Porous mullite bodies and methods of forming them

{
  "publication_number": "US7485594B2",
  "country": "US",
  "kind": "B2",
  "title": "Porous mullite bodies and methods of forming them",
  "abstract": "A porous mullite composition is made by forming a mixture of one or more precursor compounds having the elements present in mullite (e.g., clay, alumina, silica) and a property enhancing compound. The property enhancing compound is a compound having an element selected from the group consisting of Mg, Ca, Fe, Na, K, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, B, Y, Sc, La and combination thereof. The mixture is shaped and to form a porous green shape which is heated under an atmosphere having a fluorine containing gas to a temperature sufficient to form a mullite composition comprised substantially of acicular mullite grains that are essentially chemically bound.",
  "claims": [
    "1. A porous mullite composition comprised substantially of acicular mullite grains that are essentially chemically bound, wherein the mullite composition has a glassy grain boundary phase comprised of silica and metal impurities in the form of metal oxides situated at the mullite grain surfaces and at intersecting grain surfaces, wherein the glassy grain boundary phase is comprised of at least one first element, in the form of an oxide, selected from the group consisting of Mg, Ca, Y and combination thereof and at least one second element, in the form of an oxide, selected from the group consisting of Nd, Ce, B, Fe and combination thereof.",
    "2. The porous mullite composition of claim 1 wherein the ratio of the first element to the second element is from about 0.1 to about 10 by weight.",
    "3. The porous mullite composition of claim 1 wherein the composition has Nd and Mg therein and the ratio of Nd/Mg is from about 0.1 to about 10 by weight.",
    "4. The porous mullite composition of claim 3 wherein the ratio is about 0.2 to about 5.",
    "5. The porous mullite composition of claim 1 wherein the porous mullite composition has a porosity of about 50% to about 70%.",
    "6. The porous mullite composition of claim 1 wherein the porous mullite composition has a thermal shock factor of at least about 300° C.",
    "7. The porous mullite composition of claim 6 wherein the mullite composition has a thermal shock factor of at least about 400° C.",
    "8. A diesel particulate filter comprised of the mullite composition of claim 1.",
    "9. The diesel particulate filter of claim 8 wherein the mullite composition has a catalyst coating on at least a portion of the mullite grains of the mullite composition.",
    "10. A diesel particulate filter comprised of the mullite composition of claim 7.",
    "11. The diesel particulate filter of claim 10 wherein the mullite composition has a catalyst coating on at least a portion of the mullite grains of the mullite composition.",
    "12. A catalyst comprised of the mullite composition of claim 1 having a catalyst coating on at least a portion of the grains of the mullite composition.",
    "13. The catalyst of claim 12 wherein the catalyst is an automotive catalyst for the treatment of exhaust or a catalytic combustor.",
    "14. The mullite composition of claim 1, wherein the first and second element are in the form of crystalline precipitates in the glassy grain boundary phase.",
    "15. The mullite composition of claim 1, wherein the first and second element are a part of the glass structure of the glassy grain boundary phase."
  ],
  "cpc": [
    "B01J 23/10",
    "B01D 39/2093",
    "B01J 23/63",
    "B01J 37/0215",
    "C04B 2235/3206",
    "C04B 2235/3208",
    "C04B 2235/322",
    "C04B 2235/3224",
    "C04B 2235/3225",
    "C04B 2235/3229",
    "C04B 2235/3409",
    "C04B 2235/349",
    "C04B 2235/449",
    "C04B 2235/604",
    "C04B 2235/658",
    "C04B 2235/661",
    "C04B 2235/72",
    "C04B 2235/77",
    "C04B 2235/96",
    "C04B 2235/9607",
    "C04B 35/185",
    "C04B 35/6365",
    "F01N 2330/06",
    "F01N 2510/06",
    "F01N 2510/0682"
  ],
  "assignees": [
    "DOW GLOBAL TECHNOLOGIES INC"
  ],
  "filing_date": "2007-05-01",
  "publication_date": "2009-02-03",
  "grant_date": "2009-02-03",
  "priority_date": "2005-10-03",
  "application_number": "US-79941307-A",
  "family_id": "38479675",
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}