Patent · US5238789A · A · US
Color photographic image formation method
- (11) Publication number
- US5238789A
- (21) Application number
- US-80391791-A
- (22) Filing date
- 1991-12-09
- (30) Priority date
- 1988-10-03
- (43) Publication date
- 1993-08-24
- (45) Date of grant
- 1993-08-24
- (52) CPC
- G03C Photosensitive materials for photographic purposes; photographic processes, e.g. cine, x-ray, colour, stereo-photographic processes; auxiliary processes in photography: 7/3022, 7/413
- (73) Assignee
- FUJI PHOTO FILM CO LTD
- (54) Title
- Color photographic image formation method
- (57) Abstract
A method for forming an image, comprising developing an imagewise exposed silver halide color photographic material comprising a support having thereon at least one blue sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, and at least one red-sensitive silver halide emulsion layer with a color developer containing at least one aromatic primary amine color developing agent, wherein the red-sensitive silver halide emulsion layer contains a high silver chloride silver halide emulsion having a silver bromide content of from 0.5 to 6 mol%, and the color developer contains from 3.5×10 -2 to 1.5×10 -1 mol/l of chloride ion and from 3.0×10 -5 to 1.0×10 -3 mol/l of bromide ion. The method provides an image having a high maximum density and a low minimum density at high sensitivity while markedly suppressing variations in photographic characteristics, particularly of minimum density, even in rapid and continuous processing.
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Claims (9)
- A method for forming an image which comprises developing an imagewise exposed silver halide color photographic material comprising a support having thereon at least one blue-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, and at least one red-sensitive silver halide emulsion layer with a color developer containing at least one aromatic primary amine color developing agent, wherein said red-sensitive silver halide emulsion layer contains silver chlorobromide having not more than 1 mol% of silver iodide and having a silver bromide content of from 0.5 to 6 mol%, wherein said blue-sensitive silver halide emulsion layer and said green-sensitive silver halide emulsion layer each comprises a high silver chloride emulsion having a silver chloride content of at least 98 mol%, the total silver coverage of the photographic material is 0.80 g/m 2 or less and said color developer contains from 3.5×10 -2 to 1.5×10 -1 mol/l of chloride ions and from 5.0×10 -5 to 5.0×10 -4 mol/l of bromide ion.
- A method as claimed in claim 1, wherein said developer has a chloride ion content of from 4×10 -2 to 1 ×10 -1 mol/l.
- A method as claimed in claim 1, wherein said color developing includes replenishing said color developer at a rate of 20 to 150 ml of color developer per m 2 of said silver halide color photographic material.
- A method as claimed in claim 1, wherein the red-sensitive silver halide emulsion layer contains not more than 0.2 mol% silver iodide.
- A method as claimed in claim 1, wherein the silver halide emulsion is a monodispersed emulsion having a coefficient of variation of grain size of not more than 20%.
- A method as claimed in claim 1, wherein said color developer contains an organic preservative.
- A method as claimed in claim 6, wherein the organic preservative is selected from a hydroxylamine derivative and a hydrazine derivative.
- A method as claimed in claim 1, wherein the red-sensitive silver halide emulsion layer contains 0.5 to 2 mol% silver bromide.
- The method of claim 1, wherein the total silver coverage of the photographic material is 0.75 g/m 2 or less.
Citations (6)
- JPS63106655A
- JPS63106665A
- US4801516A
- US4851326A
- US4853321A
- US4880728A
Record as JSON
{
"publication_number": "US5238789A",
"country": "US",
"kind": "A",
"title": "Color photographic image formation method",
"abstract": "A method for forming an image, comprising developing an imagewise exposed silver halide color photographic material comprising a support having thereon at least one blue sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, and at least one red-sensitive silver halide emulsion layer with a color developer containing at least one aromatic primary amine color developing agent, wherein the red-sensitive silver halide emulsion layer contains a high silver chloride silver halide emulsion having a silver bromide content of from 0.5 to 6 mol%, and the color developer contains from 3.5×10 -2 to 1.5×10 -1 mol/l of chloride ion and from 3.0×10 -5 to 1.0×10 -3 mol/l of bromide ion. The method provides an image having a high maximum density and a low minimum density at high sensitivity while markedly suppressing variations in photographic characteristics, particularly of minimum density, even in rapid and continuous processing.",
"claims": [
"1. A method for forming an image which comprises developing an imagewise exposed silver halide color photographic material comprising a support having thereon at least one blue-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer, and at least one red-sensitive silver halide emulsion layer with a color developer containing at least one aromatic primary amine color developing agent, wherein said red-sensitive silver halide emulsion layer contains silver chlorobromide having not more than 1 mol% of silver iodide and having a silver bromide content of from 0.5 to 6 mol%, wherein said blue-sensitive silver halide emulsion layer and said green-sensitive silver halide emulsion layer each comprises a high silver chloride emulsion having a silver chloride content of at least 98 mol%, the total silver coverage of the photographic material is 0.80 g/m 2 or less and said color developer contains from 3.5×10 -2 to 1.5×10 -1 mol/l of chloride ions and from 5.0×10 -5 to 5.0×10 -4 mol/l of bromide ion.",
"2. A method as claimed in claim 1, wherein said developer has a chloride ion content of from 4×10 -2 to 1 ×10 -1 mol/l.",
"3. A method as claimed in claim 1, wherein said color developing includes replenishing said color developer at a rate of 20 to 150 ml of color developer per m 2 of said silver halide color photographic material.",
"4. A method as claimed in claim 1, wherein the red-sensitive silver halide emulsion layer contains not more than 0.2 mol% silver iodide.",
"5. A method as claimed in claim 1, wherein the silver halide emulsion is a monodispersed emulsion having a coefficient of variation of grain size of not more than 20%.",
"6. A method as claimed in claim 1, wherein said color developer contains an organic preservative.",
"7. A method as claimed in claim 6, wherein the organic preservative is selected from a hydroxylamine derivative and a hydrazine derivative.",
"8. A method as claimed in claim 1, wherein the red-sensitive silver halide emulsion layer contains 0.5 to 2 mol% silver bromide.",
"9. The method of claim 1, wherein the total silver coverage of the photographic material is 0.75 g/m 2 or less."
],
"cpc": [
"G03C 7/3022",
"G03C 7/413"
],
"assignees": [
"FUJI PHOTO FILM CO LTD"
],
"filing_date": "1991-12-09",
"publication_date": "1993-08-24",
"grant_date": "1993-08-24",
"priority_date": "1988-10-03",
"application_number": "US-80391791-A",
"family_id": "27333809",
"citations": [
"JPS63106655A",
"JPS63106665A",
"US4801516A",
"US4851326A",
"US4853321A",
"US4880728A"
]
}
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