MLchartDataset catalogue

Patent · US9181457B2 · B2 · US

Dry-to-the-touch anaerobically curable compositions and products made therefrom

(11) Publication number
US9181457B2
(21) Application number
12/621,632
(22) Filing date
2009-11-19
(30) Priority date
2007-05-22
(43) Publication date
2015-11-10
(45) Date of grant
2015-11-10
(51) IPC
B32B 27/28; B32B 27/40; B60J 10/00; B65D 53/00; B65D 53/06; C08G 18/30; C08G 18/32; C08G 18/38; C08G 18/66; C08L 75/02; C08L 75/04; C08L 81/00; C08L 81/10; C09J 175/02; C09J 175/04; C09J 175/08; C09J 181/00; C09J 181/10; C09J 4/06; F16B 39/02; F16B 39/22
(52) CPC
  • C09J Adhesives; non-mechanical aspects of adhesive processes in general; adhesive processes not provided for elsewhere; use of materials as adhesives: 4/06, 175/02, 175/04, 175/08, 181/00, 181/10
  • B32B Layered products, i.e. products built-up of strata of flat or non-flat, e.g. cellular or honeycomb, form: 2305/77, 2307/748, 27/28, 27/40
  • B60J Windows, windscreens, non-fixed roofs, doors, or similar devices for vehicles; removable external protective coverings specially adapted for vehicles: 10/0005, 10/16
  • B65D Containers for storage or transport of articles or materials, e.g. bags, barrels, bottles, boxes, cans, cartons, crates, drums, jars, tanks, hoppers, forwarding containers; accessories, closures, or fittings therefor; packaging elements; packages: 53/00, 53/06
  • C08G Macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds: 18/3203, 18/3225, 18/3876, 18/6696
  • C08L Compositions of macromolecular compounds: 75/02, 75/04, 81/00, 81/10
  • F16B Devices for fastening or securing constructional elements or machine parts together, e.g. nails, bolts, circlips, clamps, clips or wedges; joints or jointing: 39/02, 39/225
  • Y10T Technical subjects covered by former us classification: 29/49826, 428/2852, 428/2896
(73) Assignee
Henkel IP and Holding GmbH
(72) Inventors
Shabbir Attarwala; Ifeanyi C. Broderick; Qinyan Zhu; Roger J. Grismala
(54) Title
Dry-to-the-touch anaerobically curable compositions and products made therefrom
(57) Abstract

Dry-to-the-touch compositions containing a polymeric matrix and a anaerobically curable component present within the polymeric matrix are disclosed. In a particularly desirable form, the compositions are moisture curable. The compositions are non-flowable, at high temperatures, and have an improved solvent resistance once cured.

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Claims (14)

