sometimes the quality and the composition varies in broad ranges.",
  "cpc": [
    "H01M 4/0471",
    "B25J 11/00",
    "B25J 9/0084",
    "C01G 53/44",
    "C01G 53/82",
    "C01P 2004/51",
    "C01P 2004/61",
    "C01P 2006/10",
    "C01P 2006/11",
    "C01P 2006/12",
    "C01P 2006/40",
    "C01P 2006/80",
    "C01P 2006/82",
    "G01N 27/26",
    "G01N 27/30",
    "H01M 4/04",
    "H01M 4/0404",
    "H01M 4/525",
    "H01M 4/622",
    "H01M 4/625",
    "Y02E 60/10"
  ],
  "ipc": [
    "C01G 53/00",
    "H01M 4/04",
    "H01M 4/525",
    "H01M 4/62"
  ],
  "assignees": [
    "BASF SE"
  ],
  "inventors": [
    "Heino Sommer",
    "Carsten SUELING"
  ],
  "filing_date": "2021-01-12",
  "publication_date": "2024-12-24",
  "grant_date": "2024-12-24",
  "priority_date": "2020-01-28",
  "application_number": "US-202117595337-A",
  "family_id": "69375255",
  "cited_by_count": 0,
  "citations": [
    "JPH10289729A",
    "EP3093272A1",
    "US20180090759A1",
    "CN108123100A"
  ]
}