High strength and high conductivity copper alloy rod or wire

{
  "publication_number": "US9512506B2",
  "country": "US",
  "kind": "B2",
  "title": "High strength and high conductivity copper alloy rod or wire",
  "abstract": "A high strength and high conductivity copper rod or wire includes Co of 0.12 to 0.32 mass %, P of 0.042 to 0.095 mass %, Sn of 0.005 to 0.70 mass %, and O of 0.00005 to 0.0050 mass %. A relationship of 3.0≦([Co]−0.007)/([P]−0.008)≦6.2 is satisfied between a content [Co] mass % of Co and a content [P] mass % of P. The remainder includes Cu and inevitable impurities, and the rod or wire is produced by a process including a continuous casting and rolling process. Strength and conductivity of the high strength and high conductivity copper rod or wire are improved by uniform precipitation of a compound of Co and P and by solid solution of Sn. The high strength and high conductivity copper rod or wire is produced by the continuous casting and rolling process, and thus production costs are reduced.",
  "claims": [
    "1. A high strength and high conductivity copper rod or wire produced by a process including a continuous casting and rolling process, the copper rod or wire comprising: Co of 0.12 to 0.32 mass %; P of 0.042 to 0.095 mass %; Sn of 0.005 to 0.70 mass %; and O of 0.00005 to 0.0050 mass %, wherein a relationship of 3.0≦([Co]−0.007)/([P]−0.008)≦6.2 is satisfied between a content [Co] mass % of Co and a content [P] mass % of P, and the remainder includes Cu and inevitable impurities, and wherein a rolling start temperature in the continuous casting and rolling process is 860 to 1000° C., a total hot processing rate is 75% or higher, and an average cooling rate in a temperature range of 850 to 400° C. is 10° C./second or higher, a non-recrystallization ratio of a metal structure at completion of the continuous casting and rolling process is 10 to 80% and an average grain size of a recrystallized part is 2.5 to 25 μm, and the non-recrystallization ratio in a vicinity of an outer peripheral portion of the copper rod or wire is effectively higher than the non-recrystallization ratio in a center portion of the copper rod or wire, effective to increase the tensile strength in the outer peripheral portion, the outer peripheral portion corresponding to a portion of 6/7R from the center portion of the copper rod or wire.",
    "2. The high strength and high conductivity copper rod or wire according to claim 1, further comprising at least one additional element selected from the group consisting of Zn of 0.002 to 0.5 mass %, Mg of 0.002 to 0.25 mass %, Ag of 0.002 to 0.25 mass %, and Zr of 0.001 to 0.1 mass %.",
    "3. The high strength and high conductivity copper rod or wire according to claim 2, wherein a cold drawing/wire drawing process is performed after the continuous casting and rolling process, wherein a heat treatment at 350 to 620° C. for 0.5 to 16 hours is performed before, after, or during the cold drawing/wire drawing process, wherein substantially circular or substantially oval fine precipitates are uniformly dispersed in the copper rod or wire, and wherein an average grain diameter of the precipitates is 2 to 20 nm, or 90% or more of all precipitates have a size of 30 nm or less.",
    "4. The high strength and high conductivity copper rod or wire according to claim 2, wherein the wire has an outer diameter of 3 mm or less, conductivity is 45 (% IACS) or higher, a value of R 1/2 ×S is 4300 or more, where R (% IACS) is conductivity and S (N/mm 2) is tensile strength, and bending resistance is excellent.",
    "5. The high strength and high conductivity copper rod or cording to claim 2, wherein the copper rod or wire forms a wire harness.",
    "6. The high strength and high conductivity copper rod or wire according to claim 2, wherein conductivity is 45 (% IACS) or higher, elongation is 5% or higher, and a value of (R 1/2 ×S×(100+L)/100) is 4200 or more, where R (% IACS) is conductivity, S (N/mm 2) is tensile strength, and L (%) is elongation.",
    "7. The high strength and high conductivity copper rod or wire according to claim 2, wherein the copper rod or wire is used for cold forging or pressing.",
    "8. The high strength and high conductivity copper rod or wire according to claim 2, wherein Vickers hardness (HV) after heating at 700° C. for 30 seconds is 90 or higher, conductivity is 45 (% IACS) or higher, and an average grain diameter of precipitates in a metal structure after the heating is 2 to 20 nm, 90% or more of all precipitates have a size of 30 nm or less, or a recrystallization ratio of the metal structure is 45% or lower.",
    "9. The high strength and high conductivity copper rod or wire according to claim 1, wherein the wire has an outer diameter of 3 mm or less, and bending resistance is excellent.",
    "10. The high strength and high conductivity copper rod or wire according to claim 1, wherein the wire has an outer diameter of 3 mm or less, conductivity is 45 (% IACS) or higher, a value of R 1/2 ×S is 4300 or more, where R (% IACS) is conductivity and S (N/mm 2) is tensile strength, and bending resistance is excellent.",
    "11. The high strength and high conductivity copper rod or cording to claim 1, wherein the copper rod or wire forms a wire harness.",
