Basecoat for a coating system

{
  "publication_number": "US5468798A",
  "country": "US",
  "kind": "A",
  "title": "Basecoat for a coating system",
  "abstract": "A basecoat for a nonstick coating system wherein the basecoat comprises a high temperature binder resin, preferably polyamideimide resin, and a filamentary powder, preferably a nickel powder, which is combined with the high temperature binder to yield a spongelike coating which with appropriate application has a rough surface and an internal structure containing interlocking channels. These channels may be impregnated by subsequently applied coatings, especially nonstick fluoropolymer coatings.",
  "claims": [
    "1. A basecoat for a coating system, comprising: a high temperature polymer resin of sufficient binding capacity to adhere to a substrate; and a filamentary powder dispersed throughout said polymer resin to form an adhesive mixture which with appropriate application to a suitable substrate results in the basecoat having an internal spongelike structure and a rough top surface including a plurality of filaments projecting up from said polymer resin and capable of anchoring at least one finish coat to the basecoat.",
    "2. The basecoat of claim 1, wherein said high temperature polymer resin is a polyamideimide resin.",
    "3. The basecoat of claim 1, wherein said filamentary powder is a nonferrous metal.",
    "4. The basecoat of claim 3, wherein said filamentary powder is a filamentary nickel powder.",
    "5. The basecoat of claim 2, wherein said filamentary powder is a filamentary nickel powder.",
    "6. The basecoat of claim 5, wherein said nickel powder is present in said mixture from 15% to 40% of the total dry volume of said mixture.",
    "7. The basecoat of claim 5, wherein said nickel powder constitutes about 22.4 weight percent of said mixture.",
    "8. A basecoat for a nonstick coating composition, comprising: a high temperature polymer resin of sufficient binding capacity to adhere to a substrate; and a filamentary powder dispersed throughout said polymer resin to form an adhesive mixture which with appropriate application to a suitable substrate results in the basecoat having an internal spongelike structure and a rough top surface including a plurality of filaments projecting up from said polymer resin and capable of anchoring at least one fluoropolymer coating to the basecoat.",
    "9. The basecoat of claim 8, wherein said high temperature polymer resin is a polyamideimide resin.",
    "10. The basecoat of claim 8, wherein said filamentary powder is a nonferrous metal.",
    "11. The basecoat of claim 10, wherein said filamentary powder is a filamentary nickel powder.",
    "12. The basecoat of claim 9, wherein said filamentary powder is a filamentary nickel powder.",
    "13. The basecoat of claim 12, wherein said nickel powder is present in said mixture from 15% to 40% of the total dry volume of said mixture.",
    "14. The basecoat of claim 12, wherein said nickel powder constitutes about 22.4 weight percent of said mixture.",
    "15. A method of forming a basecoat for securing a nonstick coating to a substrate, the method comprising the steps of: dissolving a polyamideimide (PAI) resin in N-methyl pyrrolidone (NMP) to form a solution; adding a surfactant and water to the solution and agitating to form a dispersion in which the PAI resin is precipitated into small curds; and adding a filamentary metal powder to the dispersion and agitating until a homogeneous mixture is achieved.",
    "16. The method of claim 15, including the step of grinding the small curds to further reduce the size of the curds before the step of adding the filamentary powder.",
    "17. The method of claim 15, including the step of adding carbon black to the dispersion."
  ],
  "description_excerpt": "The present invention relates generally to adhesive compositions for securing a coating, such as a nonstick coating, to a substrate and, more particularly, to an adhesive composition or basecoat that can be applied directly onto either a treated or untreated substrate to secure one or more coatings to the substrate.\n\nFluoropolymer resins such as polytetrafluoroethylene resins (PTFE), fluorinated ethylene propylene resins (FEP), perfluoroalkoxy resins (PFA), or combinations thereof are known to have superior nonstick properties. Therefore, such resins are used in a variety of industries, including the cookware industry to minimize the sticking of food particles to the cookware. Due to the nonstick nature of fluoropolymer resins, there have been difficulties in making the coatings adhere well to the substrate.\n\nConventionally, adhesive resins or basecoats have been used in order to better adhere the fluoropolymer topcoat to the substrate. In general, such basecoats are a combination of a high temperature binder resin such as polyamideimide resins (PAI), polyethersulfone resins (PES) or polyphenylene sulfide resins (PPS) with a fluoropolymer resin. The performance of these basecoats depends upon a stratification of the applied coating. This stratification has resulted in a coating rich in high temperature binder on the bottom and rich in fluoropolymer at the top. The binder-rich bottom provides adhesion to the substrate while the fluoropolymer-rich top provides a layer to which subsequent fluoropolymer topcoats could be fused by sintering at high temperature.",
  "cpc": [
    "C09D 179/08",
    "C08K 7/06",
    "Y10T 428/24355",
    "Y10T 428/256",
    "Y10T 428/3154",
    "Y10T 428/31544",
    "Y10T 428/31721",
    "Y10T 428/31725"
  ],
  "ipc": [
    "C08K 7/06",
    "C09D 179/08"
  ],
  "assignees": [
    "Whitford Corp"
  ],
  "inventors": [
    "Lawrence D. Leech"
  ],
  "filing_date": "1994-02-18",
  "publication_date": "1995-11-21",
  "grant_date": "1995-11-21",
  "priority_date": "1994-02-18",
  "application_number": "US-19844594-A",
  "family_id": "22733415",
  "cited_by_count": 38,
  "citations": [
    "US3860559A",
    "US4049863A",
    "US4098756A",
    "US4377652A",
    "US4353950A",
    "JPS5853966A",
    "JPS604569A",
    "US5049295A",
    "US5106682A",
    "US5049437A",
    "US5071695A",
    "US5079073A",
    "WO1992010549A1",
    "US5296183A",
    "US5250356A"
  ]
}