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Antibonding molecular orbital

Term · Chemistry · MLC-T-CHM-000667

A molecular orbital formed by the out-of-phase combination of atomic orbitals, resulting in a region of zero electron density (a node) between the nuclei. Electrons occupying an antibonding orbital weaken the chemical bond between atoms. These orbitals are higher in energy than the atomic orbitals from which they are formed.

Table 1. Record
IdentifierMLC-T-CHM-000667
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1923 (https://doi.org/10.1351/pac199971101919)
See alsoMolecular orbital; Valence
Record as JSON
{
  "id": "MLC-T-CHM-000667",
  "term": "Antibonding molecular orbital",
  "field": "Chemistry",
  "definition": "A molecular orbital formed by the out-of-phase combination of atomic orbitals, resulting in a region of zero electron density (a node) between the nuclei. Electrons occupying an antibonding orbital weaken the chemical bond between atoms. These orbitals are higher in energy than the atomic orbitals from which they are formed.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "molecular orbital",
    "valence"
  ],
  "references": [
    "PAC, 1999, 71, 1919. 'Glossary of terms used in theoretical organic chemistry' on page 1923 (https://doi.org/10.1351/pac199971101919)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/antibonding-molecular-orbital/"
}

Record 710 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.