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Organobismuthane-mediated radical polymerization

Term · Chemistry · MLC-T-CHM-013366

A reversible-deactivation radical polymerization technique that uses organobismuth compounds as chain transfer agents. These agents reversibly cleave and reform carbon-bismuth bonds, allowing for controlled growth of polymer chains. This method provides good control over molecular weight and polydispersity, typically yielding polymers with polydispersity indices below 1.5.

Table 1. Record
IdentifierMLC-T-CHM-013366
FieldChemistry
SubjectPolymer
ReferencesPAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1112 (https://doi.org/10.1515/pac-2020-1211)
See alsoReversible-deactivation radical polymerization
Record as JSON
{
  "id": "MLC-T-CHM-013366",
  "term": "Organobismuthane-mediated radical polymerization",
  "field": "Chemistry",
  "definition": "A reversible-deactivation radical polymerization technique that uses organobismuth compounds as chain transfer agents. These agents reversibly cleave and reform carbon-bismuth bonds, allowing for controlled growth of polymer chains. This method provides good control over molecular weight and polydispersity, typically yielding polymers with polydispersity indices below 1.5.",
  "subject": "Polymer",
  "see_also": [
    "reversible-deactivation radical polymerization"
  ],
  "references": [
    "PAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1112 (https://doi.org/10.1515/pac-2020-1211)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/organobismuthane-mediated-radical-polymerization/"
}

Record 8,836 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.