Solvatochromic relationship
Term · Chemistry · MLC-T-CHM-011018
A quantitative correlation between a spectroscopic property, such as the absorption or emission maximum of a compound, and a parameter describing the solvent's polarity or other solvent properties. These relationships are often expressed as linear free-energy relationships, allowing for the prediction of spectral shifts in different solvents. Examples include the Kamlet-Taft and Dimroth-Reichardt ET parameters.
| Identifier | MLC-T-CHM-011018 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1164 (https://doi.org/10.1351/pac199466051077) |
| See also | Kamlet-Taft solvent parameters; Linear free-energy relation; Solvatochromism |
Record as JSON
{
"id": "MLC-T-CHM-011018",
"term": "Solvatochromic relationship",
"field": "Chemistry",
"definition": "A quantitative correlation between a spectroscopic property, such as the absorption or emission maximum of a compound, and a parameter describing the solvent's polarity or other solvent properties. These relationships are often expressed as linear free-energy relationships, allowing for the prediction of spectral shifts in different solvents. Examples include the Kamlet-Taft and Dimroth-Reichardt ET parameters.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"Kamlet-Taft solvent parameters",
"linear free-energy relation",
"solvatochromism"
],
"references": [
"PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1164 (https://doi.org/10.1351/pac199466051077)"
],
"url": "https://mlchart.com/terminology/chemistry/solvatochromic-relationship/"
}
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