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Patent · US6544942B1 · B1 · US

Phase-separating solvent composition

(11) Publication number
US6544942B1
(21) Application number
US-64177500-A
(22) Filing date
2000-08-18
(30) Priority date
2000-04-28
(43) Publication date
2003-04-08
(45) Date of grant
2003-04-08
(52) CPC
  • C11D Detergent compositions; use of single substances as detergents; soap or soap-making; resin soaps; recovery of glycerol: 3/48, 17/0017, 3/2034, 3/3945, 3/43, 7/5022
  • A01N Preservation of bodies of humans or animals or plants or parts thereof; biocides, e.g. as disinfectants, as pesticides or as herbicides; pest repellants or attractants; plant growth regulators: 25/02, 37/16, 59/00, 61/00
  • B05D Processes for applying fluent materials to surfaces, in general: 1/325, 3/067, 5/00, 7/52
  • C09D Coating compositions, e.g. paints, varnishes or lacquers; filling pastes; chemical paint or ink removers; inks; correcting fluids; woodstains; pastes or solids for colouring or printing; use of materials therefor: 7/00
  • Y10T Technical subjects covered by former us classification: 428/24479, 428/26, 428/265, 428/31551, 428/31573, 442/2139, 442/2213, 442/259
(73) Assignee
ECOLAB INC
(54) Title
Phase-separating solvent composition
(57) Abstract

A pseudo-stable phase-splitting solvent composition that forms a single liquid phase when subjected to mild agitation and retains that single phase while the composition is applied to a surface, but which forms two or more laminar liquid phases promptly after being applied. A concentrated solvent film forms on the surface, under a film containing the other phase. The solvent preferably is denser than water, and the composition preferably is diluted with water. This enables the solvent to attack the surface at near full strength, and provides a water seal over the solvent film. The solvent composition can be used full strength or in diluted form for cleaning, reducing the microbial population of, or degreasing a variety of surfaces, and for stripping a variety of difficult-to-remove coatings from surfaces.

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Claims (25)

  1. A pseudo-stable phase-splitting cleaning, antimicrobial, degreasing or stripping solvent composition that forms at least two phases promptly after being applied atop a generally horizontal surface or on a generally vertical surface, whereby a film containing a concentrated amount of the solvent lies between the surface and a film containing a much lower amount of the solvent.
  2. A composition according to claim 1, wherein the solvent comprises a polar solvent.
  3. A composition according to claim 2, wherein the polar solvent is at least one or more of an ether, an aromatic alcohol, a dialkyl diester, or mixtures thereof.
  4. A composition according to claim 2, wherein the polar solvent is at least one or more of benzyl alcohol, ethylene glycol phenyl ether, propylene glycol phenyl ether, propylene carbonate, phenoxyethanol, dimethyl adipate, dimethyl succinate, dimethyl glutarate, dimethyl malonate, diethyl adipate, diethyl succinate, diethyl glutarate, dibutyl adipate, dibutyl succinate, dibutyl glutarate, or mixtures hereof.
  5. A composition according to claim 1, wherein the composition is an antimicrobial composition or contains another antimicrobial or biocidal agent dissolved or dispersed in the solvent.
  6. A composition according to claim 1, wherein the composition contains water, and the solvent is more dense than water.
  7. A composition according to claim 6, wherein when the composition is mixed it has a pseudo-stable emulsified state that lasts for at least one minute or more after mixing while the composition is stored in a bucket or other vessel, and wherein when the composition is applied to a surface it will phase-separate to form a predominantly solvent-containing layer on the surface.
  8. A composition according to claim 7, wherein the surface is at least one or more of a hard surface, soft surface, porous surface, food substance or skin.
  9. A composition according to claim 8, wherein the surface comprises an architectural surface.
  10. A composition according to claim 9, wherein the architectural surface is at least one or more of a floor, wall, window, sink, table, counter or bathroom.
  11. A composition according to claim 8, wherein the surface is at least one or more of a medical or surgical instrument or device, a transportation vehicle, or an eating utensil.
  12. A composition according to claim 8, wherein the surface comprises a porous surface.
  13. A composition according to claim 12, wherein the porous surface comprises paper or fabric.
  14. A composition according to claim 8, when the surface comprises a floor.
  15. A composition according to claim 14, wherein the composition will phase-separate within two minutes after application.
  16. A composition according to claim 7, wherein the surface comprises a crosslinked polymeric topcoat.
  17. A composition according to claim 6, wherein the solvent has a water solubility less than about 10% by weight.
  18. A composition according to claim 6, wherein the solvent has a water solubility less than about 5% by weight.
  19. A composition according to claim 6, wherein the solvent has a water solubility less than about 1% by weight.
  20. A composition according to claim 1, further comprising cosolvent or surfactant.
  21. A composition according to claim 20, wherein the cosolvent has greater water solubility than the solvent.
  22. A composition according to claim 20, containing water and at least about 10% solvent.
  23. A composition according to claim 20, containing water and at least about 50 weight % solvent.
  24. A composition according to claim 20, containing about 75 weight % to about 95 weight % solvent.
  25. A pseudo-stable phase-splitting cleaning, antimicrobial, degreasing or stripping solvent composition, wherein the composition contains about 75 weight % to about 95 weight % solvent and the solvent comprises benzyl alcohol, ethylene glycol phenyl ether, phenoxyethanol, or propylene glycol phenyl ether, and the composition further comprises cosolvent or surfactant, contains about 5 weight % to about 25 weight % cosolvent comprising diethylene glycol monobutyl ether or dipropylene glycol N-butyl ether, and contains no more than about 3 weight % surfactant.

