MLchartDataset catalogue

Patent · US11607667B2 · B2 · US

Absorption agent and absorbent article

(11) Publication number
US11607667B2
(21) Application number
16/762,994
(22) Filing date
2018-11-14
(30) Priority date
2017-11-16
(43) Publication date
2023-03-21
(45) Date of grant
2023-03-21
(51) IPC
A61F 13/15; A61F 13/53; B01J 20/04; B01J 20/26; B01J 20/28; B65G 31/04; B65G 65/48; C08F 220/06
(52) CPC
  • B01J Chemical or physical processes, e.g. catalysis or colloid chemistry; their relevant apparatus: 20/267, 20/043, 20/26, 20/28, 20/28011, 20/28016, 2220/68
  • A61F Filters implantable into blood vessels; prostheses; devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents; orthopaedic, nursing or contraceptive devices; fomentation; treatment or protection of eyes or ears; bandages, dressings or absorbent pads; first-aid kits: 13/15658, 13/45, 13/53, 2013/15463, 2013/530489, 2013/530591, 2013/530686, 2013/530693, 2013/530751
  • A61L Methods or apparatus for sterilising materials or objects in general; disinfection, sterilisation or deodorisation of air; chemical aspects of bandages, dressings, absorbent pads or surgical articles; materials for bandages, dressings, absorbent pads or surgical articles: 15/48, 15/60
  • B65G Transport or storage devices, e.g. conveyors for loading or tipping, shop conveyor systems or pneumatic tube conveyors: 31/04, 65/48
  • C08F Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds: 220/06, 2800/20, 2810/20, 6/008
(73) Assignee
Nippon Shokubai Co Ltd
(72) Inventors
Hiroki Kawada; Taku Iwamura; Koji Tachi; Makiko MASUDA; Yasuhisa Nakashima; Kazushi Torii; Yukihiro Kasano
(54) Title
Absorption agent and absorbent article
(57) Abstract

Provided is a water-absorbing agent that causes no or little fluctuation of feed rate when fed with use of a feeder. A water-absorbing agent containing a water-absorbing resin as a main component, the water-absorbing agent satisfying the following (a) and (b): (a) K-index is 70 or more; and (b) Moisture absorption blocking ratio, after 30 minutes of standing at a temperature of 25° C. and a relative humidity of 80% RH, is 70 weight % or less, the K-index being defined by the following equation: K-index=100−(−438+3.6×angle of repose+3.5×angle of difference+7.9×compressibility rate+290×bulk density (EDANA method)).

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Claims (13)

  1. A water-absorbing agent comprising a water-absorbing resin as a main component and a polyvalent metal salt in an amount of 0.001 to 10 parts by weight relative to 100 parts by weight of the water-absorbing resin, wherein said water-absorbing agent satisfies the following (a) and (b): (a) K-index is 70 or more; and (b) Moisture absorption blocking ratio, after 30 minutes of standing at a temperature of 25° C. and a relative humidity of 80% RH, is 70 weight % or less, the K-index being defined by the following equation: K-index=100−(−438+3.6×angle of repose+3.5×angle of difference+7.9×compressibility rate+290×bulk density (EDANA method)).
  2. The water-absorbing agent according to claim 1, wherein the moisture absorption blocking ratio is 40 weight % or less.
  3. The water-absorbing agent according to claim 1, wherein the moisture absorption blocking ratio is 30 weight % or less.
  4. The water-absorbing agent according to claim 1, wherein a powder flowability of said water-absorbing agent is 10.0 g/s or more.
  5. The water-absorbing agent according to claim 1, wherein a powder flowability of said water-absorbing agent is 11.0 g/s or more.
  6. The water-absorbing agent according to claim 1, wherein a surface tension of said water-absorbing agent is 65 mN/m or more.
  7. The water-absorbing agent according to claim 1, wherein diffusing absorbency, which is measured 10 minutes after a start of absorption of 0.9 weight % aqueous sodium chloride solution by said water-absorbing agent under a load of 1.96 kPa, is 15 g/g or more.
  8. The water-absorbing agent according to claim 1, wherein a probe insertion work of said water-absorbing agent is 30000 gf×mm or less.
  9. The water-absorbing agent according to claim 1, wherein a moisture content of said water-absorbing agent is 10 weight % or less.
  10. The water-absorbing agent according to claim 1, further comprising a surfactant.
  11. The water-absorbing agent according to claim 1, further comprising a hydrophilic polymer compound.
  12. The water-absorbing agent according to claim 1, wherein said water-absorbing agent is in the form of particles having a non-uniformly pulverized shape.
  13. An absorbent article comprising a water-absorbing agent recited in claim 1.

