MLchartDataset catalogue

Intersection space

Term · Chemistry · MLC-T-CHM-005984

The region in the nuclear coordinate space where two or more potential energy surfaces of different electronic states meet or come very close. This area is where non-adiabatic transitions between electronic states are most probable. The geometry of this space dictates the efficiency and pathways of photochemical reactions.

Table 1. Record
IdentifierMLC-T-CHM-005984
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 356 (https://doi.org/10.1351/pac200779030293)
See alsoConical intersection
Record as JSON
{
  "id": "MLC-T-CHM-005984",
  "term": "Intersection space",
  "field": "Chemistry",
  "definition": "The region in the nuclear coordinate space where two or more potential energy surfaces of different electronic states meet or come very close. This area is where non-adiabatic transitions between electronic states are most probable. The geometry of this space dictates the efficiency and pathways of photochemical reactions.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "conical intersection"
  ],
  "references": [
    "PAC, 2007, 79, 293. 'Glossary of terms used in photochemistry, 3rd edition (IUPAC Recommendations 2006)' on page 356 (https://doi.org/10.1351/pac200779030293)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/intersection-space/"
}

Record 6,352 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.