Citations (30)

  • DE19811386A1
  • GB2173508A
  • US4130435A
  • US4414128A
  • US4592787A
  • US4689168A
  • US4891073A
  • US4992108A
  • US5007969A
  • US5080822A
  • US5080831A
  • US5096501A
  • US5158710A
  • US5342551A
  • US5419848A
  • US5529887A
  • US5585341A
  • US5637559A
  • US5744440A
  • US5786319A
  • US5811383A
  • US5849682A
  • US5854187A
  • US5922665A
  • US5972874A
  • US5997042A
  • US6010995A
  • WO9422965A2
  • WO9718285A1
  • WO9811168A1
Record as JSON
{
  "publication_number": "US6544942B1",
  "country": "US",
  "kind": "B1",
  "title": "Phase-separating solvent composition",
  "abstract": "A pseudo-stable phase-splitting solvent composition that forms a single liquid phase when subjected to mild agitation and retains that single phase while the composition is applied to a surface, but which forms two or more laminar liquid phases promptly after being applied. A concentrated solvent film forms on the surface, under a film containing the other phase. The solvent preferably is denser than water, and the composition preferably is diluted with water. This enables the solvent to attack the surface at near full strength, and provides a water seal over the solvent film. The solvent composition can be used full strength or in diluted form for cleaning, reducing the microbial population of, or degreasing a variety of surfaces, and for stripping a variety of difficult-to-remove coatings from surfaces.",
  "claims": [
    "1. A pseudo-stable phase-splitting cleaning, antimicrobial, degreasing or stripping solvent composition that forms at least two phases promptly after being applied atop a generally horizontal surface or on a generally vertical surface, whereby a film containing a concentrated amount of the solvent lies between the surface and a film containing a much lower amount of the solvent.",
    "2. A composition according to claim 1, wherein the solvent comprises a polar solvent.",
    "3. A composition according to claim 2, wherein the polar solvent is at least one or more of an ether, an aromatic alcohol, a dialkyl diester, or mixtures thereof.",
    "4. A composition according to claim 2, wherein the polar solvent is at least one or more of benzyl alcohol, ethylene glycol phenyl ether, propylene glycol phenyl ether, propylene carbonate, phenoxyethanol, dimethyl adipate, dimethyl succinate, dimethyl glutarate, dimethyl malonate, diethyl adipate, diethyl succinate, diethyl glutarate, dibutyl adipate, dibutyl succinate, dibutyl glutarate, or mixtures hereof.",
    "5. A composition according to claim 1, wherein the composition is an antimicrobial composition or contains another antimicrobial or biocidal agent dissolved or dispersed in the solvent.",
    "6. A composition according to claim 1, wherein the composition contains water, and the solvent is more dense than water.",
    "7. A composition according to claim 6, wherein when the composition is mixed it has a pseudo-stable emulsified state that lasts for at least one minute or more after mixing while the composition is stored in a bucket or other vessel, and wherein when the composition is applied to a surface it will phase-separate to form a predominantly solvent-containing layer on the surface.",
    "8. A composition according to claim 7, wherein the surface is at least one or more of a hard surface, soft surface, porous surface, food substance or skin.",
    "9. A composition according to claim 8, wherein the surface comprises an architectural surface.",
