Process for the isolation of alkylated aromatic amines

{
  "publication_number": "US4973759A",
  "country": "US",
  "kind": "A",
  "title": "Process for the isolation of alkylated aromatic amines",
  "abstract": "Alkylated aromatic amines can be isolated from crude catalyst-containing mixtures of these with olefins by a procedure in which in general equivalent amounts of an inorganic base and water are added to the alkylation mixture, the catalyst is hydrolysed, the water present in the reaction mixture after the hydrolysis is removed by distillation and the solid catalyst residue is separated off. The catalyst-free alkylation mixture which remains is then fed to customary further working up.",
  "claims": [
    "1. In a process for the isolation of alkylated aromatic amines comprising working up crude mixtures from the alkylation of aromatic amines with olefins containing metal catalysts and/or metal halide catalysts, wherein when a metal halide catalyst is employed an inorganic base in an amount which is at least equivalent to the amount of the catalyst halide is added to the alkylation mixture, and wherein water in an amount which is at least sufficient to hydrolyze all the catalyst metal is added to the alkylation mixture, the improvement which comprises removing by distillation the water present in the reaction mixture after the hydrolysis, separating off a solid catalyst residue and feeding a catalyst-free alkylation mixture which remains to the working up.",
    "2. The process according to claim 1, wherein aromatic amines of the formula ##STR4## in which R 1 and R 2 independently of one another denote hydrogen, methyl or phenyl which is substituted by R 3, R 4 and R 5, R 3 and R 4 independently of one another denote hydrogen, straight-chain or branched C 1 -C 10 -alkyl, straight chain or branched C 1 -C 10 -alkoxy, phenyl, fluorine, chlorine or bromine and R 5 represents hydrogen, methyl, ethyl or amino, are employed for the alkylation.",
    "3. The process according to claim 2, wherein aromatic amines of the formula ##STR5## in which R 11 denotes hydrogen or phenyl which is substituted by R 5, R 13 and R 14, R 13 and R 14 independently of one another denote hydrogen, straight-chain or branched C 1 -C 4 -alkyl, straight-chain or branched C 1 -C 4 -alkoxy, phenyl, fluorine or chlorine and R 5 represents hydrogen, methyl, ethyl or amino, are employed for the alkylation.",
    "4. The process according to claim 3, wherein aromatic amines of the formula ##STR6## in which R 21 denotes hydrogen or phenyl which is substituted by R 5 and R 23, R 5 represents hydrogen, methyl, ethyl or amino and R 23 represents hydrogen, straight-chain or branched C 1 -C 4 -alkyl, straight-chain or branched C 1 -C 4 -alkoxy or phenyl are employed for the alkylation.",
    "5. The process according to claim 1, wherein straight-chain or branched C 2 -C 10 -olefins are employed.",
    "6. The process according to claim 5, wherein straight-chain or branched C 2 -C 6 -olefins are employed.",
    "7. The process according to claim 6, wherein straight-chain or branched C 2 -C 4 -olefins are employed.",
    "8. The process according to claim 1, wherein an aluminum-containing catalyst is present in the crude alkylation mixture.",
    "9. The process according to claim 8, wherein Al, Al/AlCl 3, Al/Zn/AlCl 3 or AlCl 3 is present in the crude alkylation mixture.",
    "10. The process according to claim 1, wherein the hydrides, oxides, hydroxides, carbonates, bicarbonates or alkaline salts of other weak acids of the alkali metals and alkaline earth metals are employed as the inorganic bases.",
    "11. The process according to claim 1, wherein the inorganic base is employed in an amount which extends from the amount based stoichiometricalIy on the halogen content of the catalyst up to 300% of the amount based stoichiometrically on the metal content and the halogen content of the catalyst.",
    "12. The process according to claim 11, wherein the inorganic base is employed up to 150% of the amount based stoichiometrically on the metal content and the halogen content of the catalyst.",
    "13. The process according to claim 1, wherein the water is added in an amount which is 1.1 to 10 times the amount sufficient for hydrolysis of the catalyst metal.",
    "14. The process according to claim 13, wherein the water is added in an amount which is 1.5 to 4 times the amount sufficient for hydrolysis of the catalyst metal.",
    "15. The process according to claim 1, wherein the excess water is removed by distillation under 400 to 1000 mbar up to a bottom temperature of 140°-160° C.",
    "16. The process according to claim 15 wherein the excess water is removed by distillation under normal pressure.",
    "17. The process according to claim 1, wherein an agent which forms an azeotrope is added for removal of the excess water by distillation.",
    "18. The process according to claim 1, wherein the water which remains after the hydrolysis and has been removed by distillation is employed as part of the hydrolysis water of a subsequent batch.",
    "19. A process according to claim 1, wherein the further working up comprises a distillation.",
    "20. A process according to claim 1, wherein the further working up comprises a fine distillation."
  ],
  "cpc": [
    "C07C 209/84"
  ],
  "assignees": [
    "BAYER AG"
  ],
  "filing_date": "1989-09-20",
  "publication_date": "1990-11-27",
  "grant_date": "1990-11-27",
  "priority_date": "1988-10-07",
  "application_number": "US-41018389-A",
  "family_id": "6364629",
  "citations": [
    "US2187820A",
    "US2814646A",
    "US3862233A",
    "US4128582A",
    "US4760185A"
  ]
}