Wear resistant polymer composition having improved surface appearance

{
  "publication_number": "US11407957B2",
  "country": "US",
  "kind": "B2",
  "title": "Wear resistant polymer composition having improved surface appearance",
  "abstract": "A tribologically modified polyoxymethylene polymer composition is disclosed. The polyoxymethylene polymer composition is comprised of a polyoxymethylene polymer in combination with a tribological modifier system. The tribological modifier system may include the combination of a fluoropolymer with a high density polyethylene, such as an oxidized high density polyethylene. The particular formulation provides a synergistic blend of properties. For instance, the polymer composition not only has an excellent surface appearance when molded into articles but has excellent low friction characteristics when tested against aluminum.",
  "claims": [
    "1. A conveyor device comprising: a conveyor chain that moves over a track, the conveyor chain including a plurality of conveyor components having a top surface for receiving and transporting products, the conveyor components being comprised of a polymer composition containing a polyoxymethylene polymer, a first tribological modifier comprising a fluoropolymer and a second tribological modifier comprising a polyolefin, and wherein the polymer composition has a dynamic coefficient of friction against a countermaterial of less than about 0.2, the countermaterial comprising aluminum, and wherein the composition exhibits a wear track depth of less than 2 microns when tested against aluminum, and wherein the polymer composition contains the polyoxymethylene polymer in an amount of at least 90% by weight, and wherein the fluoropolymer comprises polytetrafluoroethylene particles having a mean particle diameter of from about 1 micron to about 10 microns when tested according to ISO Test 13321, the polytetrafluoroethylene particles being present in the polymer composition in an amount of from about 1% to about 5% by weight, the polyolefin polymer comprising an oxidized high density polyethylene polymer, the oxidized high density polyethylene polymer being present in the polymer composition in an amount from about 0.3% to about 3% by weight.",
    "2. A conveyor device as defined in claim 1, wherein the polymer composition further contains one or more coloring agents, the one or more coloring agents being present in the composition in an amount from about 0.3% to about 2% by weight, the one or more coloring agents comprising titanium dioxide, carbon black, a pigment, or mixtures thereof.",
    "3. A conveyor device comprising: a conveyor chain that moves over a track, the conveyor chain including a plurality of conveyor components having a top surface for receiving and transporting products, the conveyor components being comprised of: a polyoxymethylene polymer; a first tribological modifier comprising a fluoropolymer, the fluoropolymer being present in the composition in an amount of at least about 1% by weight; a second tribological modifier comprising a high density polyethylene, the high density polyethylene having a density greater than 0.94 g/cm 3 and less than about 0.99 g/cm 3; and wherein the composition does not contain any other tribological modifiers.",
    "4. A conveyor device as defined in claim 3, wherein the polymer composition has a dynamic coefficient of friction against a countermaterial of less than about 0.2, the countermaterial comprising aluminum.",
    "5. A conveyor device as defined in claim 3, wherein the composition exhibits a wear track depth of less than 2 microns when tested against aluminum.",
    "6. A conveyor device as defined in claim 3, wherein the first tribological modifier comprises polytetrafluoroethylene particles.",
    "7. A conveyor device as defined in claim 6, wherein the polytetrafluoroethylene particles have an average particle size of from about 1 micron to about 10 microns when tested according to ISO Test 13321.",
    "8. A conveyor device as defined in claim 3, wherein the high density polyethylene polymer has a Shore D hardness of from about 69 to about 80 when tested according to ASTM Test D785.",
    "9. A conveyor device as defined in claim 3, wherein the high density polyethylene polymer comprises an oxidized high density polyethylene homopolymer.",
    "10. A conveyor device as defined in claim 3, wherein the high density polyethylene polymer has a density of from 0.95 g/cm 3 to about 0.99 g/cm 3.",
    "11. A conveyor device as defined in claim 3, wherein the fluoropolymer is present in the composition in an amount from about 1.5% to about 3% by weight and the high density polyethylene is present in the composition in an amount from about 0.3% to about 3% by weight.",
    "12. A conveyor device as defined in claim 3, wherein the polymer composition further contains a lubricant.",
    "13. A conveyor device as defined in claim 3, wherein the polymer composition further contains a copolyamide.",
    "14. A conveyor device as defined in claim 3, wherein the polymer composition further contains an acid scavenger.",
    "15. A conveyor device as defined in claim 14, wherein the acid scavenger comprises tricalcium citrate.",
    "16. A conveyor device as defined in claim 3, wherein the polymer composition further contains a nucleant, wherein the nucleant comprises a polyoxymethylene terpolymer.",
    "17. A conveyor device as defined in claim 3, wherein the polymer composition further contains one or more coloring agents, the one or more coloring agents being present in the composition in an amount from about 0.3% to about 2% by weight.",
    "18. A conveyor device as defined in claim 17, wherein the one or more coloring agents comprises titanium dioxide, carbon black, a pigment, or mixtures thereof.",
    "19. A conveyor device as defined in claim 3, wherein the polyoxymethylene polymer is present in the composition in an amount of at least 85% by weight.",
    "20. A conveyor device comprising: a conveyor chain that moves over a track, the conveyor chain including a plurality of conveyor components having a top surface for receiving and transporting products, the conveyor components being comprised of: a polyoxymethylene polymer; a first tribological modifier comprising a fluoropolymer, the fluoropolymer being present in the composition in an amount of at least about 1% by weight; a second tribological modifier comprising a high density polyethylene, the high density polyethylene having a density of greater than 0.94 g/cm 3 to about 0.99 g/cm 3; a third tribological modifier comprising an ultrahigh molecular weight polyethylene; and wherein the composition does not contain any other tribological modifiers."