Description

The present invention relates to a water-absorbing agent and an absorbent article.

Water-absorbing resin (Super Absorbent Polymer, or SAP) is a water-swellable, water-insoluble polymer gelling agent. Water-absorbing resin is used for various applications. For example, water-absorbing resin is used in sanitary materials such as disposable diapers, sanitary napkins, and incontinence articles for adults, agricultural and horticultural water retaining agents, industrial waterproofing agents, and the like.

When a disposable diaper (major application of SAP) is produced, a water-absorbing agent that contains a SAP (raw material) as a main component is fed. When such a feeding is carried out, generally, an apparatus to meter and convey the water-absorbing agent is used. For example, Non-patent Literature 1 (Handbook of Filters, 4 th Edition, page 281 “3.9 Feeding” George Wypych, ChemTec Publishing, Toronto, 2016 (the first edition was published in 1993)) discloses a rotary feeder, a screw feeder, a table feeder, and a belt feeder, which are examples of the above-mentioned apparatus. Non-patent Literature 1 also discloses, as an apparatus designed to accurately feed a bulk material, a bulk solid pump (BSP/Bulk Solids Pump™, also called “Bulk Solids Pump”) manufactured by Coperion K-tron.

Patent Literature 1 (U.S. Pat. No. 5,051,041) and Patent Literature 2 (Published Japanese Translation of PCT International Application, Tokuhyohei, No. 5-503492) each disclose a multiple-choke apparatus to convey and meter a particulate material. Patent Literature 3 (U.S. Pat. No. 5,355,993), Patent Literature 4 (Japanese Patent No.

Citations (47)

