Patent · US9856414B2 · B2 · US
Compositions, systems and methods of making coated additive components
- (11) Publication number
- US9856414B2
- (21) Application number
- 14/271,012
- (22) Filing date
- 2014-05-06
- (30) Priority date
- 2013-06-10
- (43) Publication date
- 2018-01-02
- (45) Date of grant
- 2018-01-02
- (51) IPC
- B05D 1/12; B05D 1/36; B05D 5/00; C09K 8/80; C09K 8/528; C09K 8/536; C09K 8/70; C09K 8/74; C09K 8/92
- (52) CPC
- C09K Materials for miscellaneous applications, not provided for elsewhere: 8/805, 2208/22, 2208/26, 2208/28, 2208/32, 2208/34, 8/528, 8/536, 8/706, 8/92
- (73) Assignee
- Dober Chemical Corp
- (72) Inventors
- Magesh Sundaram; Stephen Mosher; Joseph Yaritz
- (54) Title
- Compositions, systems and methods of making coated additive components
- (57) Abstract
Compositions, systems and methods for the prevention or reduction of clumping or sticking of particulate hydraulic fracturing chemical additives. In preferred examples the particulate hydraulic fracturing chemical additives may be coated with, for example, a coating comprising a polymeric component and with or without silica. Inorganic flow agents (IFA) may be applied to the exterior surface of the particulate hydraulic fracturing chemical additives to prevent hardening or clumping of the additives upon storage. Preferably the coating is permeable, but insoluble in an aqueous medium, whereupon the additive components are released into the medium.
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Claims (13)
- A composition comprising a chemical additive component core, said core consisting of a solid chemical additive per se, encapsulated by a single layer coating comprising an acrylic copolymer containing branched vinyl ester monomers, at least one of said vinyl ester monomers comprising a vinyl versatate monomer; said composition having an exterior surface dusted with a dry microparticulate inorganic flow agent (IFA), and said composition lacking an inert particulate incorporated as part of the single layer coating.
- The composition of claim 1 in which the median IFA particle size is about 1 micron to about 10 microns in diameter.
- The composition of claim 2 in which the median IFA particle size is about 8 microns in diameter.
- The composition of claim 1 wherein the inorganic flow agent is selected from the group consisting of metal salts of silicates, silicas, metal salts of carbonates, diatomaceous earth, talc, mica, and ceramic particles such as ceramic spheres.
- The composition of claim 4 in which the IFA comprises a silicate.
- The composition of claim 5, in which the IFA comprises calcium silicate.
- The composition of claim 1 comprising: a particulate active component comprised in said chemical additive component, said particulate active component selected from the group consisting of a scale inhibitor composition, a hydrate and or halite inhibitor composition, a pour point suppressant composition, a dispersant, a demulsifier, a tracer, a drag reducer, a viscosity-reducing composition, an oxidizer composition, a pH modulating composition, a lubricant composition, a cross-linking composition, an anti-corrosion composition, an biocide composition, a crosslink-enhancing composition, and a combination of two or more of these compositions.
- The composition of claim 1 in which the coating comprises a water insoluble component.
- The composition of claim 1 in which the polymer component is self-crosslinked.
- The composition of claim 9 in which the coating comprises a compound selected form the group consisting of an aziridine and a carbodiimide.
- The composition of claim 10 in which the coating comprises an aziridine.
- The composition of claim 1 wherein the chemical additive component comprises a breaker component.
- The composition of claim 1 wherein the chemical additive component comprises an ammonium persulfate component.
Description
This application claims priority to provisional patent application Ser. No. 61/833,286, filed Jun. 10, 2013, which is specifically incorporated by reference herein in its entirety.
The present invention relates to systems, compositions, and methods involved in the extraction of petroleum, natural gas, coal seam gas, and other substances from wells. In particular, the invention relates to additives used in hydraulic fracturing for the extraction of substances, primarily hydrocarbons, from an underground rock layer. In a particularly preferred embodiment, the invention relates to additive compositions at least partially coated with a water impervious coating, such as a polymer, and agents useful for preventing or reducing clumping of additive particles coated with such polymers.
Hydraulic fracturing, or “fracking” refers to the induction of fractures in underground rock layers by pumping a pressurized fluid within the well in order to cause fracturing of the rock layer in which the substances to be extracted are located. Although also useful for the extraction of other substances, hydraulic fracturing is of particular importance in the extraction of petroleum and natural gas for energy uses. This technology permits the extraction of substantial amounts of hydrocarbons from previously exploited oil and gas wells, thereby enhancing the yield of hydrocarbons from such wells, many of which were formerly considered to have been exhausted.
