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Patent · US6166117A · A · US

Water-soluble film

(11) Publication number
US6166117A
(21) Application number
US-9450698-A
(22) Filing date
1998-06-10
(30) Priority date
1997-06-11
(43) Publication date
2000-12-26
(45) Date of grant
2000-12-26
(52) CPC
  • C08K Use of inorganic or non-macromolecular organic substances as compounding ingredients: 5/13, 5/09, 5/1345
  • B65D Containers for storage or transport of articles or materials, e.g. bags, barrels, bottles, boxes, cans, cartons, crates, drums, jars, tanks, hoppers, forwarding containers; accessories, closures, or fittings therefor; packaging elements; packages: 65/46
  • C08F Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds: 8/00
  • C08J Working-up; general processes of compounding; after-treatment not covered by subclasses C08B, C08C, C08F, C08G or C08H: 2329/04, 5/18
  • C11D Detergent compositions; use of single substances as detergents; soap or soap-making; resin soaps; recovery of glycerol: 17/0047, 17/0056, 17/044, 3/3955
(73) Assignee
KURARAY CO
(54) Title
Water-soluble film
(57) Abstract

A water-soluble film, comprising 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.05-20 parts by weight of (B) gallic acid, salts thereof or a C 1-5 alkyl ester thereof.

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Claims (12)

  1. A water-soluble film, comprising: 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.50-20 parts by weight of (B) gallic acid, its salts or a C 1-5 alkyl ester thereof.
  2. The water-soluble film of claim 1, wherein said gallic acid ester is the methyl, ethyl, propyl or isoamyl ester.
  3. The water-soluble film of claim 1, wherein the amount of gallic acid or a C 1-5 -alkyl ester thereof ranges form 0.2-10 parts by weight.
  4. The water-soluble film of claim 1, wherein the content of the sulfonic acid group unit in the polyvinyl alcohol ranges form 0.1-20 mol. %.
  5. The water-soluble film of claim 4, wherein the content of the sulfonic acid group unit ranges from 0.5-10 mol. %.
  6. The water-soluble film of claim 1, wherein the polyvinyl alcohol is prepared from a sulfonic acid group containing monomer selected from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, 2-methacrylamido-2-methylpropanesulfonic acid, salts thereof and olefin sulfonic acids.
  7. The water-soluble film of claim 1, wherein the degree of hydrolysis of the polyvinyl alcohol ranges form 50-100 mol. %.
  8. The water-soluble film of claim 7, wherein said degree of hydrolysis ranges from 80-100 mol. %.
  9. The water-soluble film of claim 1, wherein the sulfonic acid group modified polyvinyl alcohol is prepared by the copolymerization of a vinyl ester a sulfonic acid group containing a monomer.
  10. The water-soluble film of claim 9, wherein the polyvinyl alcohol is prepared by the reaction of a sulfonic acid containing compound with polyvinyl alcohol.
  11. The water-soluble film of claim 1, wherein the polyvinyl alcohol is prepared by the reaction of a sulfonic acid containing compound with polyvinyl alcohol.
  12. A composition, comprising: 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.05-20 parts by weight of (B) gallic acid, salts thereof or a C 1-5 alkyl ester thereof.

Citations (11)

  • EP0259037A2
  • JPH07118407A
  • JPH09316270A
  • JPS5324351A
  • US4156047A
  • US4221710A
  • US4753947A
  • US4833116A
  • US4910185A
  • US4954477A
  • US5677365A
Record as JSON
{
  "publication_number": "US6166117A",
  "country": "US",
  "kind": "A",
  "title": "Water-soluble film",
  "abstract": "A water-soluble film, comprising 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.05-20 parts by weight of (B) gallic acid, salts thereof or a C 1-5 alkyl ester thereof.",
  "claims": [
    "1. A water-soluble film, comprising: 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.50-20 parts by weight of (B) gallic acid, its salts or a C 1-5 alkyl ester thereof.",
    "2. The water-soluble film of claim 1, wherein said gallic acid ester is the methyl, ethyl, propyl or isoamyl ester.",
    "3. The water-soluble film of claim 1, wherein the amount of gallic acid or a C 1-5 -alkyl ester thereof ranges form 0.2-10 parts by weight.",
    "4. The water-soluble film of claim 1, wherein the content of the sulfonic acid group unit in the polyvinyl alcohol ranges form 0.1-20 mol. %.",
    "5. The water-soluble film of claim 4, wherein the content of the sulfonic acid group unit ranges from 0.5-10 mol. %.",
    "6. The water-soluble film of claim 1, wherein the polyvinyl alcohol is prepared from a sulfonic acid group containing monomer selected from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, 2-methacrylamido-2-methylpropanesulfonic acid, salts thereof and olefin sulfonic acids.",
    "7. The water-soluble film of claim 1, wherein the degree of hydrolysis of the polyvinyl alcohol ranges form 50-100 mol. %.",
    "8. The water-soluble film of claim 7, wherein said degree of hydrolysis ranges from 80-100 mol. %.",
    "9. The water-soluble film of claim 1, wherein the sulfonic acid group modified polyvinyl alcohol is prepared by the copolymerization of a vinyl ester a sulfonic acid group containing a monomer.",
    "10. The water-soluble film of claim 9, wherein the polyvinyl alcohol is prepared by the reaction of a sulfonic acid containing compound with polyvinyl alcohol.",
    "11. The water-soluble film of claim 1, wherein the polyvinyl alcohol is prepared by the reaction of a sulfonic acid containing compound with polyvinyl alcohol.",
    "12. A composition, comprising: 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.05-20 parts by weight of (B) gallic acid, salts thereof or a C 1-5 alkyl ester thereof."
  ],
  "cpc": [
    "C08K 5/13",
    "B65D 65/46",
    "C08F 8/00",
    "C08J 2329/04",
    "C08J 5/18",
    "C08K 5/09",
    "C08K 5/1345",
    "C11D 17/0047",
    "C11D 17/0056",
    "C11D 17/044",
    "C11D 3/3955"
  ],
  "assignees": [
    "KURARAY CO"
  ],
  "filing_date": "1998-06-10",
  "publication_date": "2000-12-26",
  "grant_date": "2000-12-26",
  "priority_date": "1997-06-11",
  "application_number": "US-9450698-A",
  "family_id": "26481921",
  "citations": [
    "EP0259037A2",
    "JPH07118407A",
    "JPH09316270A",
    "JPS5324351A",
    "US4156047A",
    "US4221710A",
    "US4753947A",
    "US4833116A",
    "US4910185A",
    "US4954477A",
    "US5677365A"
  ]
}

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