Patent · US11673975B2 · B2 · US
System and method for improving dump tank purge time
- (11) Publication number
- US11673975B2
- (21) Application number
- 17/409,958
- (22) Filing date
- 2021-08-24
- (30) Priority date
- 2021-08-24
- (43) Publication date
- 2023-06-13
- (45) Date of grant
- 2023-06-13
- (51) IPC
- B01J 19/24; B01J 4/00; B01J 8/00; C08F 10/02; C08F 2/00; C08F 2/01; C08F 2/14; C08F 6/10
- (52) CPC
- C08F Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds: 2/008, 10/00, 10/02, 2/01, 2/14, 6/10, 6/28
- B01J Chemical or physical processes, e.g. catalysis or colloid chemistry; their relevant apparatus: 19/2435, 2204/005, 2208/00761, 2208/00769, 2219/0004, 2219/00042, 2219/00162, 4/008, 8/0015, 8/006
- C10G Cracking hydrocarbon oils; production of liquid hydrocarbon mixtures, e.g. by destructive hydrogenation, oligomerisation, polymerisation; recovery of hydrocarbon oils from oil-shale, oil-sand, or gases; refining mixtures mainly consisting of hydrocarbons; reforming of naphtha; mineral waxes: 50/00
- (73) Assignee
- Chevron Phillips Chemical Co LP
- (72) Inventors
- Bradley T. PRICE; Jamie N. SUTHERLAND; Joseph A Curren; James E. Hein
- (54) Title
- System and method for improving dump tank purge time
- (57) Abstract
A system including a dump tank to receive a reactor product comprising a polymer and hydrocarbons, including liquid hydrocarbons, the dump tank including a vessel with a reactor product inlet, a motive gas inlet, a purge gas inlet, gas outlet(s), and a fluid outlet, the motive gas inlet for introducing a motive gas into the vessel, the purge gas inlet for introducing a purge gas into the vessel, the one or more gas outlets located at a top of the vessel and the fluid outlet located at a bottom of the vessel and fluidly connected with a dump tank fluid outlet line having a dump tank outlet valve to control flow of fluid out of the dump tank via the fluid outlet; and a strainer fluidly connected with the dump tank fluid outlet line to allow passage of liquid hydrocarbons therethrough into a hydrocarbon outlet line.
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Claims (20)
- A system comprising: a dump tank configured to receive a reactor product comprising a polymer and hydrocarbons, including liquid hydrocarbons, wherein the dump tank comprises a vessel having a reactor product inlet, a motive gas inlet, a purge gas inlet, one or more gas outlets, and a fluid outlet, wherein the motive gas inlet is configured to introduce a motive gas into an upper portion of the vessel, wherein the purge gas inlet is configured to introduce a purge gas into a lower portion of the vessel, wherein the one or more gas outlets are located at a top of the vessel, and wherein the fluid outlet is located at a bottom of the vessel and fluidly connected with a dump tank fluid outlet line having a dump tank outlet valve to control flow of fluid out of the dump tank via the fluid outlet; and a strainer, wherein the strainer is fluidly connected with the dump tank fluid outlet line and allows passage of liquid hydrocarbons therethrough into a hydrocarbon outlet line and prevents passage therethrough of particles having a retained particle size of greater than about 150 micrometers (μm).
- The system of claim 1 further comprising a filter downstream of the strainer and fluidly connected therewith via the hydrocarbon outlet line, wherein the filter prevents passage therethrough of particles having a particle size of greater than about 50 μm.
- The system of claim 1, wherein the motive gas comprises ethylene, ethane, nitrogen, fuel gas, methane, or a combination thereof.
- The system of claim 1, wherein the purge gas comprises nitrogen, fuel gas, cracker tail gas, methane, or a combination thereof.
- The system of claim 1 further comprising the reactor, wherein the reactor is upstream from the dump tank, and wherein the reactor is fluidly connected via a reactor product outlet line with the reactor product inlet of the dump tank, and, wherein the reactor comprises a polymerization reactor for the production of polyethylene.
- The system of claim 1 further comprising a motive gas valve configured to provide the motive gas to the motive gas inlet at a motive gas pressure, wherein the motive gas pressure is greater than a pressure of a downstream unit fluidly connected with the hydrocarbon outlet line and greater than a vapor pressure of the hydrocarbons in the dump tank, and provides a differential pressure across the strainer that is less than a maximum differential pressure rating of the strainer.