  1. A dry-to-the-touch curable composition comprising: a polymeric matrix comprising a material selected from the group consisting of a polyurethane, a polyurea, a polysulfonamide, a polythiourethane and combinations thereof; and an anaerobically curable component dispersed within said polymeric matrix, wherein said polymeric matrix is present in amounts of about 30% to about 80% by weight of the composition, and the composition remains non-flowable at temperatures greater than 260° C. up to about 300° C.
  2. A dry-to-the-touch curable composition comprising: a polymeric matrix comprising a material selected from the group consisting of a polyurethane, a polyurea, a polysulfonamide, a polythiourethane and combinations thereof; and an anaerobically curable component dispersed within said polymeric matrix, wherein said polymeric matrix is present in amounts of about 30% to about 80% by weight of the composition, and the composition remains non-flowable at temperatures greater than 260° C. up to about 300° C., further comprising a moisture cure catalyst.
  3. The composition of claim 1, wherein said polymeric matrix comprises a reaction product of a multifunctional diisocyanate and a multifunctional alcohol.
  4. The composition of claim 1, wherein said polymeric matrix comprises a reaction product of a multifunctional diisocyanate and an amine.
  5. The composition of claim 1, wherein said polymeric matrix comprises a reaction product of a multifunctional diisocyanate and a thiol.
  6. A combination of (a) a composition claim 1 and (b) a carrier substrate, wherein the composition is disposed as a coating on the carrier substrate.
  7. A combination of (a) a composition claim 2 and (b) a carrier substrate, wherein the composition is disposed as a coating on the carrier substrate.
  8. The combination of claim 6, wherein the substrate is comprised of a plastic, a cellulosic material, cotton, polyurethane or polytetrafluoroethylene.
  9. The combination of claim 7, wherein the substrate is comprised of a plastic, a cellulosic material, cotton, polyurethane or polytetrafluoroethylene.
  10. The combination of claim 8, wherein the substrate is in the form of a tape, a string or a sheet.
  11. The combination of claim 9, wherein the substrate is in the form of a tape, a string or a sheet.
  12. An article of manufacture comprising a preformed gasket comprising a dry-to-the-touch curable composition comprising a polymer matrix selected from the group consisting of a polyurethane, a polyurea, a polythiourethane and combinations thereof and having an anaerobically curable component distributed therein, wherein said anaerobic curable component comprises at least one (meth)acrylate monomer and a peroxide, wherein said polymeric matrix is present in amounts of about 30% to about 80% by weight of the composition.
  13. A method of preparing an article of manufacture comprising: (a) providing a threaded member; and (b) at least partially coating said threaded member with a dry to the touch curable composition comprising: a polymeric matrix comprising a material selected from the group consisting of a polyurethane, a polyurea, a polysulfonamide, a polythiourethane and combinations thereof; and an anaerobically curable component dispersed within said polymeric matrix, wherein said polymeric matrix is present in amounts of about 30% to about 80% by weight of the composition, and the composition remains non-flowable at temperatures greater than 260° C. up to about 300° C.
  14. A method of assembling threaded parts comprising: (a) providing a first threaded member; (b) providing a second threaded member capable of matingly engaging said first threaded member; at least one of said first and second threaded members being at least partially coated with a dry-to-the-touch curable composition comprising: a polymeric matrix comprising a material selected from the group consisting of a polyurethane, a polyurea, a polysulfonamide, a polythiourethane and combinations thereof; and an anaerobically curable component dispersed within said polymeric matrix, wherein said polymeric matrix is present in amounts of about 30% to about 80% by weight of the composition, and the composition remains non-flowable at temperatures greater than 260° C. up to about 300° C.; and (c) matingly engaging said first and second threaded parts and permitting the composition to anaerobically cure therebetween.

Description

This application continues from International Patent Application No. PCT/US2008/006295, filed on May 16, 2008, which claims the benefit of an earlier filing date from U.S. Provisional Application No. 60/939,526, filed May 22, 2007, the disclosures of each of which hereby being expressly incorporated herein by reference.

1. Field of the Invention

The present invention relates to curable adhesive and sealant compositions in a dry-to-the-touch form. More particularly, the present invention relates to dry-to-the-touch adhesive and sealant compositions which are particularly useful in threadlocking and sealing applications and may include various product forms of the compositions including dry-to-the-touch tapes and gaskets.

2. Brief Description of Related Technology

It is common practice in the use of threaded mechanical fasteners, such as nut/bolt assemblies, to apply to one or more of the threadable engagement surfaces thereof, an adhesive/sealant composition, termed a threadlocking composition, for the purpose of locking and/or sealing the constituent members of such fasteners when they are engaged in their final interlocked state.

Such threadlocking compositions significantly increased the torque required to break or turn the engaged threaded members. Conventional threadlocking compositions oftentimes include co-reactive adhesive systems. With this type of threadlocking composition, two or more components are mixed before applying the resulting composition to the threaded engagement surface(s) of the fastener on which the components in the threadlocking composition react to cure.