Citations (21)
- US5066698A
- US5373901A
- US6010639A
- US6444316B1
- US6527051B1
- US6554071B1
- US6642185B2
- US6878309B2
- US6767868B2
- US7857051B2
- US20060063693A1
- US6923264B2
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- US7287590B1
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- US20130255951A1
Record as JSON
{
"publication_number": "US9856414B2",
"country": "US",
"kind": "B2",
"title": "Compositions, systems and methods of making coated additive components",
"abstract": "Compositions, systems and methods for the prevention or reduction of clumping or sticking of particulate hydraulic fracturing chemical additives. In preferred examples the particulate hydraulic fracturing chemical additives may be coated with, for example, a coating comprising a polymeric component and with or without silica. Inorganic flow agents (IFA) may be applied to the exterior surface of the particulate hydraulic fracturing chemical additives to prevent hardening or clumping of the additives upon storage. Preferably the coating is permeable, but insoluble in an aqueous medium, whereupon the additive components are released into the medium.",
"claims": [
"1. A composition comprising a chemical additive component core, said core consisting of a solid chemical additive per se, encapsulated by a single layer coating comprising an acrylic copolymer containing branched vinyl ester monomers, at least one of said vinyl ester monomers comprising a vinyl versatate monomer; said composition having an exterior surface dusted with a dry microparticulate inorganic flow agent (IFA), and said composition lacking an inert particulate incorporated as part of the single layer coating.",
"2. The composition of claim 1 in which the median IFA particle size is about 1 micron to about 10 microns in diameter.",
"3. The composition of claim 2 in which the median IFA particle size is about 8 microns in diameter.",
"4. The composition of claim 1 wherein the inorganic flow agent is selected from the group consisting of metal salts of silicates, silicas, metal salts of carbonates, diatomaceous earth, talc, mica, and ceramic particles such as ceramic spheres.",
"5. The composition of claim 4 in which the IFA comprises a silicate.",
"6. The composition of claim 5, in which the IFA comprises calcium silicate.",
"7. The composition of claim 1 comprising: a particulate active component comprised in said chemical additive component, said particulate active component selected from the group consisting of a scale inhibitor composition, a hydrate and or halite inhibitor composition, a pour point suppressant composition, a dispersant, a demulsifier, a tracer, a drag reducer, a viscosity-reducing composition, an oxidizer composition, a pH modulating composition, a lubricant composition, a cross-linking composition, an anti-corrosion composition, an biocide composition, a crosslink-enhancing composition, and a combination of two or more of these compositions.",
"8. The composition of claim 1 in which the coating comprises a water insoluble component.",
"9. The composition of claim 1 in which the polymer component is self-crosslinked.",
"10. The composition of claim 9 in which the coating comprises a compound selected form the group consisting of an aziridine and a carbodiimide.",
"11. The composition of claim 10 in which the coating comprises an aziridine.",
"12. The composition of claim 1 wherein the chemical additive component comprises a breaker component.",
"13. The composition of claim 1 wherein the chemical additive component comprises an ammonium persulfate component."
],
"description_excerpt": "This application claims priority to provisional patent application Ser. No. 61/833,286, filed Jun. 10, 2013, which is specifically incorporated by reference herein in its entirety.\n\nThe present invention relates to systems, compositions, and methods involved in the extraction of petroleum, natural gas, coal seam gas, and other substances from wells. In particular, the invention relates to additives used in hydraulic fracturing for the extraction of substances, primarily hydrocarbons, from an underground rock layer. In a particularly preferred embodiment, the invention relates to additive compositions at least partially coated with a water impervious coating, such as a polymer, and agents useful for preventing or reducing clumping of additive particles coated with such polymers.\n\nHydraulic fracturing, or “fracking” refers to the induction of fractures in underground rock layers by pumping a pressurized fluid within the well in order to cause fracturing of the rock layer in which the substances to be extracted are located. Although also useful for the extraction of other substances, hydraulic fracturing is of particular importance in the extraction of petroleum and natural gas for energy uses. This technology permits the extraction of substantial amounts of hydrocarbons from previously exploited oil and gas wells, thereby enhancing the yield of hydrocarbons from such wells, many of which were formerly considered to have been exhausted.",
"cpc": [
"C09K 8/805",
"C09K 2208/22",
"C09K 2208/26",
"C09K 2208/28",
"C09K 2208/32",
"C09K 2208/34",
"C09K 8/528",
"C09K 8/536",
"C09K 8/706",
"C09K 8/92"
],
"ipc": [
"B05D 1/12",
"B05D 1/36",
"B05D 5/00",
"C09K 8/80",
"C09K 8/528",
"C09K 8/536",
"C09K 8/70",
"C09K 8/74",
"C09K 8/92"
],
"assignees": [
"Dober Chemical Corp"
],
"inventors": [
"Magesh Sundaram",
"Stephen Mosher",
"Joseph Yaritz"
],
"filing_date": "2014-05-06",
"publication_date": "2018-01-02",
"grant_date": "2018-01-02",
"priority_date": "2013-06-10",
"application_number": "US-201414271012-A",
"family_id": "52005953",
"cited_by_count": 4,
"citations": [
"US5066698A",
"US5373901A",
"US6010639A",
"US6444316B1",
"US6527051B1",
"US6554071B1",
"US6642185B2",
"US6878309B2",
"US6767868B2",
"US7857051B2",
"US20060063693A1",
"US6923264B2",
"US7090015B2",
"US7000701B2",
"US7287590B1",
"US8012914B2",
"US20110278008A1",
"US20090301968A1",
"US20100159009A1",
"US8058212B2",
"US20130255951A1"
]
}
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