Patent · US10731262B2 · B2 · US
Corrosion control coating
- (11) Publication number
- US10731262B2
- (21) Application number
- 15/288,222
- (22) Filing date
- 2016-10-07
- (30) Priority date
- 2015-10-09
- (43) Publication date
- 2020-08-04
- (45) Date of grant
- 2020-08-04
- (51) IPC
- C23C 2/06; C23C 2/26; C23F 13/02; C23F 17/00; C25D 3/22; B05D 7/00; C09D 5/10; C09D 7/61; C23C 28/00; C23F 13/06; C23F 13/14
- (52) CPC
- C23F Non-mechanical removal of metallic material from surface; inhibiting corrosion of metallic material or incrustation in general; multi-step processes for surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by subclass C21D or C22F or class C25: 13/02, 13/06, 13/14, 17/00
- B05D Processes for applying fluent materials to surfaces, in general: 1/005, 1/02, 1/18, 2202/10, 7/14, 7/24, 7/52
- C08K Use of inorganic or non-macromolecular organic substances as compounding ingredients: 3/08
- C09D Coating compositions, e.g. paints, varnishes or lacquers; filling pastes; chemical paint or ink removers; inks; correcting fluids; woodstains; pastes or solids for colouring or printing; use of materials therefor: 5/10, 5/106, 7/61
- C23C Coating metallic material; coating material with metallic material; surface treatment of metallic material by diffusion into the surface, by chemical conversion or substitution; coating by vacuum evaporation, by sputtering, by ion implantation or by chemical vapour deposition, in general: 2/06, 2/26, 24/02, 28/00, 28/322, 28/3225, 28/345, 28/3455
- C25D Processes for the electrolytic or electrophoretic production of coatings; electroforming; apparatus therefor: 3/22, 5/48
- (73) Assignee
- Ewald Doerken AG
- (72) Inventors
- Marcel Roth; Kai Owczarek; Heike Mertens; Sandra BÖHM; Vanessa KURZE; Gerhard Reusmann
- (54) Title
- Corrosion control coating
- (57) Abstract
The present invention relates to a corrosion control coating, more particularly a high-temperature corrosion control coating, and to a method for producing it.
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Claims (18)
- A coating, for generating cathodic high-temperature corrosion protection on a metallic substrate, comprising at least two layers, characterized by a) a first layer in the form of a cathodic corrosion control coating, wherein the first layer is a first inorganic matrix comprising metal particles, wherein the metal particles are selected from the group consisting of pure zinc, zinc alloys, and combinations thereof, and wherein the first inorganic matrix further comprises oxides selected from the group consisting of oxides of silicon, of oxides of titanium, oxides of zirconium, and combinations thereof, and b) a second layer in the form of a coating selected from the group consisting of a corrosion control coating, and an oxygen barrier coating, wherein the second layer comprises a second inorganic matrix formed by oxides selected from the group consisting of oxides of silicon, oxides of titanium, oxides of zirconium, and combinations thereof, wherein the second layer further comprises aluminium particles in the range from 35 to 95 wt %, based on the second layer, and wherein the second layer is free from zinc.
- The coating according to claim 1, wherein the coating has a layer thickness in the range from 0.5 to 200 μm.
- The coating according to claim 1, wherein the first layer has a layer thickness in the range from 0.1 to 180 μm.
- The coating according to claim 3, characterized: in that the first layer includes at least 50 wt % of metal particles, based on the first layer.
- The coating according to claim 3, wherein the zinc alloys are selected from the group consisting of zinc-bismuth alloys, zinc-aluminium alloys and zinc-aluminium-magnesium alloys.
- The coating according to claim 5, wherein the zinc alloys selected include zinc-bismuth alloys.
- The coating according to claim 5, wherein the zinc alloys selected include zinc-aluminium alloys.
- The coating according to claim 5, wherein the zinc alloys selected include zinc-aluminium-magnesium alloys.
