Horwitz ratio
Term · Chemistry · MLC-T-CHM-005398
A metric used to compare the observed interlaboratory reproducibility standard deviation of an analytical method with the predicted standard deviation derived from the Horwitz equation. It indicates how well a method's performance aligns with the expected variability for a given analyte concentration. A Horwitz ratio close to unity suggests that the method's reproducibility is within acceptable limits for chemical analysis.
| Identifier | MLC-T-CHM-005398 |
|---|---|
| Field | Chemistry |
| Subject | Analytical Chemistry |
| Synonyms | Horrat |
| References | PAC, 2021, 93, 997. 'Metrological and quality concepts in analytical chemistry (IUPAC Recommendations 2021)' on page 1026 (https://doi.org/10.1515/pac-2019-0819) |
| See also | Horwitz equation; Chemical analysis; Fitness for purpose; Repeatability condition of measurement |
Record as JSON
{
"id": "MLC-T-CHM-005398",
"term": "Horwitz ratio",
"field": "Chemistry",
"definition": "A metric used to compare the observed interlaboratory reproducibility standard deviation of an analytical method with the predicted standard deviation derived from the Horwitz equation. It indicates how well a method's performance aligns with the expected variability for a given analyte concentration. A Horwitz ratio close to unity suggests that the method's reproducibility is within acceptable limits for chemical analysis.",
"synonyms": [
"Horrat"
],
"subject": "Analytical Chemistry",
"see_also": [
"Horwitz equation",
"chemical analysis",
"fitness for purpose",
"repeatability condition of measurement"
],
"references": [
"PAC, 2021, 93, 997. 'Metrological and quality concepts in analytical chemistry (IUPAC Recommendations 2021)' on page 1026 (https://doi.org/10.1515/pac-2019-0819)"
],
"url": "https://mlchart.com/terminology/chemistry/horwitz-ratio/"
}
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