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Patent · US10662121B1 · B1 · US

Concrete mixing and concrete products

(11) Publication number
US10662121B1
(21) Application number
14/980,389
(22) Filing date
2015-12-28
(30) Priority date
2015-12-28
(43) Publication date
2020-05-26
(45) Date of grant
2020-05-26
(51) IPC
B28B 1/14; B28C 5/08; B29B 7/00; C04B 41/45
(52) CPC
  • C04B Lime, magnesia; slag; cements; compositions thereof, e.g. mortars, concrete or like building materials; artificial stone {}; ceramics; refractories; treatment of natural stone: 41/4578, 2111/00019, 28/00, 28/02, 28/10, 40/0231
  • B01D Separation: 53/1475
  • B28B Shaping clay or other ceramic compositions; shaping slag; shaping mixtures containing cementitious material, e.g. plaster: 1/14, 11/245
  • B28C Preparing clay; producing mixtures containing clay or cementitious material, e.g. plaster: 5/003, 5/0806, 5/42
  • B29B Preparation or pretreatment of the material to be shaped; making granules or preforms; recovery of plastics or other constituents of waste material containing plastics: 7/00
  • Y02C Capture, storage, sequestration or disposal of greenhouse gases [ghg]: 20/40
  • Y02P Climate change mitigation technologies in the production or processing of goods: 40/18
(73) Assignee
Concrete Products Group LLC
(72) Inventors
Canan D'Avela
(54) Title
Concrete mixing and concrete products
(57) Abstract

Some implementations herein described improvements to concrete products and processes for producing concrete products that may provide a positive environmental impact and that can be stronger relative to the percent of cement used. Particular examples include improvements to zero-slump to near-zero-slump concrete mixture design, material storage and handling, batching, mixing, sequencing and curing processes, as well as forming and curing techniques.

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Claims (32)

