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Patent · US9453085B2 · B2 · US

Initiator composition for curing resin

(11) Publication number
US9453085B2
(21) Application number
14/492,066
(22) Filing date
2014-09-21
(30) Priority date
2012-04-19
(43) Publication date
2016-09-27
(45) Date of grant
2016-09-27
(52) CPC
  • C08F Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds: 4/34, 299/045, 4/38
  • C08G Macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds: 63/91
(73) Assignee
WUHAN KEDA MARBLE PROTECTIVE MAT CO LTD
(54) Title
Initiator composition for curing resin
(57) Abstract

An initiator composition, including at least two compounds represented by the chemical formula R - CO - O - O - CO - R and a compound represented by R 1 - O - O - R 2, where R represents a C 2 -C 12 alkyl or a C 6 -C 10 aryl or substituted aryl, and R 1 and R 2 independently, at each occurrence, represent a C 1 -C 10 alkyl or a C 6 -C 10 aryl.

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Claims (6)

  1. An initiator composition, comprising 75 parts by weight of at least two first peroxides and 25 parts by weight of a second peroxide, wherein the at least two first peroxides comprise 25 parts by weight of benzoyl peroxide, 30 parts by weight of 2,4-dichlorobenzene acyl peroxide, and 20 parts by weight of lauroyl peroxide, and the second peroxide is di-t-butyl peroxide.
  2. An initiator composition, comprising 95 parts by weight of at least two first peroxides and 5 parts by weight of a second peroxide, wherein the at least two first peroxides comprise 35 parts by weight of benzoyl peroxide, 40 parts by weight of 2,4-dichlorobenzene acyl peroxide, 10 parts by weight of lauroyl peroxide, and 10 parts by weight of diacetyl peroxide, and the second peroxide is t-butyl cumyl peroxide.
  3. An initiator composition, comprising 90 parts by weight of at least two first peroxides and 10 parts by weight of a second peroxide, wherein the at least two first peroxides comprise 40 parts by weight of benzoyl peroxide and 50 parts by weight of 2,4-dichlorobenzene acyl peroxide, and the second peroxide is dicumyl peroxide.
  4. An initiator composition for expediting curing of an unsaturated polyester resin at room temperature, the initiator composition comprising: at least two first peroxides selected from the group consisting of benzoyl peroxide, 2,4-dichlorobenzene acyl peroxide, lauroyl peroxide, and diacetyl peroxide; a second peroxide selected from the group consisting of dicumyl peroxide, di-t-butyl peroxide, and t-butyl cumyl peroxide; and a carboxylic ester peroxide selected from the group consisting of tert-butyl peroxybenzoate (TBPB), tert-butyl peroxy diethyl acetate, t-butyl peroctoate (TBPO); wherein: the initiator composition comprises between 70 and 85 parts by weight of the at least two first peroxides, between 5 and 15 parts by weight of the second peroxide, and between 5 and 15 parts by weight of the carboxylic ester peroxide.
  5. The initiator composition of claim 4, wherein the initiator composition expedites the curing of an unsaturated polyester resin at a temperature not higher than 15° C.
  6. An initiator composition, comprising at least two first peroxides, a second peroxide, and a carboxylic ester peroxide; wherein the at least two first peroxides are 75 parts by weight; the second peroxide is 12 parts by weight; the carboxylic ester peroxide is 13 parts by weight; the at least two first peroxides comprise 35 parts by weight of benzoyl peroxide and 40 parts by weight of 2,4-dichlorobenzene acyl peroxide; the second peroxide is dicumyl peroxide; and the carboxylic ester peroxide is tert-butyl peroxybenzoate.

Citations (3)

  • CN1350917A
  • US4873274A
  • US6194525B1
Record as JSON
{
  "publication_number": "US9453085B2",
  "country": "US",
  "kind": "B2",
  "title": "Initiator composition for curing resin",
  "abstract": "An initiator composition, including at least two compounds represented by the chemical formula R - CO - O - O - CO - R and a compound represented by R 1 - O - O - R 2, where R represents a C 2 -C 12 alkyl or a C 6 -C 10 aryl or substituted aryl, and R 1 and R 2 independently, at each occurrence, represent a C 1 -C 10 alkyl or a C 6 -C 10 aryl.",
  "claims": [
    "1. An initiator composition, comprising 75 parts by weight of at least two first peroxides and 25 parts by weight of a second peroxide, wherein the at least two first peroxides comprise 25 parts by weight of benzoyl peroxide, 30 parts by weight of 2,4-dichlorobenzene acyl peroxide, and 20 parts by weight of lauroyl peroxide, and the second peroxide is di-t-butyl peroxide.",
    "2. An initiator composition, comprising 95 parts by weight of at least two first peroxides and 5 parts by weight of a second peroxide, wherein the at least two first peroxides comprise 35 parts by weight of benzoyl peroxide, 40 parts by weight of 2,4-dichlorobenzene acyl peroxide, 10 parts by weight of lauroyl peroxide, and 10 parts by weight of diacetyl peroxide, and the second peroxide is t-butyl cumyl peroxide.",
    "3. An initiator composition, comprising 90 parts by weight of at least two first peroxides and 10 parts by weight of a second peroxide, wherein the at least two first peroxides comprise 40 parts by weight of benzoyl peroxide and 50 parts by weight of 2,4-dichlorobenzene acyl peroxide, and the second peroxide is dicumyl peroxide.",
    "4. An initiator composition for expediting curing of an unsaturated polyester resin at room temperature, the initiator composition comprising: at least two first peroxides selected from the group consisting of benzoyl peroxide, 2,4-dichlorobenzene acyl peroxide, lauroyl peroxide, and diacetyl peroxide; a second peroxide selected from the group consisting of dicumyl peroxide, di-t-butyl peroxide, and t-butyl cumyl peroxide; and a carboxylic ester peroxide selected from the group consisting of tert-butyl peroxybenzoate (TBPB), tert-butyl peroxy diethyl acetate, t-butyl peroctoate (TBPO); wherein: the initiator composition comprises between 70 and 85 parts by weight of the at least two first peroxides, between 5 and 15 parts by weight of the second peroxide, and between 5 and 15 parts by weight of the carboxylic ester peroxide.",
    "5. The initiator composition of claim 4, wherein the initiator composition expedites the curing of an unsaturated polyester resin at a temperature not higher than 15° C.",
    "6. An initiator composition, comprising at least two first peroxides, a second peroxide, and a carboxylic ester peroxide; wherein the at least two first peroxides are 75 parts by weight; the second peroxide is 12 parts by weight; the carboxylic ester peroxide is 13 parts by weight; the at least two first peroxides comprise 35 parts by weight of benzoyl peroxide and 40 parts by weight of 2,4-dichlorobenzene acyl peroxide; the second peroxide is dicumyl peroxide; and the carboxylic ester peroxide is tert-butyl peroxybenzoate."
  ],
  "cpc": [
    "C08F 4/34",
    "C08F 299/045",
    "C08F 4/38",
    "C08G 63/91"
  ],
  "assignees": [
    "WUHAN KEDA MARBLE PROTECTIVE MAT CO LTD"
  ],
  "filing_date": "2014-09-21",
  "publication_date": "2016-09-27",
  "grant_date": "2016-09-27",
  "priority_date": "2012-04-19",
  "application_number": "US-201414492066-A",
  "family_id": "46618499",
  "citations": [
    "CN1350917A",
    "US4873274A",
    "US6194525B1"
  ]
}

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