- The coating according to claim 3, characterized: in that the first layer includes a fraction of metal particles in the range from 50 to 95 wt %.
- The coating according to claim 1, wherein the first inorganic-matrix of the first layer, is organically modified.
- The coating according to claim 1, wherein the second layer has a layer thickness in the range from 0.1 to 50 μm.
- The coating according to claim 11, wherein at least one inorganic-matrix is organically modified.
- The coating according to claim 11, wherein the at least one inorganic-matrix has a carbon content in the range from 0.01 to 50 wt %, based on the at least one inorganic-matrix.
- A coated substrate comprising a corrosion control coating according to claim 13 and optionally an adhesion promoter layer.
- The coating according to claim 11, wherein the at least one inorganic matrix is an inorganic matrix having a carbon content of not more than 50 wt % based on the at least one inorganic matrix.
- The coating according to claim 11, wherein the second layer comprises an inorganic matrix, in amounts of 50 to 100 wt %, based on the second layer.
- The coating according to claim 1, wherein the first layer comprises zinc lamellae as platelet-shaped metal particles, and wherein the zinc lamellae are selected from the group consisting of pure zinc lamellae, zinc alloy lamellae, and combinations thereof.
- A method for producing a cathodic high-temperature corrosion control coating on a metallic substrate, including: (A) in a first method step, a coating selected from the group consisting of a corrosion control coating, a coating composition for producing a cathodic corrosion control layer, and combinations thereof is applied to the metallic substrate, to give a cathodic corrosion control layer, wherein the first layer is formed on the basis of a first inorganic matrix comprising metal particles, wherein the metal particles are formed on the basis of metal particles selected from the group consisting of pure zinc, zinc alloys, and combinations thereof, wherein the first inorganic matrix comprises oxides selected from the group consisting of oxides of silicon, of oxides of titanium, oxides of zirconium, and combinations thereof, and (B) in a subsequent second method step, a corrosion control coating for producing an oxygen barrier layer is applied to the substrate, to give an oxygen barrier layer, wherein the oxygen barrier layer comprises a second inorganic matrix, wherein the second inorganic matrix is formed by oxides selected from the group consisting of oxides of silicon, oxides of titanium, oxides of zirconium, and combinations thereof, wherein the oxygen barrier layer comprises aluminium particles in the range from 35 to 95 wt %, based on the oxygen barrier layer, and wherein the second layer is free from zinc.
Description
The present invention relates to the technical field of corrosion control, more particularly the corrosion control of metallic substrates during and after temperature exposure.
More particularly the present invention relates to a coating, more particularly a high-temperature corrosion control coating, for generating cathodic high-temperature corrosion protection on a metallic substrate.
The present invention further relates to a first coating composition for producing a cathodic corrosion control layer and to a second coating composition for producing an oxygen barrier layer.
Furthermore, the present invention relates to a method for producing a high-temperature corrosion control coating on a metallic substrate.
Moreover, the present invention relates to a coated metallic substrate which comprises a corrosion control coating.
Moreover, the present invention relates to the use of an oxygen barrier layer for improving the temperature stability of a cathodic corrosion control coating.
Lastly the present invention relates to the use of a coating composition for improving the temperature stability of a cathodic corrosion control coating.
Signs of corrosion on metals are observed across all fields of industry, and are of high significance, since the durability or service life of machines, vehicles, industrial plant, or even buildings is dependent, often decisively so, on the corrosion properties of the metals used. Corrosion means that metal parts must be replaced or renovated, operations which always involve time, materials and costs.