- A method comprising: introducing a polymer product from a polymerization reactor into a dump tank of a dump tank system comprising: a dump tank configured to receive a reactor product comprising a polymer and hydrocarbons, including liquid hydrocarbons, wherein the dump tank comprises a vessel having a reactor product inlet, a motive gas inlet, a purge gas inlet, one or more gas outlets, and a fluid outlet, wherein the motive gas inlet is configured to introduce a motive gas into an upper portion of the vessel, wherein the purge gas inlet is configured to introduce a purge gas into a lower portion of the vessel, wherein the one or more gas outlets are located at a top of the vessel, and wherein the fluid outlet is located at a bottom of the vessel and fluidly connected with a dump tank fluid outlet line having a dump tank outlet valve to control flow of fluid out of the dump tank via the fluid outlet; and a strainer, wherein the strainer is fluidly connected with the dump tank fluid outlet line and allows passage of liquid hydrocarbons therethrough into a hydrocarbon outlet line and prevents passage therethrough of particles having a retained particle size of greater than about 150 micrometers (μm); and draining liquid hydrocarbons from the dump tank by: opening the dump tank outlet valve on the dump tank fluid outlet line and introducing motive gas via the motive gas inlet, whereby fluid comprising liquid hydrocarbons and motive gas flows out the fluid outlet to the strainer, whereby the liquid hydrocarbons pass through the strainer to the hydrocarbon outlet line and particles having the particle size greater than the retained particle size are prevented passage through the strainer to the hydrocarbon outlet line; monitoring the hydrocarbon outlet line to determine when a majority of the liquid hydrocarbons have been removed from the vessel; and ceasing the introducing of the motive gas into the dump tank and closing the dump tank outlet valve.
- The method of claim 7, wherein the polymer product in the dump tank after introducing the polymer product from the reactor into the dump tank comprises a first amount of hydrocarbons, and wherein the polymer product in the dump tank after the majority of the liquid hydrocarbons have been removed from the vessel comprises a second amount of hydrocarbons, and wherein the second amount of hydrocarbons is less than or equal to about 30 weight percent (wt %) of the first amount of hydrocarbons.
- The method of claim 7, wherein the introducing of the motive gas via the motive gas inlet comprises introducing the motive gas via a motive gas valve configured to provide the motive gas to the motive gas inlet at a motive gas pressure, wherein the motive gas pressure is greater than a pressure of a downstream unit with which the hydrocarbon outlet line is fluidly connected, and provides a differential pressure across the strainer that is less than a maximum differential pressure rating of the strainer.
- The method of claim 9 further comprising flashing hydrocarbons from the dump tank by reducing the pressure of the dump tank from the motive gas pressure, whereby at least a portion of liquid hydrocarbons remaining in the polymer product evaporate to provide a flash gas, and extracting the flash gas via at least one of the one or more gas outlets of the vessel.
- The method of claim 10 further comprising purging the polymer product in the dump tank, wherein purging comprises introducing a purge gas into the vessel via the purge gas inlet, whereby a purged gas comprising hydrocarbons is produced, and extracting the purged gas from the vessel via at least one of the one or more gas outlets to provide a purged polymer product in the dump tank.
- The method of claim 11, wherein the purged polymer product comprises less than or equal to about 25 weight percent (wt %) of the hydrocarbons in the polymer product introduced into the dump tank from the polymerization reactor.
- The method of claim 11, wherein a time from introducing the polymer product into the dump tank to providing the purged polymer product is less than about 10 hours and/or less than about 15% of a time from introducing the polymer product into the dump tank to providing the purged polymer product obtained via a method excluding draining the liquid hydrocarbons from the dump tank.
- The method of claim 11 further comprising introducing the purged gas into a flare, an isobutane and nitrogen recovery unit (INRU), a flash gas system, or a combination thereof.
- The method of claim 10 further comprising introducing the flash gas into a flare, an isobutane and nitrogen recovery unit (INRU), a flash gas system, or a combination thereof.
