Paracrystalline disorder of the first kind
Term · Chemistry · MLC-T-CHM-008436
Structural disorder of a paracrystal in which atoms are displaced from their average lattice positions by uncorrelated fluctuations, mostly thermal, so each displacement is independent of the others and of distance. Long-range order of the average lattice is kept, so Bragg reflections stay sharp but lose intensity at higher scattering angles, as in the Debye-Waller effect. It contrasts with disorder of the second kind, where displacements accumulate and the reflections broaden.
| Identifier | MLC-T-CHM-008436 |
|---|---|
| Field | Chemistry |
| Subject | Polymer |
| Synonyms | uncorrelated paracrystalline disorder |
| References | PAC, 2011, 83, 1831. 'Definitions of terms relating to crystalline polymers (IUPAC Recommendations 2011)' on page 1848 (https://doi.org/10.1351/PAC-REC-10-11-13) |
| See also | Paracrystal |
Record as JSON
{
"id": "MLC-T-CHM-008436",
"term": "Paracrystalline disorder of the first kind",
"field": "Chemistry",
"definition": "Structural disorder of a paracrystal in which atoms are displaced from their average lattice positions by uncorrelated fluctuations, mostly thermal, so each displacement is independent of the others and of distance. Long-range order of the average lattice is kept, so Bragg reflections stay sharp but lose intensity at higher scattering angles, as in the Debye-Waller effect. It contrasts with disorder of the second kind, where displacements accumulate and the reflections broaden.",
"synonyms": [
"uncorrelated paracrystalline disorder"
],
"subject": "Polymer",
"see_also": [
"paracrystal"
],
"references": [
"PAC, 2011, 83, 1831. 'Definitions of terms relating to crystalline polymers (IUPAC Recommendations 2011)' on page 1848 (https://doi.org/10.1351/PAC-REC-10-11-13)"
],
"url": "https://mlchart.com/terminology/chemistry/paracrystalline-disorder-of-the-first-kind/"
}
Record 8,961 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.