Citations (19)
- JPS4818090B1
- US4098749A
- US4487815A
- JP2001049147A
- FR2799211A1
- JP2003531285A
- US6656607B1
- CN1944545A
- US20020119337A1
- US20040137238A1
- US20050129964A1
- US20100136359A1
- US20100183892A1
- WO2010043708A1
- JP2013013855A
- US20130143032A1
- JP2013119572A
- WO2013139599A1
- JP2014152269A
Record as JSON
{
"publication_number": "US10731262B2",
"country": "US",
"kind": "B2",
"title": "Corrosion control coating",
"abstract": "The present invention relates to a corrosion control coating, more particularly a high-temperature corrosion control coating, and to a method for producing it.",
"claims": [
"1. A coating, for generating cathodic high-temperature corrosion protection on a metallic substrate, comprising at least two layers, characterized by a) a first layer in the form of a cathodic corrosion control coating, wherein the first layer is a first inorganic matrix comprising metal particles, wherein the metal particles are selected from the group consisting of pure zinc, zinc alloys, and combinations thereof, and wherein the first inorganic matrix further comprises oxides selected from the group consisting of oxides of silicon, of oxides of titanium, oxides of zirconium, and combinations thereof, and b) a second layer in the form of a coating selected from the group consisting of a corrosion control coating, and an oxygen barrier coating, wherein the second layer comprises a second inorganic matrix formed by oxides selected from the group consisting of oxides of silicon, oxides of titanium, oxides of zirconium, and combinations thereof, wherein the second layer further comprises aluminium particles in the range from 35 to 95 wt %, based on the second layer, and wherein the second layer is free from zinc.",
"2. The coating according to claim 1, wherein the coating has a layer thickness in the range from 0.5 to 200 μm.",
"3. The coating according to claim 1, wherein the first layer has a layer thickness in the range from 0.1 to 180 μm.",
"4. The coating according to claim 3, characterized: in that the first layer includes at least 50 wt % of metal particles, based on the first layer.",
"5. The coating according to claim 3, wherein the zinc alloys are selected from the group consisting of zinc-bismuth alloys, zinc-aluminium alloys and zinc-aluminium-magnesium alloys.",
"6. The coating according to claim 5, wherein the zinc alloys selected include zinc-bismuth alloys.",
"7. The coating according to claim 5, wherein the zinc alloys selected include zinc-aluminium alloys.",
"8. The coating according to claim 5, wherein the zinc alloys selected include zinc-aluminium-magnesium alloys.",
"9. The coating according to claim 3, characterized: in that the first layer includes a fraction of metal particles in the range from 50 to 95 wt %.",
"10. The coating according to claim 1, wherein the first inorganic-matrix of the first layer, is organically modified.",
"11. The coating according to claim 1, wherein the second layer has a layer thickness in the range from 0.1 to 50 μm.",
"12. The coating according to claim 11, wherein at least one inorganic-matrix is organically modified.",
"13. The coating according to claim 11, wherein the at least one inorganic-matrix has a carbon content in the range from 0.01 to 50 wt %, based on the at least one inorganic-matrix.",
"14. A coated substrate comprising a corrosion control coating according to claim 13 and optionally an adhesion promoter layer.",
"15. The coating according to claim 11, wherein the at least one inorganic matrix is an inorganic matrix having a carbon content of not more than 50 wt % based on the at least one inorganic matrix.",
"16. The coating according to claim 11, wherein the second layer comprises an inorganic matrix, in amounts of 50 to 100 wt %, based on the second layer.",
"17. The coating according to claim 1, wherein the first layer comprises zinc lamellae as platelet-shaped metal particles, and wherein the zinc lamellae are selected from the group consisting of pure zinc lamellae, zinc alloy lamellae, and combinations thereof.",
"18. A method for producing a cathodic high-temperature corrosion control coating on a metallic substrate, including: (A) in a first method step, a coating selected from the group consisting of a corrosion control coating, a coating composition for producing a cathodic corrosion control layer, and combinations thereof is applied to the metallic substrate, to give a cathodic corrosion control layer, wherein the first layer is formed on the basis of a first inorganic matrix comprising metal particles, wherein the metal particles are formed on the basis of metal particles selected from the group consisting of pure zinc, zinc alloys, and combinations thereof, wherein the first inorganic matrix comprises oxides selected from the group consisting of oxides of silicon, of oxides of titanium, oxides of zirconium, and combinations thereof, and (B) in a subsequent second method step, a corrosion control coating for producing an oxygen barrier layer is applied to the substrate, to give an oxygen barrier layer, wherein the oxygen barrier layer comprises a second inorganic matrix, wherein the second inorganic matrix is formed by oxides selected from the group consisting of oxides of silicon, oxides of titanium, oxides of zirconium, and combinations thereof, wherein the oxygen barrier layer comprises aluminium particles in the range from 35 to 95 wt %, based on the oxygen barrier layer, and wherein the second layer is free from zinc."