  1. A method of forming a concrete product from a batch of zero-slump to near-zero-slump concrete mixture including at least a predetermined total amount of aggregates, a predetermined amount of water, and a predetermined amount of cementitious material, the method comprising: (a) mixing an initial portion of the predetermined total amount of aggregates and all of the predetermined amount of water during an initial mixing stage to provide a non-cementitious slurry, the initial portion of the predetermined total amount of aggregates being 50% or less of the predetermined total amount of aggregates; (b) mixing the non-cementitious slurry with the predetermined amount of cementitious material during an intermediate mixing stage to provide a slumped cementitious mixture; (c) mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture during a subsequent mixing stage after the intermediate mixing stage to provide a zero-slump to near-zero-slump concrete mixture, the remaining portion of the predetermined total amount of aggregates being 50% or more of the predetermined amount of aggregates, the remaining portion of the predetermined total amount of aggregates having the same characteristics as the initial portion of the predetermined total amount of aggregates; (d) after the subsequent mixing stage, discharging the zero-slump to near-zero-slump concrete mixture into a mold to form at least one green unit having a predetermined shape, the zero-slump to near-zero-slump concrete mixture having a residence time in the mold of less than 30 seconds; and (e) curing the at least one green unit so as to form a concrete product.
  2. The method of claim 1, wherein the initial mixing stage further comprises mixing an admixture with the initial portion of the predetermined amount of aggregates and the predetermined amount of water prior to the intermediate mixing stage.
  3. The method of claim 2, wherein during the initial mixing stage, the initial portion of the predetermined total amount of aggregates is about 5% to 30% of the predetermined total amount of aggregates.
  4. The method of claim 1, wherein the batch of zero-slump to near-zero-slump concrete mixture has the predetermined amount of water and the predetermined amount of cementitious material that define a water-to-cement ratio by weight which is greater than 0.5:1 and less than 2.0:1.
  5. The method of claim 4, wherein the batch of zero-slump to near-zero-slump concrete mixture has the predetermined amount of water and the predetermined amount of cementitious material that define a water-to-cement ratio by weight in the range of 0.85:1 to 1.25:1.
  6. The method of claim 1, wherein the batch of zero-slump to near-zero-slump concrete mixture has the predetermined amount of water that is an amount of 100%+ water.
  7. The method of claim 1, wherein during the initial mixing stage, the initial portion of the predetermined total amount of aggregates consists of protected aggregates.
  8. The method of claim 7, wherein the predetermined total amount of aggregates consists of protected aggregates.
  9. The method of claim 1, wherein the at least one green unit formed in the mold retains said predetermined shape during said curing, wherein the at least one green unit hardens during said curing to provide said concrete product that sequesters ambient carbon dioxide for an extended period of days after said curing.
  10. The method of claim 9, wherein said concrete product provides ambient carbon dioxide sequestration of at least 5% weight percent of the cement over a 28 day period.
  11. The method of claim 1, wherein said curing comprises maintaining the at least one green unit in a curing chamber that provides a suspended fog condition with supplemental carbon dioxide delivery, said supplemental carbon dioxide delivery being redirect from an exhaust of a heat source of the curing chamber.
  12. The method of claim 1, wherein mixing is performed by a concrete mixer comprising: (a) a mixing chamber configured to receive staged delivery of aggregates, water, and the cementitious material; (b) at least one mixing blade connected to a shaft extending through the mixing chamber, the at least one mixing blade comprising a plurality of shearing elements extending from a surface of the mixing blade; and (c) a cleaning ring positioned around the shaft in the mixing chamber such that mixing by rotating the at least one mixing blade causes the shearing elements to periodically engage the cleaning ring to cause the clearing ring to twist relative to the shaft.
  13. The method of claim 12, wherein the shearing elements form elongated straight lines or elongated curved lines projecting out from the surface of the mixing blade.
  14. The method of claim 12, wherein the shearing elements of the mixing chamber provide deagglomerating, counter-ferromagnetic shear mixing during a mixing stage that mixes together aggregates, water, and a cementitious material.
  15. The method of claim 1, wherein discharging the zero-slump to near-zero-slump concrete mixture into a mold comprises: compressing, using a molding machine, the zero-slump to near-zero-slump concrete mixture to conform to the predetermined shape in the mold.
  16. The method of claim 15, wherein the zero-slump to near-zero-slump concrete mixture is not conformable within the mold by gravity.
  17. The method of claim 1, wherein curing the at least one green unit comprises: curing the at least one green unit outside the mold so as to form a precast concrete product.
