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Lippert-Mataga equation

Term · Chemistry · MLC-T-CHM-006671

A mathematical model that describes the relationship between the Stokes shift of a fluorescent molecule and the polarity of the solvent. This equation relates the difference in energy between the absorption and emission maxima to the dielectric constant and refractive index of the solvent. It is used to estimate the change in dipole moment of a molecule upon excitation.

Table 1. Record
IdentifierMLC-T-CHM-006671
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 365 (https://doi.org/10.1351/pac200779030293)
Record as JSON
{
  "id": "MLC-T-CHM-006671",
  "term": "Lippert-Mataga equation",
  "field": "Chemistry",
  "definition": "A mathematical model that describes the relationship between the Stokes shift of a fluorescent molecule and the polarity of the solvent. This equation relates the difference in energy between the absorption and emission maxima to the dielectric constant and refractive index of the solvent. It is used to estimate the change in dipole moment of a molecule upon excitation.",
  "subject": "Organic and Biomolecular Chemistry",
  "references": [
    "PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 365 (https://doi.org/10.1351/pac200779030293)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/lippert-mataga-equation/"
}

Record 7,068 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.