Patent · US5607982A · A · US
Flexible open-cell polyurethane foam
- (11) Publication number
- US5607982A
- (21) Application number
- US-59454596-A
- (22) Filing date
- 1996-01-31
- (30) Priority date
- 1994-07-11
- (43) Publication date
- 1997-03-04
- (45) Date of grant
- 1997-03-04
- (52) CPC
- C08G Macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds: 18/48, 18/4845, 18/632, 2110/0008, 2110/005, 2110/0083
- (73) Assignee
- BASF CORP
- (54) Title
- Flexible open-cell polyurethane foam
- (57) Abstract
A flexible open-cell polyurethane is described that is the reaction product of a mixture comprising (a) a polyisocyanate component comprising monomeric or polymeric MDI, and (b) a polyol component having at least 50% of its 0H functional groups as secondary OH groups.
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Claims (20)
- A method of preparing a flexible open-cell polyurethane foam comprising the steps of (a) mixing (1) a polyisocyanate component comprising monomeric or polymeric MDI, and (2) a polyol component having at least 50% of its OH functional groups as secondary OH groups to form a polyurethane reaction mixture and filling a dispensing trough having an overflow weir with said polyurethane reaction mixture, (b) causing the polyurethane mixture to flow across the overflow weir, thereby applying the polyurethane reaction mixture onto a moving substrate to form a polyurethane bun, and (c) removing the polyurethane bun from the substrate.
- A method of preparing a flexible open-cell polyurethane foam according to claim 22 wherein the polyol component has an equivalent weight of from 700 to 2500.
- A method of preparing a flexible open-cell polyurethane foam according to claim 24 wherein the polyol component has an equivalent weight of 1000 to 2000.
- A method of preparing a flexible open-cell polyurethane foam according to claim 2 wherein the polyol component comprises a dispersion of polymer particles dispersed in a carrier polyol.
- A method of preparing a flexible open-cell polyurethane foam according to claim 2 wherein the polyol component comprises a dispersion of polymer particles dispersed in a carrier polyol.
- A method of preparing a flexible open-cell polyurethane foam according to claim 5 wherein the polymer particles are a copolymer of acrylonitrile and styrene.
- A method of preparing a flexible open-cell polyurethane foam according to claim 6 wherein the ratio of acrylonitrile to styrene is between 4:1 and 1:4.
- A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein the polyol component has an average hydroxyl functionality of 2 to 4.
- A method of preparing a flexible open-cell polyurethane foam according to claim 6 wherein the polyol component has an OH number of 20 to 60.
- A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein said polyol component comprises a polyether polyether polyol having an equivalent weight of from 1000 to 2000.
- A method of preparing a flexible open-cell polyurethane foam according to claim 9 wherein said polyether polyol comprises from 5 to 20% ethylene oxide units and is at least partially capped with propylene oxide.
- A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein said polyol component has 70-100% of its OH functional groups as secondary OH groups.
- A method of preparing a flexible open-cell polyurethane foam according to claim 12 wherein the polyol component is a polyether polyol and said secondary OH groups are derived from propylene oxide capping groups.
- A method of preparing a flexible open-cell polyurethane foam according to claim 12 wherein 100% of the polyol component's OH functional groups are secondary OH groups.
- A method of preparing a flexible open-cell polyurethane foam according to claim 14 wherein the polyol component is a polyether polyol and said secondary OH groups are derived from propylene oxide capping groups.
- A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein said polyisocyanate component further comprises TDI.
- A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein the foam thereby produced has a density of at least 3 lbs/ft 3.
- A method of preparing a flexible open-cell polyurethane foam according to claim 16 wherein the foam thereby produced has a catastophic fatigue of at least 65% retained at 65% IFD.
- A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein the foam thereby produced has a catastophic fatigue of at least 65% retained at 65% IFD.
- A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein the foam thereby produced has a tensile strength of at least 35.0 psi.
