Closed loop recycle of vent gas in polymerization process

{
  "publication_number": "US4666998A",
  "country": "US",
  "kind": "A",
  "title": "Closed loop recycle of vent gas in polymerization process",
  "abstract": "A fluidized bed olefin polymerization process incorporates a recycle of a vent gas, containing unreacted monomers, from the product purge bin vessel to the polymerization reactor. The recycle of the vent gas minimizes the loss of the unpolymerized reactants, thereby decreasing overall process and product costs.",
  "claims": [
    "1. In a vapor phase, fluidized bed process for polymerizing at least one C 2 to C 10 alpha-olefin comprising: polymerizing the alpha-olefin in a fluidized bed reactor means having a stream of a substantially pure inert gas introduced thereinto to maintain the required operating pressure in the reactor means; recovering the polymerized alpha-olefin product from the fluidized bed reactor means into a product discharge system; conveying the product from the product discharge system to a purge vessel means wherein the product is contacted with a substantially pure inert purge gas to separate unreacted alpha-olefin from the product; and, removing a vent gas from the purge vessel means; an improvement comprising: (a) eliminating the introduction of the stream of a substantially pure inert gas into the fluidized bed reactor means; (b) recycling the vent gas, without a concentration or purification treatment thereof, to the fluidized bed reactor means, the recycled vent gas comprising a significant amount of the unreacted alpha-olefin; and (c) removing a reactor vent gas stream from the fluidized bed reactor means.",
    "2. A process of claim 1 wherein the product discharge system comprises a product vessel means followed by a blow tank means, and wherein the product recovered from the fluidized bed reactor means is first conducted to the product vessel means and subsequently to the blow tank means.",
    "3. A process of claim 1 wherein the vent gas recycled to the fluidized bed reactor means, after its removal from the purge vessel means, is separated into a first gas stream, conducted to the fluidized bed reactor means, and a second gas stream, conducted to the blow tank means, downstream of the fluidized bed reactor means.",
    "4. A process of claim 3 wherein the first gas stream comprises 20% to 80% by volume of the vent gas removed from the purge vessel means.",
    "5. A process of claim 3 wherein the pressure of the vent gas from the purge vessel means is increased to about 350 to about 450 psig, after the vent gas is removed from the purge vessel means.",
    "6. A process of claim 5 wherein the inert purge gas is nitrogen or helium.",
    "7. A process of claim 6 wherein the second gas stream is conducted to a surge tank means, upstream of its point of introduction into the blow tank means.",
    "8. A process of claim 7 wherein a linear low density copolymer of ethylene with one or more C 3 -C 10 alpha-olefins is produced.",
    "9. A process of claim 8 wherein the C 3 -C 10 alphaolefin is 1-hexene.",
    "10. A process of claim 9 wherein the reactor vent gas removed from the fluidized bed reactor means comprises about 7% to 45% by volume of ethylene and about 0.3% to 6.0 % by volume of 1-hexene.",
    "11. A process of claim 3 wherein a portion of the vent gas is removed from the process through an auxiliary vent system and the remainder thereof is separated into the first gas stream and the second gas stream.",
    "12. A process of claim 4 wherein the first gas stream comprises 30% to 50% by volume of the vent gas removed from the purge vessel means.",
    "13. In a vapor phase, fluidized bed process for polymerizing at least one C 2 to C 10 alpha-olefin comprising: polymerizing the alpha-olefin in a fluidized bed reactor means having a stream of a substantially pure inert gas introduced thereinto to maintain the required operating pressure in the reactor means; recovering the polymerized alpha-olefin product from the fluidized bed reactor means into a product discharge system; conveying the product from the product discharge system to a purge vessel means wherein the product is contacted with a substantially pure inert purge gas to separate unreacted alpha-olefin from the product; and, removing a vent gas from the purge vessel means; an improvement comprising (a) eliminating the introduction of the stream of a substantially pure inert gas into the fluidized bed reactor means; (b) conducting the vent gas, comprising a significant amount of the unreacted alphs-olefin, to a condenser means to preferentially condense heavy hydrocarbons; (c) recycling the thus-produced condensed heavy hydrocarbons and at least a portion of uncondensed components to the fluidized bed reactor means; and (d) removing a reactor vent gas stream from the fluidized bed reactor means.",
    "14. A process of claim 13 wherein the remainder of the uncondensed components is conducted to a vent gas means downstream of the purge vessel means.",
    "15. A process of claim 14 wherein the condensed heavy hydrocarbons comprise 1-hexene.",
    "16. A process of claim 1 wherein the product discharge system comprises a product vessel means followed by a blow tank means, and wherein the product recovered from the fluidized bed reactor means is first conducted to the product vessel means and subsequently to the blow tank means."
  ],
  "description_excerpt": "This is a continuation of copending application Ser. No. 687,878, filed on Dec. 31, 1984, now abandoned.\n\n1. Field of the Invention\n\nThis invention relates to a method for polymerizing alpha-olefins. More particularly, the invention relates to an improved method of polymerizing alpha-olefins to produce, preferably, linear low density polyethylene and polypropylene, wherein the loss of monomers experienced in prior art processes is greatly reduced.\n\n2. Description of the Prior Art\n\nPolymers and copolymers of C 2 -C 10 olefins, particularly copolymers of ethylene and higher alpha-olefins, have in recent years been produced in gas phase, fluid bed reactors. Karol et al, U.S. Pat. No. 4,302,566, describe a gas phase, fluid bed reactor for producing linear low density polyethylene polymers. Graff, U.S. Pat. No. 4,173,547, Stevens et al, U.S. Pat. No. 3,787,384, Strobel et al, U.S. Pat. No. 4,148,754 and Ziegler, deceased, et al, U.S. Pat. No. 4,063,009, describe various polymerization processes which produce polyethylene other than linear low density polyethylene.\n\nNowlin et al, U.S. Pat. No. 4,481,301, the entire contents of which are incorporated herein by reference, teach the preparation of a highly active alpha-olefin polymerization catalyst comprising contacting a support material, e.g., silica, containing reactive OH groups with a stoichiometric excess of an organomagnesium composition, and subsequently reacting the product with a tetravalent titanium compound.\n\nBobst et al, U.S. Pat. No.",
  "cpc": [
    "B01J 8/003",
    "B01J 2208/00761",
    "B01J 8/24",
    "C08F 10/00"
  ],
  "ipc": [
    "B01J 8/00",
    "B01J 8/24",
    "C08F 10/00",
    "C08F 2/34"
  ],
  "assignees": [
    "Mobil Oil AS"
  ],
  "inventors": [
    "Robert O. Hagerty"
  ],
  "filing_date": "1986-05-09",
  "publication_date": "1987-05-19",
  "grant_date": "1987-05-19",
  "priority_date": "1984-12-31",
  "application_number": "US-86216386-A",
  "family_id": "27104105",
  "cited_by_count": 17,
  "citations": [
    "US3256263A",
    "US3488339A",
    "GB1226659A",
    "US3595840A",
    "US4340701A",
    "US4372758A",
    "US4481301A",
    "EP0089691A2",
    "US4469855A",
    "EP0100550A1"
  ]
}