- A method comprising: introducing a polymer product from a polymerization reactor into a dump tank, wherein the polymer product comprises a polymer and hydrocarbons, including liquid hydrocarbons, and wherein the dump tank comprises: a vessel having a reactor product inlet, a motive gas inlet, a purge gas inlet, one or more gas outlets, and a fluid outlet, wherein the motive gas inlet is configured to introduce a motive gas into an upper portion of the vessel, wherein the purge gas inlet is configured to introduce a purge gas into a lower portion of the vessel, wherein the one or more gas outlets are located at a top of the vessel, and wherein the fluid outlet is located at a bottom of the vessel and fluidly connected with a dump tank fluid outlet line having a dump tank outlet valve to control flow of fluid out of the dump tank via the fluid outlet, wherein the dump tank outlet valve is in a closed position during the introducing of the polymer product into the dump tank from the reactor; and draining liquid hydrocarbons from the dump tank by: opening the dump tank outlet valve on the fluid outlet line and introducing motive gas at a motive gas pressure via the motive gas inlet, whereby liquid hydrocarbons flow out the fluid outlet to a strainer, whereby the liquid hydrocarbons pass, as a strained liquid, through the strainer to a hydrocarbon outlet line and particles having the particle size greater than a retained particle size are prevented passage through the strainer to the hydrocarbon outlet line, wherein the strainer is fluidly connected with the fluid outlet line and has a strainer mesh size that allows passage of liquid hydrocarbons therethrough into the hydrocarbon outlet line and prevents passage therethrough of particles having a retained particle size of greater than about 150 micrometers (μm); and maintaining a pressure of the dump tank at a draining pressure of greater than a vapor pressure of the hydrocarbons in the polymer product until a majority of the liquid hydrocarbons have been removed from the vessel, such that a majority of the hydrocarbons remain liquid during the draining; and ceasing the introducing of the motive gas into the dump tank and closing the dump tank outlet valve.
- The method of claim 16 further comprising monitoring the hydrocarbon outlet line during the draining to determine when the majority of the liquid hydrocarbons have been removed from the vessel.
- The method of claim 16 further comprising: flashing hydrocarbons from the vessel by reducing the pressure of the dump tank from the draining pressure, whereby at least a portion of any liquid hydrocarbons remaining in the polymer product evaporate to provide a flash gas, and extracting the flash gas via at least one of the one or more gas outlets of the vessel.
- The method of claim 18 further comprising purging the polymer product in the dump tank, wherein purging comprises introducing the purge gas into the dump tank via the purge gas inlet, whereby a purged gas comprising hydrocarbons is produced, and extracting the purged gas from the dump tank via at least one of the one or more gas outlets to provide a purged polymer product in the dump tank.
- The method of claim 16, wherein draining further comprises passing the strained liquid through a filter, wherein the filter has a filter mesh size that is less than the strainer mesh size.
Description
Not applicable.
The disclosed apparatus, systems, and methods relate to transferring (e.g., “dumping”) the contents or inventory of one or more polymerization reactors to a relief vessel (e.g., a “dump” tank). More specifically, the disclosed apparatus, systems, and methods relate to improved dump tanks and methods of removing non-product components from a polymerization reactor inventory comprising polymer fluff transferred to a dump tank during a polymerization reactor dump. Still more specifically, the disclosed apparatus, systems, and methods relate to improved methods of removing non-product components of a polymerization reactor inventory transferred to a dump tank during a polymerization reactor dump via draining of non-product liquids through a strainer and optional subsequent filter.
During certain atypical operating situations within a polymerization unit, such as, without limitation, loss of utilities (e.g., power), loss of steam, loss of a circulation pump/circulation pump seal, loss of reactor outlets, or any other significant event where continuing to circulate or have polymer in a polymerization reactor is undesirable, there is a need to quickly divert, drain or empty the polymerization reactor (e.g., to “dump” the contents or “inventory” of the polymerization reactor). Polymerization units are typically equipped with dump tanks for this purpose.
In large units, the length of time necessary to remove residual hydrocarbons from the polymer fluff transferred to the dump tank (also referred to as a polymer bed) can be very long, sometimes longer than ten or more days.