],
"description_excerpt": "The present invention relates to the technical field of corrosion control, more particularly the corrosion control of metallic substrates during and after temperature exposure.\n\nMore particularly the present invention relates to a coating, more particularly a high-temperature corrosion control coating, for generating cathodic high-temperature corrosion protection on a metallic substrate.\n\nThe present invention further relates to a first coating composition for producing a cathodic corrosion control layer and to a second coating composition for producing an oxygen barrier layer.\n\nFurthermore, the present invention relates to a method for producing a high-temperature corrosion control coating on a metallic substrate.\n\nMoreover, the present invention relates to a coated metallic substrate which comprises a corrosion control coating.\n\nMoreover, the present invention relates to the use of an oxygen barrier layer for improving the temperature stability of a cathodic corrosion control coating.\n\nLastly the present invention relates to the use of a coating composition for improving the temperature stability of a cathodic corrosion control coating.\n\nSigns of corrosion on metals are observed across all fields of industry, and are of high significance, since the durability or service life of machines, vehicles, industrial plant, or even buildings is dependent, often decisively so, on the corrosion properties of the metals used. Corrosion means that metal parts must be replaced or renovated, operations which always involve time, materials and costs.",
"cpc": [
"C23F 13/02",
"B05D 1/005",
"B05D 1/02",
"B05D 1/18",
"B05D 2202/10",
"B05D 7/14",
"B05D 7/24",
"B05D 7/52",
"C08K 3/08",
"C09D 5/10",
"C09D 5/106",
"C09D 7/61",
"C23C 2/06",
"C23C 2/26",
"C23C 24/02",
"C23C 28/00",
"C23C 28/322",
"C23C 28/3225",
"C23C 28/345",
"C23C 28/3455",
"C23F 13/06",
"C23F 13/14",
"C23F 17/00",
"C25D 3/22",
"C25D 5/48"
],
"ipc": [
"C23C 2/06",
"C23C 2/26",
"C23F 13/02",
"C23F 17/00",
"C25D 3/22",
"B05D 7/00",
"C09D 5/10",
"C09D 7/61",
"C23C 28/00",
"C23F 13/06",
"C23F 13/14"
],
"assignees": [
"Ewald Doerken AG"
],
"inventors": [
"Marcel Roth",
"Kai Owczarek",
"Heike Mertens",
"Sandra BÖHM",
"Vanessa KURZE",
"Gerhard Reusmann"
],
"filing_date": "2016-10-07",
"publication_date": "2020-08-04",
"grant_date": "2020-08-04",
"priority_date": "2015-10-09",
"application_number": "US-201615288222-A",
"family_id": "54330600",
"cited_by_count": 1,
"citations": [
"JPS4818090B1",
"US4098749A",
"US4487815A",
"JP2001049147A",
"FR2799211A1",
"JP2003531285A",
"US6656607B1",
"CN1944545A",
"US20020119337A1",
"US20040137238A1",
"US20050129964A1",
"US20100136359A1",
"US20100183892A1",
"WO2010043708A1",
"JP2013013855A",
"US20130143032A1",
"JP2013119572A",
"WO2013139599A1",
"JP2014152269A"
]
}
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