  18. The method of claim 17, further comprising: prior to curing, removing the at least one green unit from the mold, the at least one green unit maintaining the predetermined shape before and during the curing.
  19. The method of claim 17, wherein the at least one green unit is cured in a curing chamber configured to provide a predetermined temperature, moisture condition, carbon dioxide atmosphere, and carbon dioxide supplement level.
  20. The method of claim 1, wherein mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture, and mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture during a subsequent mixing stage after the intermediate mixing stage to provide a zero-slump to near-zero-slump concrete mixture, are performed without additional water beyond the predetermined amount of water.
  21. The method of claim 20, wherein the initial portion of the predetermined total amount of aggregates is dry prior to mixing an initial portion of the predetermined total amount of aggregates and the predetermined amount of water during an initial mixing stage to provide a non-cementitious slurry.
  22. The method of claim 2, wherein discharging the zero-slump to near-zero-slump concrete mixture into a mold comprises: compressing, using a molding machine, the zero-slump to near-zero-slump concrete mixture to conform to the predetermined shape in the mold.
  23. The method of claim 22, wherein the zero-slump to near-zero-slump concrete mixture is not conformable within the mold by gravity.
  24. The method of claim 2, wherein curing the at least one green unit comprises: curing the at least one green unit outside the mold so as to form a precast concrete product.
  25. The method of claim 24, further comprising: prior to curing, removing the at least one green unit from the mold, the at least one green unit maintaining the predetermined shape before and during the curing.
  26. The method of claim 24, wherein the at least one green unit is cured in a curing chamber configured to provide a predetermined temperature, moisture condition, carbon dioxide atmosphere, and carbon dioxide supplement level.
  27. The method of claim 2, wherein mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture, and mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture during a subsequent mixing stage after the intermediate mixing stage to provide a zero-slump to near-zero-slump concrete mixture, are performed without additional water beyond the predetermined amount of water.
  28. The method of claim 27, wherein the initial portion of the predetermined total amount of aggregates is dry prior to mixing an initial portion of the predetermined total amount of aggregates and the predetermined amount of water during an initial mixing stage to provide a non-cementitious slurry.
  29. A method of forming a concrete product from a batch of zero-slump to near-zero-slump concrete mixture including at least a predetermined total amount of aggregates, a predetermined amount of water, and a predetermined amount of cementitious material, the method comprising: (a) mixing an initial portion of the predetermined total amount of aggregates and all of the predetermined amount of water during an initial mixing stage to provide a non-cementitious slurry, the initial portion of the predetermined total amount of aggregates being 50% or less of the predetermined total amount of aggregates; (b) mixing the non-cementitious slurry with the predetermined amount of cementitious material during an intermediate mixing stage to provide a slumped cementitious mixture; (c) mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture during a subsequent mixing stage after the intermediate mixing stage, the remaining portion of the predetermined total amount of aggregates having the same characteristics as the initial portion of the predetermined total amount of aggregates; (d) after the subsequent mixing stage, discharging the zero-slump to near-zero-slump concrete mixture into a mold to form at least one green unit having a predetermined shape, the zero-slump to near-zero-slump concrete mixture having a residence time in the mold of less than 30 seconds; and (e) curing the at least one green unit so as to form a concrete product; wherein said subsequent mixing stage is a third mixing stage, further comprising a fourth mixing stage that comprises one or more additives mixed together with the concrete mixture resulting from the third mixing stage, wherein the fourth mixing stage outputs the zero-slump to near-zero-slump concrete mixture.
  30. The method of claim 29, wherein the initial mixing stage comprises mixing the initial portion of the predetermined amount of aggregates, the predetermined amount of water, and at least one admixture in a mixing chamber for about 0.5 minutes to about 13 minutes prior to adding any of predetermined amount of cementitious material, wherein the mixing chamber is equipped with one or more shearing elements.
  31. The method of claim 30, wherein the predetermined amount of cementitious material is dispensed into the mixing chamber during the intermediate mixing stage only after the initial mixing stage in which the initial portion of the predetermined amount of aggregates, the predetermined amount of water, and at least one admixture are initially mixed to provide the non-cementitious slurry.
  32. The method of claim 31, wherein the intermediate mixing stage comprises mixing the non-cementitious slurry with the predetermined amount of cementitious material in the mixing chamber for about 2 minutes, wherein the shearing elements of the mixing chamber provide deagglomerating, counter-ferromagnetic shear mixing.

