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Electron-deficient bond

Term · Chemistry · MLC-T-CHM-003745

A chemical bond in which there are fewer electrons than required to form conventional two-electron, two-center bonds between all directly bonded atoms. These bonds are often found in compounds of boron and other main group elements. A classic example is the three-center, two-electron bond in diborane.

Table 1. Record
IdentifierMLC-T-CHM-003745
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1110 (https://doi.org/10.1351/pac199466051077)
Record as JSON
{
  "id": "MLC-T-CHM-003745",
  "term": "Electron-deficient bond",
  "field": "Chemistry",
  "definition": "A chemical bond in which there are fewer electrons than required to form conventional two-electron, two-center bonds between all directly bonded atoms. These bonds are often found in compounds of boron and other main group elements. A classic example is the three-center, two-electron bond in diborane.",
  "subject": "Organic and Biomolecular Chemistry",
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1110 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/electron-deficient-bond/"
}

Record 3,974 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.