  ],
  "description_excerpt": "Polyacetal polymers, which are commonly referred to as polyoxymethylene polymers, have become established as exceptionally useful engineering materials in a variety of applications. For instance, because polyoxymethylene polymers have excellent mechanical properties, fatigue resistance, abrasion resistance, chemical resistance, and moldability, they are widely used in constructing polymer articles, such as articles for use in the automotive industry and the electrical industry.\n\nThe mechanical properties of polyoxymethylene molding compositions are the reason for their use in numerous applications. To improve their properties, polyoxymethylene polymers are often provided with additives to adapt the properties for a specific application, for example by using reinforcing fibers or tribological modifiers. For instance, polyoxymethylene polymers have been combined with a tribological modifier for producing polymer compositions well suited for use in tribological applications where the polymer article is in moving contact with other articles, such as metal articles, plastic articles, and the like. These tribological applications can include embodiments where the polymer composition is formed into gear wheels, pulleys, sliding elements, and the like. The addition of a tribological modifier can provide a composition with a reduced coefficient of friction and low wear.\n\nIn the past, high molecular weight polyolefins have been used to improve the wear resistance of polyoxymethylene resins. For instance, U.S. Pat. No.",
  "cpc": [
    "C10M 107/38",
    "B29D 29/06",
    "B65G 17/40",
    "C08L 2205/03",
    "C08L 2205/035",
    "C08L 23/06",
    "C08L 23/30",
    "C08L 27/18",
    "C08L 59/02",
    "C08L 59/04",
    "C10M 2213/0623"
  ],
  "ipc": [
    "B29D 29/06",
    "B65G 17/40",
    "C08L 23/30",
    "C08L 27/18",
    "C08L 59/02",
    "C08L 59/04",
    "C10M 107/38"
  ],
  "assignees": [
    "Celanese Sales Germany GmbH"
  ],
  "inventors": [
    "Qamer Zia",
    "Kirsten Markgraf"
  ],
  "filing_date": "2020-01-17",
  "publication_date": "2022-08-09",
  "grant_date": "2022-08-09",
  "priority_date": "2016-10-11",
  "application_number": "US-202016746162-A",
  "family_id": "60269883",
  "cited_by_count": 0,
  "citations": [
    "EP0179668A2",
    "US4843115A",
    "JPH05247351A",
    "US5559180A",
    "EP0617085A1",
    "US5686176A",
    "US5973081A",
    "DE4445316A1",
    "US5641824A",
    "CN1177366A",
    "US5482987A",
    "US6025441A",
    "US6284828B1",
    "US6147146A",
    "US5962376A",
    "WO1999046331A1",
    "US6211268B1",
    "US6590020B1",
    "US6512047B2",
    "US6558428B2",
    "WO2000063291A1",
    "US8053499B2",
    "US7311489B2",
    "US6716248B2",
    "US20060052492A1",
    "US6974849B2",
    "US20070123617A1",
    "EP1522554A1",
    "US20070129484A1",
    "US20070073007A1",
    "US20090143506A1",
    "US8067493B2",
    "US8034866B2",
    "US20050143508A1",
    "US7772310B2",
    "US7625969B2",
    "US20060063863A1",
    "US7557154B2",
    "US9301845B2",
    "US7645821B2",
    "WO2007012469A1",
    "US20070105989A1",
    "US20090234050A1",
    "US7906594B2",
    "US7855238B2",
    "US7807745B2",
    "US7923506B2",
    "US7935737B2",
    "US7795320B2",
    "US8680167B2",
    "US8110609B2",
    "US7527859B2",
    "US20090143508A1",
    "US20110086952A1",
    "US20110184098A1",
    "JP2010189463A",
    "US9376558B2",
    "CN101575437A",
    "US8921471B2",
    "US9090770B2",
    "US20120277353A1",
    "US9296874B2",
    "US20130102718A1",
    "CN103946292A",
    "US20140329729A1",
    "US20130171430A1",
    "US8816015B2",
    "EP2712827A1",
    "US20150111796A1",
    "CN105793353A",
    "JP2015124056A",
    "CN104045965A",
    "US20160096196A1",
    "CN105175982A",
    "US20170258596A1",
    "US10166120B2",
    "US20190125548A1",
    "US20180100113A1",
    "US20180258278A1",
    "US20180291136A1",
    "US20190338116A1"
  ]
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