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Hard base

Term · Chemistry · MLC-T-CHM-013143

A Lewis base characterized by a donor atom of high electronegativity, low polarizability, and high resistance to oxidation. These bases hold their valence electrons tightly and have highest occupied molecular orbitals of low energy. Common examples of hard bases include H2O, OH−, F−, and NH3, which form strong interactions with hard acids.

Table 1. Record
IdentifierMLC-T-CHM-013143
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1120 (https://doi.org/10.1351/pac199466051077)
See alsoLewis base; Hard acid; Polarizability
Record as JSON
{
  "id": "MLC-T-CHM-013143",
  "term": "Hard base",
  "field": "Chemistry",
  "definition": "A Lewis base characterized by a donor atom of high electronegativity, low polarizability, and high resistance to oxidation. These bases hold their valence electrons tightly and have highest occupied molecular orbitals of low energy. Common examples of hard bases include H2O, OH−, F−, and NH3, which form strong interactions with hard acids.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "Lewis base",
    "hard acid",
    "polarizability"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1120 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/hard-base/"
}

Record 5,405 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.