Citations (8)
- GB794403A
- US3380967A
- US3632707A
- US4074960A
- US4230823A
- US4298557A
- US4487854A
- US4950694A
Record as JSON
{
"publication_number": "US5607982A",
"country": "US",
"kind": "A",
"title": "Flexible open-cell polyurethane foam",
"abstract": "A flexible open-cell polyurethane is described that is the reaction product of a mixture comprising (a) a polyisocyanate component comprising monomeric or polymeric MDI, and (b) a polyol component having at least 50% of its 0H functional groups as secondary OH groups.",
"claims": [
"1. A method of preparing a flexible open-cell polyurethane foam comprising the steps of (a) mixing (1) a polyisocyanate component comprising monomeric or polymeric MDI, and (2) a polyol component having at least 50% of its OH functional groups as secondary OH groups to form a polyurethane reaction mixture and filling a dispensing trough having an overflow weir with said polyurethane reaction mixture, (b) causing the polyurethane mixture to flow across the overflow weir, thereby applying the polyurethane reaction mixture onto a moving substrate to form a polyurethane bun, and (c) removing the polyurethane bun from the substrate.",
"2. A method of preparing a flexible open-cell polyurethane foam according to claim 22 wherein the polyol component has an equivalent weight of from 700 to 2500.",
"3. A method of preparing a flexible open-cell polyurethane foam according to claim 24 wherein the polyol component has an equivalent weight of 1000 to 2000.",
"4. A method of preparing a flexible open-cell polyurethane foam according to claim 2 wherein the polyol component comprises a dispersion of polymer particles dispersed in a carrier polyol.",
"5. A method of preparing a flexible open-cell polyurethane foam according to claim 2 wherein the polyol component comprises a dispersion of polymer particles dispersed in a carrier polyol.",
"6. A method of preparing a flexible open-cell polyurethane foam according to claim 5 wherein the polymer particles are a copolymer of acrylonitrile and styrene.",
"7. A method of preparing a flexible open-cell polyurethane foam according to claim 6 wherein the ratio of acrylonitrile to styrene is between 4:1 and 1:4.",
"8. A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein the polyol component has an average hydroxyl functionality of 2 to 4.",
"9. A method of preparing a flexible open-cell polyurethane foam according to claim 6 wherein the polyol component has an OH number of 20 to 60.",
"10. A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein said polyol component comprises a polyether polyether polyol having an equivalent weight of from 1000 to 2000.",
"11. A method of preparing a flexible open-cell polyurethane foam according to claim 9 wherein said polyether polyol comprises from 5 to 20% ethylene oxide units and is at least partially capped with propylene oxide.",
"12. A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein said polyol component has 70-100% of its OH functional groups as secondary OH groups.",
"13. A method of preparing a flexible open-cell polyurethane foam according to claim 12 wherein the polyol component is a polyether polyol and said secondary OH groups are derived from propylene oxide capping groups.",
"14. A method of preparing a flexible open-cell polyurethane foam according to claim 12 wherein 100% of the polyol component's OH functional groups are secondary OH groups.",
"15. A method of preparing a flexible open-cell polyurethane foam according to claim 14 wherein the polyol component is a polyether polyol and said secondary OH groups are derived from propylene oxide capping groups.",
"16. A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein said polyisocyanate component further comprises TDI.",
"17. A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein the foam thereby produced has a density of at least 3 lbs/ft 3.",
"18. A method of preparing a flexible open-cell polyurethane foam according to claim 16 wherein the foam thereby produced has a catastophic fatigue of at least 65% retained at 65% IFD.",
"19. A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein the foam thereby produced has a catastophic fatigue of at least 65% retained at 65% IFD.",
"20. A method of preparing a flexible open-cell polyurethane foam according to claim 1 wherein the foam thereby produced has a tensile strength of at least 35.0 psi."
],
"cpc": [
"C08G 18/48",
"C08G 18/4845",
"C08G 18/632",
"C08G 2110/0008",
"C08G 2110/005",
"C08G 2110/0083"
],
"assignees": [
"BASF CORP"
],
"filing_date": "1996-01-31",
"publication_date": "1997-03-04",
"grant_date": "1997-03-04",
"priority_date": "1994-07-11",
"application_number": "US-59454596-A",
"family_id": "23039957",
"citations": [
"GB794403A",
"US3380967A",
"US3632707A",
"US4074960A",
"US4230823A",
"US4298557A",
"US4487854A",
"US4950694A"
]
}
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