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Organostibane-mediated radical polymerization

Term · Chemistry · MLC-T-CHM-008325

A form of reversible-deactivation radical polymerization where an organostibane compound acts as the agent for reversible chain transfer. The process involves the transfer of a radical from the growing polymer chain to the antimony center, creating a dormant species and a new radical. This equilibrium between active and dormant chains provides control over the polymerization, influencing the final polymer's molecular weight and architecture.

Table 1. Record
IdentifierMLC-T-CHM-008325
FieldChemistry
SubjectPolymer
ReferencesPAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1112 (https://doi.org/10.1515/pac-2020-1211)
See alsoReversible-deactivation radical polymerization
Record as JSON
{
  "id": "MLC-T-CHM-008325",
  "term": "Organostibane-mediated radical polymerization",
  "field": "Chemistry",
  "definition": "A form of reversible-deactivation radical polymerization where an organostibane compound acts as the agent for reversible chain transfer. The process involves the transfer of a radical from the growing polymer chain to the antimony center, creating a dormant species and a new radical. This equilibrium between active and dormant chains provides control over the polymerization, influencing the final polymer's molecular weight and architecture.",
  "subject": "Polymer",
  "see_also": [
    "reversible-deactivation radical polymerization"
  ],
  "references": [
    "PAC, 2022, 94, 1093. 'Terminology for chain polymerization (IUPAC Recommendations 2021)' on page 1112 (https://doi.org/10.1515/pac-2020-1211)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/organostibane-mediated-radical-polymerization/"
}

Record 8,847 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.