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Record as JSON
{
  "publication_number": "US11607667B2",
  "country": "US",
  "kind": "B2",
  "title": "Absorption agent and absorbent article",
  "abstract": "Provided is a water-absorbing agent that causes no or little fluctuation of feed rate when fed with use of a feeder. A water-absorbing agent containing a water-absorbing resin as a main component, the water-absorbing agent satisfying the following (a) and (b): (a) K-index is 70 or more; and (b) Moisture absorption blocking ratio, after 30 minutes of standing at a temperature of 25° C. and a relative humidity of 80% RH, is 70 weight % or less, the K-index being defined by the following equation: K-index=100−(−438+3.6×angle of repose+3.5×angle of difference+7.9×compressibility rate+290×bulk density (EDANA method)).",
  "claims": [
    "1. A water-absorbing agent comprising a water-absorbing resin as a main component and a polyvalent metal salt in an amount of 0.001 to 10 parts by weight relative to 100 parts by weight of the water-absorbing resin, wherein said water-absorbing agent satisfies the following (a) and (b): (a) K-index is 70 or more; and (b) Moisture absorption blocking ratio, after 30 minutes of standing at a temperature of 25° C. and a relative humidity of 80% RH, is 70 weight % or less, the K-index being defined by the following equation: K-index=100−(−438+3.6×angle of repose+3.5×angle of difference+7.9×compressibility rate+290×bulk density (EDANA method)).",
    "2. The water-absorbing agent according to claim 1, wherein the moisture absorption blocking ratio is 40 weight % or less.",
    "3. The water-absorbing agent according to claim 1, wherein the moisture absorption blocking ratio is 30 weight % or less.",
    "4. The water-absorbing agent according to claim 1, wherein a powder flowability of said water-absorbing agent is 10.0 g/s or more.",
    "5. The water-absorbing agent according to claim 1, wherein a powder flowability of said water-absorbing agent is 11.0 g/s or more.",
    "6. The water-absorbing agent according to claim 1, wherein a surface tension of said water-absorbing agent is 65 mN/m or more.",
    "7. The water-absorbing agent according to claim 1, wherein diffusing absorbency, which is measured 10 minutes after a start of absorption of 0.9 weight % aqueous sodium chloride solution by said water-absorbing agent under a load of 1.96 kPa, is 15 g/g or more.",
    "8. The water-absorbing agent according to claim 1, wherein a probe insertion work of said water-absorbing agent is 30000 gf×mm or less.",
    "9. The water-absorbing agent according to claim 1, wherein a moisture content of said water-absorbing agent is 10 weight % or less.",
    "10. The water-absorbing agent according to claim 1, further comprising a surfactant.",
    "11. The water-absorbing agent according to claim 1, further comprising a hydrophilic polymer compound.",
    "12. The water-absorbing agent according to claim 1, wherein said water-absorbing agent is in the form of particles having a non-uniformly pulverized shape.",
    "13. An absorbent article comprising a water-absorbing agent recited in claim 1."
  ],
  "description_excerpt": "The present invention relates to a water-absorbing agent and an absorbent article.\n\nWater-absorbing resin (Super Absorbent Polymer, or SAP) is a water-swellable, water-insoluble polymer gelling agent. Water-absorbing resin is used for various applications. For example, water-absorbing resin is used in sanitary materials such as disposable diapers, sanitary napkins, and incontinence articles for adults, agricultural and horticultural water retaining agents, industrial waterproofing agents, and the like.\n\nWhen a disposable diaper (major application of SAP) is produced, a water-absorbing agent that contains a SAP (raw material) as a main component is fed. When such a feeding is carried out, generally, an apparatus to meter and convey the water-absorbing agent is used. For example, Non-patent Literature 1 (Handbook of Filters, 4 th Edition, page 281 “3.9 Feeding” George Wypych, ChemTec Publishing, Toronto, 2016 (the first edition was published in 1993)) discloses a rotary feeder, a screw feeder, a table feeder, and a belt feeder, which are examples of the above-mentioned apparatus. Non-patent Literature 1 also discloses, as an apparatus designed to accurately feed a bulk material, a bulk solid pump (BSP/Bulk Solids Pump™, also called “Bulk Solids Pump”) manufactured by Coperion K-tron.\n\nPatent Literature 1 (U.S. Pat. No. 5,051,041) and Patent Literature 2 (Published Japanese Translation of PCT International Application, Tokuhyohei, No. 5-503492) each disclose a multiple-choke apparatus to convey and meter a particulate material. Patent Literature 3 (U.S. Pat. No. 5,355,993), Patent Literature 4 (Japanese Patent No.",
  "cpc": [
    "B01J 20/267",
    "A61F 13/15658",
    "A61F 13/45",
    "A61F 13/53",
    "A61F 2013/15463",
    "A61F 2013/530489",
    "A61F 2013/530591",
    "A61F 2013/530686",
    "A61F 2013/530693",
    "A61F 2013/530751",
    "A61L 15/48",
    "A61L 15/60",
    "B01J 20/043",
    "B01J 20/26",
    "B01J 20/28",
    "B01J 20/28011",
    "B01J 20/28016",
    "B01J 2220/68",
    "B65G 31/04",
    "B65G 65/48",
    "C08F 220/06",
    "C08F 2800/20",
    "C08F 2810/20",
    "C08F 6/008"
  ],
  "ipc": [
    "A61F 13/15",
    "A61F 13/53",
    "B01J 20/04",
    "B01J 20/26",
    "B01J 20/28",
    "B65G 31/04",
    "B65G 65/48",
    "C08F 220/06"
  ],
  "assignees": [
    "Nippon Shokubai Co Ltd"
  ],
  "inventors": [
    "Hiroki Kawada",
    "Taku Iwamura",
    "Koji Tachi",
    "Makiko MASUDA",
    "Yasuhisa Nakashima",
    "Kazushi Torii",
    "Yukihiro Kasano"
  ],
  "filing_date": "2018-11-14",
  "publication_date": "2023-03-21",
  "grant_date": "2023-03-21",
  "priority_date": "2017-11-16",
  "application_number": "US-201816762994-A",
  "family_id": "66539071",
  "cited_by_count": 1,
  "citations": [
    "JPS553492B2",
    "JPS6065184A",
    "US4988239A",
    "US5051041A",
    "JP3548575B2",
    "US5355993A",
    "US5381886A",
    "US5402876A",
    "JP3659645B2",
    "US5485909A",
    "JP2001137704A",
    "JP2005522391A",
    "US20040028485A1",
    "US20030190198A1",
    "US20080142340A1",
    "US20060157322A1",
    "JP2004261796A",
    "US20050118423A1",
    "WO2004096304A1",
    "JP2006528119A",
    "WO2005075070A1",
    "US20050209352A1",
    "CN1934170A",
    "US20070066167A1",
    "US20070141338A1",
    "WO2006109844A1",
    "US20070084700A1",
    "JP2009511393A",
    "WO2008120742A1",
    "US20100119312A1",
    "JP2011032422A",
    "CN102548654A",
    "US20120184670A1",
    "CN105771945A",
    "US20150129799A1",
    "JP5503492B2",
    "JP2013039804A",
    "JP2014073448A",
    "JP6068745B2",
    "WO2014162843A1",
    "WO2015053372A1",
    "EP3056268A1",
    "WO2015108084A1",
    "WO2015129917A1",
    "US20170014801A1",
    "CN204027530U",
    "WO2017170605A1"
  ]
}

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