MLchartDataset catalogue

Irregular adjacent re-entry model

Term · Chemistry · MLC-T-CHM-006154

A model of chain folding in a lamellar polymer crystal in which each chain re-enters the crystal at an adjacent stem position, but the length of the stems, and so the fold period, is allowed to vary from fold to fold. The lamellar surface is therefore rougher than in the regular model, which fixes one fold period. Both differ from the switchboard model, where the stems are joined randomly.

Table 1. Record
IdentifierMLC-T-CHM-006154
FieldChemistry
SubjectPolymer
ReferencesPAC, 2011, 83, 1831. 'Definitions of terms relating to crystalline polymers (IUPAC Recommendations 2011)' on page 1851 (https://doi.org/10.1351/PAC-REC-10-11-13)
See alsoFold period
Record as JSON
{
  "id": "MLC-T-CHM-006154",
  "term": "Irregular adjacent re-entry model",
  "field": "Chemistry",
  "definition": "A model of chain folding in a lamellar polymer crystal in which each chain re-enters the crystal at an adjacent stem position, but the length of the stems, and so the fold period, is allowed to vary from fold to fold. The lamellar surface is therefore rougher than in the regular model, which fixes one fold period. Both differ from the switchboard model, where the stems are joined randomly.",
  "subject": "Polymer",
  "see_also": [
    "fold period"
  ],
  "references": [
    "PAC, 2011, 83, 1831. 'Definitions of terms relating to crystalline polymers (IUPAC Recommendations 2011)' on page 1851 (https://doi.org/10.1351/PAC-REC-10-11-13)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/irregular-adjacent-re-entry-model/"
}

Record 6,530 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.