Patent · US6166117A · A · US
Water-soluble film
- (11) Publication number
- US6166117A
- (21) Application number
- US-9450698-A
- (22) Filing date
- 1998-06-10
- (30) Priority date
- 1997-06-11
- (43) Publication date
- 2000-12-26
- (45) Date of grant
- 2000-12-26
- (52) CPC
- C08K Use of inorganic or non-macromolecular organic substances as compounding ingredients: 5/13, 5/09, 5/1345
- B65D Containers for storage or transport of articles or materials, e.g. bags, barrels, bottles, boxes, cans, cartons, crates, drums, jars, tanks, hoppers, forwarding containers; accessories, closures, or fittings therefor; packaging elements; packages: 65/46
- C08F Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds: 8/00
- C08J Working-up; general processes of compounding; after-treatment not covered by subclasses C08B, C08C, C08F, C08G or C08H: 2329/04, 5/18
- C11D Detergent compositions; use of single substances as detergents; soap or soap-making; resin soaps; recovery of glycerol: 17/0047, 17/0056, 17/044, 3/3955
- (73) Assignee
- KURARAY CO
- (54) Title
- Water-soluble film
- (57) Abstract
A water-soluble film, comprising 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.05-20 parts by weight of (B) gallic acid, salts thereof or a C 1-5 alkyl ester thereof.
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Claims (12)
- A water-soluble film, comprising: 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.50-20 parts by weight of (B) gallic acid, its salts or a C 1-5 alkyl ester thereof.
- The water-soluble film of claim 1, wherein said gallic acid ester is the methyl, ethyl, propyl or isoamyl ester.
- The water-soluble film of claim 1, wherein the amount of gallic acid or a C 1-5 -alkyl ester thereof ranges form 0.2-10 parts by weight.
- The water-soluble film of claim 1, wherein the content of the sulfonic acid group unit in the polyvinyl alcohol ranges form 0.1-20 mol. %.
- The water-soluble film of claim 4, wherein the content of the sulfonic acid group unit ranges from 0.5-10 mol. %.
- The water-soluble film of claim 1, wherein the polyvinyl alcohol is prepared from a sulfonic acid group containing monomer selected from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, 2-methacrylamido-2-methylpropanesulfonic acid, salts thereof and olefin sulfonic acids.
- The water-soluble film of claim 1, wherein the degree of hydrolysis of the polyvinyl alcohol ranges form 50-100 mol. %.
- The water-soluble film of claim 7, wherein said degree of hydrolysis ranges from 80-100 mol. %.
- The water-soluble film of claim 1, wherein the sulfonic acid group modified polyvinyl alcohol is prepared by the copolymerization of a vinyl ester a sulfonic acid group containing a monomer.
- The water-soluble film of claim 9, wherein the polyvinyl alcohol is prepared by the reaction of a sulfonic acid containing compound with polyvinyl alcohol.
- The water-soluble film of claim 1, wherein the polyvinyl alcohol is prepared by the reaction of a sulfonic acid containing compound with polyvinyl alcohol.
- A composition, comprising: 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.05-20 parts by weight of (B) gallic acid, salts thereof or a C 1-5 alkyl ester thereof.
Citations (11)
- EP0259037A2
- JPH07118407A
- JPH09316270A
- JPS5324351A
- US4156047A
- US4221710A
- US4753947A
- US4833116A
- US4910185A
- US4954477A
- US5677365A
Record as JSON
{
"publication_number": "US6166117A",
"country": "US",
"kind": "A",
"title": "Water-soluble film",
"abstract": "A water-soluble film, comprising 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.05-20 parts by weight of (B) gallic acid, salts thereof or a C 1-5 alkyl ester thereof.",
"claims": [
"1. A water-soluble film, comprising: 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.50-20 parts by weight of (B) gallic acid, its salts or a C 1-5 alkyl ester thereof.",
"2. The water-soluble film of claim 1, wherein said gallic acid ester is the methyl, ethyl, propyl or isoamyl ester.",
"3. The water-soluble film of claim 1, wherein the amount of gallic acid or a C 1-5 -alkyl ester thereof ranges form 0.2-10 parts by weight.",
"4. The water-soluble film of claim 1, wherein the content of the sulfonic acid group unit in the polyvinyl alcohol ranges form 0.1-20 mol. %.",
"5. The water-soluble film of claim 4, wherein the content of the sulfonic acid group unit ranges from 0.5-10 mol. %.",
"6. The water-soluble film of claim 1, wherein the polyvinyl alcohol is prepared from a sulfonic acid group containing monomer selected from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, 2-methacrylamido-2-methylpropanesulfonic acid, salts thereof and olefin sulfonic acids.",
"7. The water-soluble film of claim 1, wherein the degree of hydrolysis of the polyvinyl alcohol ranges form 50-100 mol. %.",
"8. The water-soluble film of claim 7, wherein said degree of hydrolysis ranges from 80-100 mol. %.",
"9. The water-soluble film of claim 1, wherein the sulfonic acid group modified polyvinyl alcohol is prepared by the copolymerization of a vinyl ester a sulfonic acid group containing a monomer.",
"10. The water-soluble film of claim 9, wherein the polyvinyl alcohol is prepared by the reaction of a sulfonic acid containing compound with polyvinyl alcohol.",
"11. The water-soluble film of claim 1, wherein the polyvinyl alcohol is prepared by the reaction of a sulfonic acid containing compound with polyvinyl alcohol.",
"12. A composition, comprising: 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.05-20 parts by weight of (B) gallic acid, salts thereof or a C 1-5 alkyl ester thereof."
],
"cpc": [
"C08K 5/13",
"B65D 65/46",
"C08F 8/00",
"C08J 2329/04",
"C08J 5/18",
"C08K 5/09",
"C08K 5/1345",
"C11D 17/0047",
"C11D 17/0056",
"C11D 17/044",
"C11D 3/3955"
],
"assignees": [
"KURARAY CO"
],
"filing_date": "1998-06-10",
"publication_date": "2000-12-26",
"grant_date": "2000-12-26",
"priority_date": "1997-06-11",
"application_number": "US-9450698-A",
"family_id": "26481921",
"citations": [
"EP0259037A2",
"JPH07118407A",
"JPH09316270A",
"JPS5324351A",
"US4156047A",
"US4221710A",
"US4753947A",
"US4833116A",
"US4910185A",
"US4954477A",
"US5677365A"
]
}
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