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Solvatochromism

Term · Chemistry · MLC-T-CHM-011019

The phenomenon where the color or spectral properties (e.g., absorption or emission maxima) of a chemical compound change significantly with a change in the solvent. This effect arises from differential stabilization of the ground and excited electronic states by solvent-solute interactions. It is commonly observed in highly polar or charge-transfer compounds and is used to probe solvent polarity.

Table 1. Record
IdentifierMLC-T-CHM-011019
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1164 (https://doi.org/10.1351/pac199466051077); PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2274 (https://doi.org/10.1351/pac199668122223)
See alsoZ-value; Dimroth-Reichardt ET parameter; Bathochromic shift; Hypsochromic shift; Polarity
Record as JSON
{
  "id": "MLC-T-CHM-011019",
  "term": "Solvatochromism",
  "field": "Chemistry",
  "definition": "The phenomenon where the color or spectral properties (e.g., absorption or emission maxima) of a chemical compound change significantly with a change in the solvent. This effect arises from differential stabilization of the ground and excited electronic states by solvent-solute interactions. It is commonly observed in highly polar or charge-transfer compounds and is used to probe solvent polarity.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "Z-value",
    "Dimroth-Reichardt ET parameter",
    "bathochromic shift",
    "hypsochromic shift",
    "polarity"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1164 (https://doi.org/10.1351/pac199466051077)",
    "PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2274 (https://doi.org/10.1351/pac199668122223)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/solvatochromism/"
}

Record 11,733 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.