Citations (13)
- US3356662A
- US5376742A
- US20020182121A1
- US6559247B2
- US6472483B1
- CN1302225C
- US8258245B2
- US7098301B1
- US8129486B2
- WO2010027912A1
- US7999044B2
- US20200354483A1
- WO2020227251A1
Record as JSON
{
"publication_number": "US11673975B2",
"country": "US",
"kind": "B2",
"title": "System and method for improving dump tank purge time",
"abstract": "A system including a dump tank to receive a reactor product comprising a polymer and hydrocarbons, including liquid hydrocarbons, the dump tank including a vessel with a reactor product inlet, a motive gas inlet, a purge gas inlet, gas outlet(s), and a fluid outlet, the motive gas inlet for introducing a motive gas into the vessel, the purge gas inlet for introducing a purge gas into the vessel, the one or more gas outlets located at a top of the vessel and the fluid outlet located at a bottom of the vessel and fluidly connected with a dump tank fluid outlet line having a dump tank outlet valve to control flow of fluid out of the dump tank via the fluid outlet; and a strainer fluidly connected with the dump tank fluid outlet line to allow passage of liquid hydrocarbons therethrough into a hydrocarbon outlet line.",
"claims": [
"1. A system comprising: a dump tank configured to receive a reactor product comprising a polymer and hydrocarbons, including liquid hydrocarbons, wherein the dump tank comprises a vessel having a reactor product inlet, a motive gas inlet, a purge gas inlet, one or more gas outlets, and a fluid outlet, wherein the motive gas inlet is configured to introduce a motive gas into an upper portion of the vessel, wherein the purge gas inlet is configured to introduce a purge gas into a lower portion of the vessel, wherein the one or more gas outlets are located at a top of the vessel, and wherein the fluid outlet is located at a bottom of the vessel and fluidly connected with a dump tank fluid outlet line having a dump tank outlet valve to control flow of fluid out of the dump tank via the fluid outlet; and a strainer, wherein the strainer is fluidly connected with the dump tank fluid outlet line and allows passage of liquid hydrocarbons therethrough into a hydrocarbon outlet line and prevents passage therethrough of particles having a retained particle size of greater than about 150 micrometers (μm).",
"2. The system of claim 1 further comprising a filter downstream of the strainer and fluidly connected therewith via the hydrocarbon outlet line, wherein the filter prevents passage therethrough of particles having a particle size of greater than about 50 μm.",
"3. The system of claim 1, wherein the motive gas comprises ethylene, ethane, nitrogen, fuel gas, methane, or a combination thereof.",
"4. The system of claim 1, wherein the purge gas comprises nitrogen, fuel gas, cracker tail gas, methane, or a combination thereof.",
"5. The system of claim 1 further comprising the reactor, wherein the reactor is upstream from the dump tank, and wherein the reactor is fluidly connected via a reactor product outlet line with the reactor product inlet of the dump tank, and, wherein the reactor comprises a polymerization reactor for the production of polyethylene.",
"6. The system of claim 1 further comprising a motive gas valve configured to provide the motive gas to the motive gas inlet at a motive gas pressure, wherein the motive gas pressure is greater than a pressure of a downstream unit fluidly connected with the hydrocarbon outlet line and greater than a vapor pressure of the hydrocarbons in the dump tank, and provides a differential pressure across the strainer that is less than a maximum differential pressure rating of the strainer.",
"7. A method comprising: introducing a polymer product from a polymerization reactor into a dump tank of a dump tank system comprising: a dump tank configured to receive a reactor product comprising a polymer and hydrocarbons, including liquid hydrocarbons, wherein the dump tank comprises a vessel having a reactor product inlet, a motive gas inlet, a purge gas inlet, one or more gas outlets, and a fluid outlet, wherein the motive gas inlet is configured to introduce a motive gas into an upper portion of the vessel, wherein the purge gas inlet is configured to introduce a purge gas into a lower portion of the vessel, wherein the one or more gas outlets are located at a top of the vessel, and wherein the fluid outlet is located at a bottom of the vessel and fluidly connected with a dump tank fluid outlet line having a dump tank outlet valve to control flow of fluid out of the dump tank via the fluid outlet; and a strainer, wherein the strainer is fluidly connected with the dump tank fluid outlet line and allows passage of liquid hydrocarbons therethrough into a hydrocarbon outlet line and prevents passage therethrough of particles having a retained