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Observation pathlength

Term · Chemistry · MLC-T-CHM-008172

The length of the path that a beam of radiation travels through the absorbing or emitting medium, specifically the flame, in atomic spectrometry. According to the Beer-Lambert law, absorbance is directly proportional to this pathlength, so a longer pathlength results in a higher signal and greater sensitivity. For slot burners used in flame atomic absorption, this corresponds to the length of the burner slot and is measured in centimeters.

Table 1. Record
IdentifierMLC-T-CHM-008172
FieldChemistry
SubjectChemistry and Human Health
ReferencesPAC, 1986, 58, 1737. 'Quantities and units in clinical chemistry: Nebulizer and flame properties in flame emission and absorption spectrometry (Recommendations 1986)' on page 1741 (https://doi.org/10.1351/pac198658121737)
Record as JSON
{
  "id": "MLC-T-CHM-008172",
  "term": "Observation pathlength",
  "field": "Chemistry",
  "definition": "The length of the path that a beam of radiation travels through the absorbing or emitting medium, specifically the flame, in atomic spectrometry. According to the Beer-Lambert law, absorbance is directly proportional to this pathlength, so a longer pathlength results in a higher signal and greater sensitivity. For slot burners used in flame atomic absorption, this corresponds to the length of the burner slot and is measured in centimeters.",
  "subject": "Chemistry and Human Health",
  "references": [
    "PAC, 1986, 58, 1737. 'Quantities and units in clinical chemistry: Nebulizer and flame properties in flame emission and absorption spectrometry (Recommendations 1986)' on page 1741 (https://doi.org/10.1351/pac198658121737)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/observation-pathlength/"
}

Record 8,685 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.