    "10. A composition according to claim 9, wherein the architectural surface is at least one or more of a floor, wall, window, sink, table, counter or bathroom.",
    "11. A composition according to claim 8, wherein the surface is at least one or more of a medical or surgical instrument or device, a transportation vehicle, or an eating utensil.",
    "12. A composition according to claim 8, wherein the surface comprises a porous surface.",
    "13. A composition according to claim 12, wherein the porous surface comprises paper or fabric.",
    "14. A composition according to claim 8, when the surface comprises a floor.",
    "15. A composition according to claim 14, wherein the composition will phase-separate within two minutes after application.",
    "16. A composition according to claim 7, wherein the surface comprises a crosslinked polymeric topcoat.",
    "17. A composition according to claim 6, wherein the solvent has a water solubility less than about 10% by weight.",
    "18. A composition according to claim 6, wherein the solvent has a water solubility less than about 5% by weight.",
    "19. A composition according to claim 6, wherein the solvent has a water solubility less than about 1% by weight.",
    "20. A composition according to claim 1, further comprising cosolvent or surfactant.",
    "21. A composition according to claim 20, wherein the cosolvent has greater water solubility than the solvent.",
    "22. A composition according to claim 20, containing water and at least about 10% solvent.",
    "23. A composition according to claim 20, containing water and at least about 50 weight % solvent.",
    "24. A composition according to claim 20, containing about 75 weight % to about 95 weight % solvent.",
    "25. A pseudo-stable phase-splitting cleaning, antimicrobial, degreasing or stripping solvent composition, wherein the composition contains about 75 weight % to about 95 weight % solvent and the solvent comprises benzyl alcohol, ethylene glycol phenyl ether, phenoxyethanol, or propylene glycol phenyl ether, and the composition further comprises cosolvent or surfactant, contains about 5 weight % to about 25 weight % cosolvent comprising diethylene glycol monobutyl ether or dipropylene glycol N-butyl ether, and contains no more than about 3 weight % surfactant."
  ],
  "cpc": [
    "C11D 3/48",
    "A01N 25/02",
    "A01N 37/16",
    "A01N 59/00",
    "A01N 61/00",
    "B05D 1/325",
    "B05D 3/067",
    "B05D 5/00",
    "B05D 7/52",
    "C09D 7/00",
    "C11D 17/0017",
    "C11D 3/2034",
    "C11D 3/3945",
    "C11D 3/43",
    "C11D 7/5022",
    "Y10T 428/24479",
    "Y10T 428/26",
    "Y10T 428/265",
    "Y10T 428/31551",
    "Y10T 428/31573",
    "Y10T 442/2139",
    "Y10T 442/2213",
    "Y10T 442/259"
  ],
  "assignees": [
    "ECOLAB INC"
  ],
  "filing_date": "2000-08-18",
  "publication_date": "2003-04-08",
  "grant_date": "2003-04-08",
  "priority_date": "2000-04-28",
  "application_number": "US-64177500-A",
  "family_id": "24236665",
  "citations": [
    "DE19811386A1",
    "GB2173508A",
    "US4130435A",
    "US4414128A",
    "US4592787A",
    "US4689168A",
    "US4891073A",
    "US4992108A",
    "US5007969A",
    "US5080822A",
    "US5080831A",
    "US5096501A",
    "US5158710A",
    "US5342551A",
    "US5419848A",
    "US5529887A",
    "US5585341A",
    "US5637559A",
    "US5744440A",
    "US5786319A",
    "US5811383A",
    "US5849682A",
    "US5854187A",
    "US5922665A",
    "US5972874A",
    "US5997042A",
    "US6010995A",
    "WO9422965A2",
    "WO9718285A1",
    "WO9811168A1"
  ]
}

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