Solvent shift
Term · Chemistry · MLC-T-CHM-011030
A change in the position of an absorption or emission band in a spectrum, typically observed in ultraviolet-visible or infrared spectroscopy, when the solvent is changed. This shift results from differential stabilization of the ground and excited states by solvent-solute interactions. A shift to longer wavelengths is called a bathochromic shift, while a shift to shorter wavelengths is a hypsochromic shift.
| Identifier | MLC-T-CHM-011030 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2274 (https://doi.org/10.1351/pac199668122223) |
| See also | Bathochromic shift; Hypsochromic shift |
Record as JSON
{
"id": "MLC-T-CHM-011030",
"term": "Solvent shift",
"field": "Chemistry",
"definition": "A change in the position of an absorption or emission band in a spectrum, typically observed in ultraviolet-visible or infrared spectroscopy, when the solvent is changed. This shift results from differential stabilization of the ground and excited states by solvent-solute interactions. A shift to longer wavelengths is called a bathochromic shift, while a shift to shorter wavelengths is a hypsochromic shift.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"bathochromic shift",
"hypsochromic shift"
],
"references": [
"PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2274 (https://doi.org/10.1351/pac199668122223)"
],
"url": "https://mlchart.com/terminology/chemistry/solvent-shift/"
}
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