Citations (12)

  • US4118442A
  • US4039705A
  • US4111890A
  • US5087643A
  • US6086795A
  • JPH11302347A
  • WO2000001767A1
  • US6727320B2
  • US7041747B1
  • US6673875B2
  • US7408010B1
  • US20060096535A1
Record as JSON
{
  "publication_number": "US9181457B2",
  "country": "US",
  "kind": "B2",
  "title": "Dry-to-the-touch anaerobically curable compositions and products made therefrom",
  "abstract": "Dry-to-the-touch compositions containing a polymeric matrix and a anaerobically curable component present within the polymeric matrix are disclosed. In a particularly desirable form, the compositions are moisture curable. The compositions are non-flowable, at high temperatures, and have an improved solvent resistance once cured.",
  "claims": [
    "1. A dry-to-the-touch curable composition comprising: a polymeric matrix comprising a material selected from the group consisting of a polyurethane, a polyurea, a polysulfonamide, a polythiourethane and combinations thereof; and an anaerobically curable component dispersed within said polymeric matrix, wherein said polymeric matrix is present in amounts of about 30% to about 80% by weight of the composition, and the composition remains non-flowable at temperatures greater than 260° C. up to about 300° C.",
    "2. A dry-to-the-touch curable composition comprising: a polymeric matrix comprising a material selected from the group consisting of a polyurethane, a polyurea, a polysulfonamide, a polythiourethane and combinations thereof; and an anaerobically curable component dispersed within said polymeric matrix, wherein said polymeric matrix is present in amounts of about 30% to about 80% by weight of the composition, and the composition remains non-flowable at temperatures greater than 260° C. up to about 300° C., further comprising a moisture cure catalyst.",
    "3. The composition of claim 1, wherein said polymeric matrix comprises a reaction product of a multifunctional diisocyanate and a multifunctional alcohol.",
    "4. The composition of claim 1, wherein said polymeric matrix comprises a reaction product of a multifunctional diisocyanate and an amine.",
    "5. The composition of claim 1, wherein said polymeric matrix comprises a reaction product of a multifunctional diisocyanate and a thiol.",
    "6. A combination of (a) a composition claim 1 and (b) a carrier substrate, wherein the composition is disposed as a coating on the carrier substrate.",
    "7. A combination of (a) a composition claim 2 and (b) a carrier substrate, wherein the composition is disposed as a coating on the carrier substrate.",
    "8. The combination of claim 6, wherein the substrate is comprised of a plastic, a cellulosic material, cotton, polyurethane or polytetrafluoroethylene.",
    "9. The combination of claim 7, wherein the substrate is comprised of a plastic, a cellulosic material, cotton, polyurethane or polytetrafluoroethylene.",
    "10. The combination of claim 8, wherein the substrate is in the form of a tape, a string or a sheet.",
    "11. The combination of claim 9, wherein the substrate is in the form of a tape, a string or a sheet.",
    "12. An article of manufacture comprising a preformed gasket comprising a dry-to-the-touch curable composition comprising a polymer matrix selected from the group consisting of a polyurethane, a polyurea, a polythiourethane and combinations thereof and having an anaerobically curable component distributed therein, wherein said anaerobic curable component comprises at least one (meth)acrylate monomer and a peroxide, wherein said polymeric matrix is present in amounts of about 30% to about 80% by weight of the composition.",
    "13. A method of preparing an article of manufacture comprising: (a) providing a threaded member; and (b) at least partially coating said threaded member with a dry to the touch curable composition comprising: a polymeric matrix comprising a material selected from the group consisting of a polyurethane, a polyurea, a polysulfonamide, a polythiourethane and combinations thereof; and an anaerobically curable component dispersed within said polymeric matrix, wherein said polymeric matrix is present in amounts of about 30% to about 80% by weight of the composition, and the composition remains non-flowable at temperatures greater than 260° C. up to about 300° C.",