particle size of greater than about 150 micrometers (μm); and draining liquid hydrocarbons from the dump tank by: opening the dump tank outlet valve on the dump tank fluid outlet line and introducing motive gas via the motive gas inlet, whereby fluid comprising liquid hydrocarbons and motive gas flows out the fluid outlet to the strainer, whereby the liquid hydrocarbons pass through the strainer to the hydrocarbon outlet line and particles having the particle size greater than the retained particle size are prevented passage through the strainer to the hydrocarbon outlet line; monitoring the hydrocarbon outlet line to determine when a majority of the liquid hydrocarbons have been removed from the vessel; and ceasing the introducing of the motive gas into the dump tank and closing the dump tank outlet valve.",
"8. The method of claim 7, wherein the polymer product in the dump tank after introducing the polymer product from the reactor into the dump tank comprises a first amount of hydrocarbons, and wherein the polymer product in the dump tank after the majority of the liquid hydrocarbons have been removed from the vessel comprises a second amount of hydrocarbons, and wherein the second amount of hydrocarbons is less than or equal to about 30 weight percent (wt %) of the first amount of hydrocarbons.",
"9. The method of claim 7, wherein the introducing of the motive gas via the motive gas inlet comprises introducing the motive gas via a motive gas valve configured to provide the motive gas to the motive gas inlet at a motive gas pressure, wherein the motive gas pressure is greater than a pressure of a downstream unit with which the hydrocarbon outlet line is fluidly connected, and provides a differential pressure across the strainer that is less than a maximum differential pressure rating of the strainer.",
"10. The method of claim 9 further comprising flashing hydrocarbons from the dump tank by reducing the pressure of the dump tank from the motive gas pressure, whereby at least a portion of liquid hydrocarbons remaining in the polymer product evaporate to provide a flash gas, and extracting the flash gas via at least one of the one or more gas outlets of the vessel.",
"11. The method of claim 10 further comprising purging the polymer product in the dump tank, wherein purging comprises introducing a purge gas into the vessel via the purge gas inlet, whereby a purged gas comprising hydrocarbons is produced, and extracting the purged gas from the vessel via at least one of the one or more gas outlets to provide a purged polymer product in the dump tank.",
"12. The method of claim 11, wherein the purged polymer product comprises less than or equal to about 25 weight percent (wt %) of the hydrocarbons in the polymer product introduced into the dump tank from the polymerization reactor.",
"13. The method of claim 11, wherein a time from introducing the polymer product into the dump tank to providing the purged polymer product is less than about 10 hours and/or less than about 15% of a time from introducing the polymer product into the dump tank to providing the purged polymer product obtained via a method excluding draining the liquid hydrocarbons from the dump tank.",
"14. The method of claim 11 further comprising introducing the purged gas into a flare, an isobutane and nitrogen recovery unit (INRU), a flash gas system, or a combination thereof.",
"15. The method of claim 10 further comprising introducing the flash gas into a flare, an isobutane and nitrogen recovery unit (INRU), a flash gas system, or a combination thereof.",
"16. A method comprising: introducing a polymer product from a polymerization reactor into a dump tank, wherein the polymer product comprises a polymer and hydrocarbons, including liquid hydrocarbons, and wherein the dump tank comprises: a vessel having a reactor product inlet, a motive gas inlet, a purge gas inlet, one or more gas outlets, and a fluid outlet, wherein the motive gas inlet is configured to introduce a motive gas into an upper portion of the vessel, wherein the purge gas inlet is configured to introduce a purge gas into a lower portion of the vessel, wherein the one or more gas outlets are located at a top of the vessel, and wherein the fluid outlet is located at a bottom of the vessel and fluidly connected with a dump tank fluid outlet line having a dump tank outlet valve to control flow of fluid out of the dump tank via the fluid outlet, wherein the dump tank outlet valve is in a closed position during the introducing of the polymer product into the dump tank from the reactor; and draining liquid hydrocarbons from the dump tank by: opening the dump tank outlet valve on the fluid outlet line and introducing motive gas at a motive gas pressure via the motive gas inlet, whereby liquid hydrocarbons flow out the fluid outlet to a