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Alternant

Term · Chemistry · MLC-T-CHM-000452

Describing a conjugated hydrocarbon in which the carbon atoms can be conceptually divided into two sets, such that atoms of one set are bonded only to atoms of the other. This structural classification means the molecule contains no odd-membered rings. In the Hückel molecular orbital approximation, alternant hydrocarbons have paired bonding and antibonding orbitals symmetrically distributed about the non-bonding energy level.

Table 1. Record
IdentifierMLC-T-CHM-000452
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1082 (https://doi.org/10.1351/pac199466051077)
See alsoConjugated system
Record as JSON
{
  "id": "MLC-T-CHM-000452",
  "term": "Alternant",
  "field": "Chemistry",
  "definition": "Describing a conjugated hydrocarbon in which the carbon atoms can be conceptually divided into two sets, such that atoms of one set are bonded only to atoms of the other. This structural classification means the molecule contains no odd-membered rings. In the Hückel molecular orbital approximation, alternant hydrocarbons have paired bonding and antibonding orbitals symmetrically distributed about the non-bonding energy level.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "conjugated system"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1082 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/alternant/"
}

Record 478 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.