Description

This document relates to improved methods of concrete mixing and concrete products, including for example, zero-slump to near-zero-slump concrete mix designs and methods that provide improved strength, durability, and/or environmental impact.

In its simplest form, concrete is a mixture of paste and aggregates, or rocks. The paste, composed of portland cement and water, coats the surface of the fine (small) and coarse (larger) aggregates. Through a chemical reaction called hydration, the paste hardens and gains strength to form the rock-like mass known as concrete. Within this process lies the key to a remarkable trait of concrete: it is malleable when newly mixed, strong and durable when hardened. These qualities explain why concrete can be suitable for building skyscrapers, bridges, sidewalks and superhighways, houses and dams.

A concrete block is often used as a building material in the construction of walls. It is sometimes called a concrete masonry unit (CMU). A concrete block is one of several precast concrete products used in construction. Others include segmental retaining walls (SRW), interlocking concrete pavers (ICP), veneer, and a host of other concrete products. The term “precast” refers to concrete products that are formed and hardened before they are brought to the job site. Most concrete blocks have one or more hollow cavities, and their sides may be cast smooth or with a design. In use, concrete blocks are stacked one at a time and may be held together at joints between the units with fresh concrete mortar to form the desired length and height of the wall.

Citations (22)

  • US3758034A
  • US4308069A
  • US4856976A
  • US4802836A
  • US5236501A
  • US5139721A
  • US5358214A
  • US5250113A
  • US5362324A
  • US5432212A
  • US6656262B1
  • US6113379A
  • US6322742B1
  • US6258161B1
  • US20050276155A1
  • US7687005B2
  • US20060185560A1
  • US20100195433A1
  • US20080106009A1
  • US20150101513A1
  • US20150152006A1
  • US20170008810A1
Record as JSON
{
  "publication_number": "US10662121B1",
  "country": "US",
  "kind": "B1",
  "title": "Concrete mixing and concrete products",
  "abstract": "Some implementations herein described improvements to concrete products and processes for producing concrete products that may provide a positive environmental impact and that can be stronger relative to the percent of cement used. Particular examples include improvements to zero-slump to near-zero-slump concrete mixture design, material storage and handling, batching, mixing, sequencing and curing processes, as well as forming and curing techniques.",
  "claims": [
    "1. A method of forming a concrete product from a batch of zero-slump to near-zero-slump concrete mixture including at least a predetermined total amount of aggregates, a predetermined amount of water, and a predetermined amount of cementitious material, the method comprising: (a) mixing an initial portion of the predetermined total amount of aggregates and all of the predetermined amount of water during an initial mixing stage to provide a non-cementitious slurry, the initial portion of the predetermined total amount of aggregates being 50% or less of the predetermined total amount of aggregates; (b) mixing the non-cementitious slurry with the predetermined amount of cementitious material during an intermediate mixing stage to provide a slumped cementitious mixture; (c) mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture during a subsequent mixing stage after the intermediate mixing stage to provide a zero-slump to near-zero-slump concrete mixture, the remaining portion of the predetermined total amount of aggregates being 50% or more of the predetermined amount of aggregates, the remaining portion of the predetermined total amount of aggregates having the same characteristics as the initial portion of the predetermined total amount of aggregates; (d) after the subsequent mixing stage, discharging the zero-slump to near-zero-slump concrete mixture into a mold to form at least one green unit having a predetermined shape, the zero-slump to near-zero-slump concrete mixture having a residence time in the mold of less than 30 seconds; and (e) curing the at least one green unit so as to form a concrete product.",
    "2. The method of claim 1, wherein the initial mixing stage further comprises mixing an admixture with the initial portion of the predetermined amount of aggregates and the predetermined amount of water prior to the intermediate mixing stage.",
    "3. The method of claim 2, wherein during the initial mixing stage, the initial portion of the predetermined total amount of aggregates is about 5% to 30% of the predetermined total amount of aggregates.",
    "4. The method of claim 1, wherein the batch of zero-slump to near-zero-slump concrete mixture has the predetermined amount of water and the predetermined amount of cementitious material that define a water-to-cement ratio by weight which is greater than 0.5:1 and less than 2.0:1.",
    "5. The method of claim 4, wherein the batch of zero-slump to near-zero-slump concrete mixture has the predetermined amount of water and the predetermined amount of cementitious material that define a water-to-cement ratio by weight in the range of 0.85:1 to 1.25:1.",
    "6. The method of claim 1, wherein the batch of zero-slump to near-zero-slump concrete mixture has the predetermined amount of water that is an amount of 100%+ water.",
    "7. The method of claim 1, wherein during the initial mixing stage, the initial portion of the predetermined total amount of aggregates consists of protected aggregates.",