    "12. The high strength and high conductivity copper rod or wire according to claim 1, wherein conductivity is 45 (% IACS) or higher, elongation is 5% or higher, and a value of (R 1/2 ×S×(100+L)/100) is 4200 or more, where R (% IACS) is conductivity, S (N/mm 2) is tensile strength, and L (%) is elongation.",
    "13. The high strength and high conductivity copper rod or wire according to claim 1, wherein the copper rod or wire has high-temperature strength in which tensile strength at 400° C. is 180 N/mm 2 or higher.",
    "14. The high strength and high conductivity copper rod or wire according to claim 1, wherein the copper rod or wire is used for cold forging or pressing.",
    "15. The high strength and high conductivity copper rod or wire according to claim 1, wherein Vickers hardness (HV) after heating at 700° C. for 30 seconds is 90 or higher, conductivity is 45 (% IACS) or higher, and an average grain diameter of precipitates in a metal structure after the heating is 2 to 20 nm, 90% or more of all precipitates have a size of 30 nm or less, or a recrystallization ratio of the metal structure is 45% or lower.",
    "16. The high strength and high conductivity copper rod or wire according to claim 1, wherein a cold drawing/wire drawing process is performed after the continuous casting and rolling process, wherein a heat treatment at 350 to 620° C. for 0.5 to 16 hours is performed before, after, or during the cold drawing/wire drawing process, wherein substantially circular or substantially oval fine precipitates are uniformly dispersed in the copper rod or wire, and wherein an average grain diameter of the precipitates is 2 to 20 nm, or 90% or more of all precipitates have a size of 30 nm or less.",
    "17. The high strength and high conductivity copper rod or wire according to claim 1, wherein a heat treatment at 200 to 700° C. for 0.001 seconds to 180 minutes is performed during or after the cold wire drawing process, and bending resistance is excellent."
  ],
  "description_excerpt": "This is a National Phase Application in the United States of International Patent Application No. PCT/JP2009/053220 filed Feb. 23, 2009, which claims priority on Japanese Patent Application No. JP2008-044353, filed Feb. 26, 2008. The entire disclosures of the above patent applications are hereby incorporated by reference.\n\nThe present invention relates to a high strength and high conductivity copper rod or wire produced by a process including a continuous casting and rolling process.\n\nCopper rods and wires have been used as electrical conductors in various fields. For example, copper rods and wires have been used in the wire harnesses of cars, and the weights of the cars need to be reduced to improve fuel efficiency to counter global warming. However, the weights of the wire harnesses used tend to increase along with developments in car information, electronics, and hybridization. Since copper is expensive metal, the car manufacturing industry wants to reduce the amount of copper to be used in view of the cost. For this reason, when using a copper wire having high strength, high conductivity, bending resistance, and excellent ductility for a wire harness, it is possible to reduce the amount of copper used and thus it is possible to reduce the size and weight of cars. As described above, the invention of a high strength and high conductivity rod or wire has been made in response to contemporary needs.\n\nThere are several kinds of wire harnesses, such as a power system and a signal system in which very little current flows. For the former, conductivity close to that of pure copper is required as the first priority.",
  "cpc": [
    "H01B 1/026",
    "B23K 35/30",
    "C22C 9/02",
    "C22C 9/06",
    "C22F 1/08",
    "H01B 13/0016",
    "H01B 13/01209",
    "H01B 7/0045",
    "Y10T 428/2913"
  ],
  "ipc": [
    "H01B 1/22",
    "H01B 5/02",
    "C22C 9/02",
    "C22C 9/06",
    "C22F 1/08",
    "H01B 1/02"
  ],
  "assignees": [
    "Mitsubishi Shindoh Co Ltd",
    "Mitsubishi Materials Corp"
  ],
  "inventors": [
    "Keiichiro Oishi",
    "Kazumasa Hori"
  ],
  "filing_date": "2009-02-23",
  "publication_date": "2016-12-06",
  "grant_date": "2016-12-06",
  "priority_date": "2008-02-26",
  "application_number": "US-91920609-A",
  "family_id": "41015980",
  "cited_by_count": 11,
  "citations": [
    "US2074713A",
    "US4073667A",
    "US4427627A",
    "US4260432A",
    "US4388270A",
    "JPS60245753A",
    "US4666667A",
    "JPS60245754A",
    "JPS6365039A",
    "JPH01108322A",
    "US5004498A",
    "US5322575A",
    "JPH04272148A",
    "JPH0653901A",
    "JPH0694390A",
    "US5814168A",
    "US6132529A",
    "JPH10168532A",
    "JPH10130754A",
    "JPH1197609A",
    "JPH11256255A",
    "JP2001214226A",
    "JP2001316742A",
    "JP2003268467A",
    "JP2004137551A",
    "EP1630240A1",
    "TW200417616A",
    "WO2004079026A1",
    "US7608157B2",
    "US20060260721A1",
    "WO2004079206A1",
    "JP2004292917A",
    "CN1546701A",
    "US20060016528A1",
    "US20090014102A1",
    "CN1693502A",
    "TW200706660A",
    "US20090084473A1",
    "US20070051442A1",
    "US20100297464A1",
    "WO2007139213A1",
    "US20100008817A1",
    "WO2008099892A1",
    "US20100047112A1",
    "US20100206513A1",
    "US20110056596A1",
    "WO2009107586A1",
    "US7928541B2",
    "US20110200479A1"
  ]
}