Time-temperature superposition principle
Term · Chemistry · MLC-T-CHM-012074
A principle stating that for certain viscoelastic polymers, the effect of changing the temperature is equivalent to the effect of scaling the timescale. This allows viscoelastic property data measured over a limited frequency or time range at several temperatures to be combined into a single master curve covering a much broader range. The amount of horizontal shifting required to align the data is described by a shift factor, which is often modeled by the Williams-Landel-Ferry equation.
| Identifier | MLC-T-CHM-012074 |
|---|---|
| Field | Chemistry |
| Subject | Polymer |
| Synonyms | TTS Principle |
| References | PAC, 2013, 85, 1017. 'Glossary of terms relating to thermal and thermomechanical properties of polymers (IUPAC Recommendations 2013)' on page 1042 (https://doi.org/10.1351/PAC-REC-12-03-02) |
| See also | Williams-Landel-Ferry equation; Shift factor |
Record as JSON
{
"id": "MLC-T-CHM-012074",
"term": "Time-temperature superposition principle",
"field": "Chemistry",
"definition": "A principle stating that for certain viscoelastic polymers, the effect of changing the temperature is equivalent to the effect of scaling the timescale. This allows viscoelastic property data measured over a limited frequency or time range at several temperatures to be combined into a single master curve covering a much broader range. The amount of horizontal shifting required to align the data is described by a shift factor, which is often modeled by the Williams-Landel-Ferry equation.",
"synonyms": [
"TTS Principle"
],
"subject": "Polymer",
"see_also": [
"Williams-Landel-Ferry equation",
"shift factor"
],
"references": [
"PAC, 2013, 85, 1017. 'Glossary of terms relating to thermal and thermomechanical properties of polymers (IUPAC Recommendations 2013)' on page 1042 (https://doi.org/10.1351/PAC-REC-12-03-02)"
],
"url": "https://mlchart.com/terminology/chemistry/time-temperature-superposition-principle/"
}
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