    "8. The method of claim 7, wherein the predetermined total amount of aggregates consists of protected aggregates.",
    "9. The method of claim 1, wherein the at least one green unit formed in the mold retains said predetermined shape during said curing, wherein the at least one green unit hardens during said curing to provide said concrete product that sequesters ambient carbon dioxide for an extended period of days after said curing.",
    "10. The method of claim 9, wherein said concrete product provides ambient carbon dioxide sequestration of at least 5% weight percent of the cement over a 28 day period.",
    "11. The method of claim 1, wherein said curing comprises maintaining the at least one green unit in a curing chamber that provides a suspended fog condition with supplemental carbon dioxide delivery, said supplemental carbon dioxide delivery being redirect from an exhaust of a heat source of the curing chamber.",
    "12. The method of claim 1, wherein mixing is performed by a concrete mixer comprising: (a) a mixing chamber configured to receive staged delivery of aggregates, water, and the cementitious material; (b) at least one mixing blade connected to a shaft extending through the mixing chamber, the at least one mixing blade comprising a plurality of shearing elements extending from a surface of the mixing blade; and (c) a cleaning ring positioned around the shaft in the mixing chamber such that mixing by rotating the at least one mixing blade causes the shearing elements to periodically engage the cleaning ring to cause the clearing ring to twist relative to the shaft.",
    "13. The method of claim 12, wherein the shearing elements form elongated straight lines or elongated curved lines projecting out from the surface of the mixing blade.",
    "14. The method of claim 12, wherein the shearing elements of the mixing chamber provide deagglomerating, counter-ferromagnetic shear mixing during a mixing stage that mixes together aggregates, water, and a cementitious material.",
    "15. The method of claim 1, wherein discharging the zero-slump to near-zero-slump concrete mixture into a mold comprises: compressing, using a molding machine, the zero-slump to near-zero-slump concrete mixture to conform to the predetermined shape in the mold.",
    "16. The method of claim 15, wherein the zero-slump to near-zero-slump concrete mixture is not conformable within the mold by gravity.",
    "17. The method of claim 1, wherein curing the at least one green unit comprises: curing the at least one green unit outside the mold so as to form a precast concrete product.",
    "18. The method of claim 17, further comprising: prior to curing, removing the at least one green unit from the mold, the at least one green unit maintaining the predetermined shape before and during the curing.",
    "19. The method of claim 17, wherein the at least one green unit is cured in a curing chamber configured to provide a predetermined temperature, moisture condition, carbon dioxide atmosphere, and carbon dioxide supplement level.",
    "20. The method of claim 1, wherein mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture, and mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture during a subsequent mixing stage after the intermediate mixing stage to provide a zero-slump to near-zero-slump concrete mixture, are performed without additional water beyond the predetermined amount of water.",
    "21. The method of claim 20, wherein the initial portion of the predetermined total amount of aggregates is dry prior to mixing an initial portion of the predetermined total amount of aggregates and the predetermined amount of water during an initial mixing stage to provide a non-cementitious slurry.",
    "22. The method of claim 2, wherein discharging the zero-slump to near-zero-slump concrete mixture into a mold comprises: compressing, using a molding machine, the zero-slump to near-zero-slump concrete mixture to conform to the predetermined shape in the mold.",
    "23. The method of claim 22, wherein the zero-slump to near-zero-slump concrete mixture is not conformable within the mold by gravity.",
    "24. The method of claim 2, wherein curing the at least one green unit comprises: curing the at least one green unit outside the mold so as to form a precast concrete product.",
    "25. The method of claim 24, further comprising: prior to curing, removing the at least one green unit from the mold, the at least one green unit maintaining the predetermined shape before and during the curing.",
    "26. The method of claim 24, wherein the at least one green unit is cured in a curing chamber configured to provide a predetermined temperature, moisture condition, carbon dioxide atmosphere, and carbon dioxide supplement level.",
    "27. The method of claim 2, wherein mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture, and mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture during a subsequent mixing stage after the intermediate mixing stage to provide a zero-slump to near-zero-slump concrete mixture, are performed without additional water beyond the predetermined amount of water.",
    "28. The method of claim 27, wherein the initial portion of the predetermined total amount of aggregates is dry prior to mixing an initial portion of the predetermined total amount of aggregates and the predetermined amount of water during an initial mixing stage to provide a non-cementitious slurry.",