    "14. A method of assembling threaded parts comprising: (a) providing a first threaded member; (b) providing a second threaded member capable of matingly engaging said first threaded member; at least one of said first and second threaded members being at least partially coated with a dry-to-the-touch curable composition comprising: a polymeric matrix comprising a material selected from the group consisting of a polyurethane, a polyurea, a polysulfonamide, a polythiourethane and combinations thereof; and an anaerobically curable component dispersed within said polymeric matrix, wherein said polymeric matrix is present in amounts of about 30% to about 80% by weight of the composition, and the composition remains non-flowable at temperatures greater than 260° C. up to about 300° C.; and (c) matingly engaging said first and second threaded parts and permitting the composition to anaerobically cure therebetween."
  ],
  "description_excerpt": "This application continues from International Patent Application No. PCT/US2008/006295, filed on May 16, 2008, which claims the benefit of an earlier filing date from U.S. Provisional Application No. 60/939,526, filed May 22, 2007, the disclosures of each of which hereby being expressly incorporated herein by reference.\n\n1. Field of the Invention\n\nThe present invention relates to curable adhesive and sealant compositions in a dry-to-the-touch form. More particularly, the present invention relates to dry-to-the-touch adhesive and sealant compositions which are particularly useful in threadlocking and sealing applications and may include various product forms of the compositions including dry-to-the-touch tapes and gaskets.\n\n2. Brief Description of Related Technology\n\nIt is common practice in the use of threaded mechanical fasteners, such as nut/bolt assemblies, to apply to one or more of the threadable engagement surfaces thereof, an adhesive/sealant composition, termed a threadlocking composition, for the purpose of locking and/or sealing the constituent members of such fasteners when they are engaged in their final interlocked state.\n\nSuch threadlocking compositions significantly increased the torque required to break or turn the engaged threaded members. Conventional threadlocking compositions oftentimes include co-reactive adhesive systems. With this type of threadlocking composition, two or more components are mixed before applying the resulting composition to the threaded engagement surface(s) of the fastener on which the components in the threadlocking composition react to cure.",
  "cpc": [
    "C09J 4/06",
    "B32B 2305/77",
    "B32B 2307/748",
    "B32B 27/28",
    "B32B 27/40",
    "B60J 10/0005",
    "B60J 10/16",
    "B65D 53/00",
    "B65D 53/06",
    "C08G 18/3203",
    "C08G 18/3225",
    "C08G 18/3876",
    "C08G 18/6696",
    "C08L 75/02",
    "C08L 75/04",
    "C08L 81/00",
    "C08L 81/10",
    "C09J 175/02",
    "C09J 175/04",
    "C09J 175/08",
    "C09J 181/00",
    "C09J 181/10",
    "F16B 39/02",
    "F16B 39/225",
    "Y10T 29/49826",
    "Y10T 428/2852",
    "Y10T 428/2896"
  ],
  "ipc": [
    "B32B 27/28",
    "B32B 27/40",
    "B60J 10/00",
    "B65D 53/00",
    "B65D 53/06",
    "C08G 18/30",
    "C08G 18/32",
    "C08G 18/38",
    "C08G 18/66",
    "C08L 75/02",
    "C08L 75/04",
    "C08L 81/00",
    "C08L 81/10",
    "C09J 175/02",
    "C09J 175/04",
    "C09J 175/08",
    "C09J 181/00",
    "C09J 181/10",
    "C09J 4/06",
    "F16B 39/02",
    "F16B 39/22"
  ],
  "assignees": [
    "Henkel IP and Holding GmbH"
  ],
  "inventors": [
    "Shabbir Attarwala",
    "Ifeanyi C. Broderick",
    "Qinyan Zhu",
    "Roger J. Grismala"
  ],
  "filing_date": "2009-11-19",
  "publication_date": "2015-11-10",
  "grant_date": "2015-11-10",
  "priority_date": "2007-05-22",
  "application_number": "US-62163209-A",
  "family_id": "40130367",
  "cited_by_count": 6,
  "citations": [
    "US4118442A",
    "US4039705A",
    "US4111890A",
    "US5087643A",
    "US6086795A",
    "JPH11302347A",
    "WO2000001767A1",
    "US6727320B2",
    "US7041747B1",
    "US6673875B2",
    "US7408010B1",
    "US20060096535A1"
  ]
}

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