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Degenerate-transfer radical polymerisation

Term · Chemistry · MLC-T-CHM-002926

A type of reversible-deactivation radical polymerization where the active radical species rapidly and reversibly transfers its radical character to a dormant species, typically through a chain transfer agent. This process maintains a low concentration of active radicals, leading to controlled polymer growth and narrow molecular weight distributions. Iodine-transfer polymerization is a common example.

Table 1. Record
IdentifierMLC-T-CHM-002926
FieldChemistry
SubjectPolymer
ReferencesPAC, 2009, 82, 483. 'Terminology for reversible-deactivation radical polymerization previously called "controlled" radical or "living" radical polymerization (IUPAC Recommendations 2010)' on page 489 (https://doi.org/10.1351/PAC-REC-08-04-03)
Record as JSON
{
  "id": "MLC-T-CHM-002926",
  "term": "Degenerate-transfer radical polymerisation",
  "field": "Chemistry",
  "definition": "A type of reversible-deactivation radical polymerization where the active radical species rapidly and reversibly transfers its radical character to a dormant species, typically through a chain transfer agent. This process maintains a low concentration of active radicals, leading to controlled polymer growth and narrow molecular weight distributions. Iodine-transfer polymerization is a common example.",
  "subject": "Polymer",
  "references": [
    "PAC, 2009, 82, 483. 'Terminology for reversible-deactivation radical polymerization previously called \"controlled\" radical or \"living\" radical polymerization (IUPAC Recommendations 2010)' on page 489 (https://doi.org/10.1351/PAC-REC-08-04-03)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/degenerate-transfer-radical-polymerisation/"
}

Record 3,112 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.