strainer, whereby the liquid hydrocarbons pass, as a strained liquid, through the strainer to a hydrocarbon outlet line and particles having the particle size greater than a retained particle size are prevented passage through the strainer to the hydrocarbon outlet line, wherein the strainer is fluidly connected with the fluid outlet line and has a strainer mesh size that allows passage of liquid hydrocarbons therethrough into the hydrocarbon outlet line and prevents passage therethrough of particles having a retained particle size of greater than about 150 micrometers (μm); and maintaining a pressure of the dump tank at a draining pressure of greater than a vapor pressure of the hydrocarbons in the polymer product until a majority of the liquid hydrocarbons have been removed from the vessel, such that a majority of the hydrocarbons remain liquid during the draining; and ceasing the introducing of the motive gas into the dump tank and closing the dump tank outlet valve.",
"17. The method of claim 16 further comprising monitoring the hydrocarbon outlet line during the draining to determine when the majority of the liquid hydrocarbons have been removed from the vessel.",
"18. The method of claim 16 further comprising: flashing hydrocarbons from the vessel by reducing the pressure of the dump tank from the draining pressure, whereby at least a portion of any liquid hydrocarbons remaining in the polymer product evaporate to provide a flash gas, and extracting the flash gas via at least one of the one or more gas outlets of the vessel.",
"19. The method of claim 18 further comprising purging the polymer product in the dump tank, wherein purging comprises introducing the purge gas into the dump tank via the purge gas inlet, whereby a purged gas comprising hydrocarbons is produced, and extracting the purged gas from the dump tank via at least one of the one or more gas outlets to provide a purged polymer product in the dump tank.",
"20. The method of claim 16, wherein draining further comprises passing the strained liquid through a filter, wherein the filter has a filter mesh size that is less than the strainer mesh size."
],
"description_excerpt": "None.\n\nNot applicable.\n\nThe disclosed apparatus, systems, and methods relate to transferring (e.g., “dumping”) the contents or inventory of one or more polymerization reactors to a relief vessel (e.g., a “dump” tank). More specifically, the disclosed apparatus, systems, and methods relate to improved dump tanks and methods of removing non-product components from a polymerization reactor inventory comprising polymer fluff transferred to a dump tank during a polymerization reactor dump. Still more specifically, the disclosed apparatus, systems, and methods relate to improved methods of removing non-product components of a polymerization reactor inventory transferred to a dump tank during a polymerization reactor dump via draining of non-product liquids through a strainer and optional subsequent filter.\n\nDuring certain atypical operating situations within a polymerization unit, such as, without limitation, loss of utilities (e.g., power), loss of steam, loss of a circulation pump/circulation pump seal, loss of reactor outlets, or any other significant event where continuing to circulate or have polymer in a polymerization reactor is undesirable, there is a need to quickly divert, drain or empty the polymerization reactor (e.g., to “dump” the contents or “inventory” of the polymerization reactor). Polymerization units are typically equipped with dump tanks for this purpose.\n\nIn large units, the length of time necessary to remove residual hydrocarbons from the polymer fluff transferred to the dump tank (also referred to as a polymer bed) can be very long, sometimes longer than ten or more days.",
"cpc": [
"C08F 2/008",
"B01J 19/2435",
"B01J 2204/005",
"B01J 2208/00761",
"B01J 2208/00769",
"B01J 2219/0004",
"B01J 2219/00042",
"B01J 2219/00162",
"B01J 4/008",
"B01J 8/0015",
"B01J 8/006",
"C08F 10/00",
"C08F 10/02",
"C08F 2/01",
"C08F 2/14",
"C08F 6/10",
"C08F 6/28",
"C10G 50/00"
],
"ipc": [
"B01J 19/24",
"B01J 4/00",
"B01J 8/00",
"C08F 10/02",
"C08F 2/00",
"C08F 2/01",
"C08F 2/14",
"C08F 6/10"
],
"assignees": [
"Chevron Phillips Chemical Co LP"
],
"inventors": [
"Bradley T. PRICE",
"Jamie N. SUTHERLAND",
"Joseph A Curren",
"James E. Hein"
],
"filing_date": "2021-08-24",
"publication_date": "2023-06-13",
"grant_date": "2023-06-13",
"priority_date": "2021-08-24",
"application_number": "US-202117409958-A",
"family_id": "83228700",
"cited_by_count": 2,
"citations": [
"US3356662A",
"US5376742A",
"US20020182121A1",
"US6559247B2",
"US6472483B1",
"CN1302225C",
"US8258245B2",
"US7098301B1",
"US8129486B2",
"WO2010027912A1",
"US7999044B2",
"US20200354483A1",
"WO2020227251A1"
]
}
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