    "29. A method of forming a concrete product from a batch of zero-slump to near-zero-slump concrete mixture including at least a predetermined total amount of aggregates, a predetermined amount of water, and a predetermined amount of cementitious material, the method comprising: (a) mixing an initial portion of the predetermined total amount of aggregates and all of the predetermined amount of water during an initial mixing stage to provide a non-cementitious slurry, the initial portion of the predetermined total amount of aggregates being 50% or less of the predetermined total amount of aggregates; (b) mixing the non-cementitious slurry with the predetermined amount of cementitious material during an intermediate mixing stage to provide a slumped cementitious mixture; (c) mixing a remaining portion of the predetermined total amount of aggregates and the slumped cementitious mixture during a subsequent mixing stage after the intermediate mixing stage, the remaining portion of the predetermined total amount of aggregates having the same characteristics as the initial portion of the predetermined total amount of aggregates; (d) after the subsequent mixing stage, discharging the zero-slump to near-zero-slump concrete mixture into a mold to form at least one green unit having a predetermined shape, the zero-slump to near-zero-slump concrete mixture having a residence time in the mold of less than 30 seconds; and (e) curing the at least one green unit so as to form a concrete product; wherein said subsequent mixing stage is a third mixing stage, further comprising a fourth mixing stage that comprises one or more additives mixed together with the concrete mixture resulting from the third mixing stage, wherein the fourth mixing stage outputs the zero-slump to near-zero-slump concrete mixture.",
    "30. The method of claim 29, wherein the initial mixing stage comprises mixing the initial portion of the predetermined amount of aggregates, the predetermined amount of water, and at least one admixture in a mixing chamber for about 0.5 minutes to about 13 minutes prior to adding any of predetermined amount of cementitious material, wherein the mixing chamber is equipped with one or more shearing elements.",
    "31. The method of claim 30, wherein the predetermined amount of cementitious material is dispensed into the mixing chamber during the intermediate mixing stage only after the initial mixing stage in which the initial portion of the predetermined amount of aggregates, the predetermined amount of water, and at least one admixture are initially mixed to provide the non-cementitious slurry.",
    "32. The method of claim 31, wherein the intermediate mixing stage comprises mixing the non-cementitious slurry with the predetermined amount of cementitious material in the mixing chamber for about 2 minutes, wherein the shearing elements of the mixing chamber provide deagglomerating, counter-ferromagnetic shear mixing."
  ],
  "description_excerpt": "This document relates to improved methods of concrete mixing and concrete products, including for example, zero-slump to near-zero-slump concrete mix designs and methods that provide improved strength, durability, and/or environmental impact.\n\nIn its simplest form, concrete is a mixture of paste and aggregates, or rocks. The paste, composed of portland cement and water, coats the surface of the fine (small) and coarse (larger) aggregates. Through a chemical reaction called hydration, the paste hardens and gains strength to form the rock-like mass known as concrete. Within this process lies the key to a remarkable trait of concrete: it is malleable when newly mixed, strong and durable when hardened. These qualities explain why concrete can be suitable for building skyscrapers, bridges, sidewalks and superhighways, houses and dams.\n\nA concrete block is often used as a building material in the construction of walls. It is sometimes called a concrete masonry unit (CMU). A concrete block is one of several precast concrete products used in construction. Others include segmental retaining walls (SRW), interlocking concrete pavers (ICP), veneer, and a host of other concrete products. The term “precast” refers to concrete products that are formed and hardened before they are brought to the job site. Most concrete blocks have one or more hollow cavities, and their sides may be cast smooth or with a design. In use, concrete blocks are stacked one at a time and may be held together at joints between the units with fresh concrete mortar to form the desired length and height of the wall.",
  "cpc": [
    "C04B 41/4578",
    "B01D 53/1475",
    "B28B 1/14",
    "B28B 11/245",
    "B28C 5/003",
    "B28C 5/0806",
    "B28C 5/42",
    "B29B 7/00",
    "C04B 2111/00019",
    "C04B 28/00",
    "C04B 28/02",
    "C04B 28/10",
    "C04B 40/0231",
    "Y02C 20/40",
    "Y02P 40/18"
  ],
  "ipc": [
    "B28B 1/14",
    "B28C 5/08",
    "B29B 7/00",
    "C04B 41/45"
  ],
  "assignees": [
    "Concrete Products Group LLC"
  ],
  "inventors": [
    "Canan D'Avela"
  ],
  "filing_date": "2015-12-28",
  "publication_date": "2020-05-26",
  "grant_date": "2020-05-26",
  "priority_date": "2015-12-28",
  "application_number": "US-201514980389-A",
  "family_id": "70775007",
  "cited_by_count": 23,
  "citations": [
    "US3758034A",
    "US4308069A",
    "US4856976A",
    "US4802836A",
    "US5236501A",
    "US5139721A",
    "US5358214A",
    "US5250113A",
    "US5362324A",
    "US5432212A",
    "US6656262B1",
    "US6113379A",
    "US6322742B1",
    "US6258161B1",
    "US20050276155A1",
    "US7687005B2",
    "US20060185560A1",
    "US20100195433A1",
    "US20080106009A1",
    "US20150101513A1",
    "US20150152006A1",
    "US20170008810A1"
  ]
}

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