Horwitz equation
Term · Chemistry · MLC-T-CHM-005397
An empirical equation that describes the relationship between the interlaboratory coefficient of variation (reproducibility relative standard deviation) and the analyte concentration in a sample. It provides an estimate of the expected variability for analytical methods across different laboratories. The equation is often used to assess the fitness for purpose of analytical methods and to set performance criteria.
| Identifier | MLC-T-CHM-005397 |
|---|---|
| Field | Chemistry |
| Subject | Analytical Chemistry |
| Synonyms | Horwitz curve; Horwitz horn curve; Horwitz trumpet curve |
| References | PAC, 2021, 93, 997. 'Metrological and quality concepts in analytical chemistry (IUPAC Recommendations 2021)' on page 1026 (https://doi.org/10.1515/pac-2019-0819) |
Record as JSON
{
"id": "MLC-T-CHM-005397",
"term": "Horwitz equation",
"field": "Chemistry",
"definition": "An empirical equation that describes the relationship between the interlaboratory coefficient of variation (reproducibility relative standard deviation) and the analyte concentration in a sample. It provides an estimate of the expected variability for analytical methods across different laboratories. The equation is often used to assess the fitness for purpose of analytical methods and to set performance criteria.",
"synonyms": [
"Horwitz curve",
"Horwitz horn curve",
"Horwitz trumpet curve"
],
"subject": "Analytical Chemistry",
"references": [
"PAC, 2021, 93, 997. 'Metrological and quality concepts in analytical chemistry (IUPAC Recommendations 2021)' on page 1026 (https://doi.org/10.1515/pac-2019-0819)"
],
"url": "https://mlchart.com/terminology/chemistry/horwitz-equation/"
}
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