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Quinone diazides

Term · Chemistry · MLC-T-CHM-009786

A class of compounds also known as diazooxides, which are formally derived from quinones by the replacement of one or both of the ring carbonyl oxygen atoms with a diazonio group. These molecules exist as zwitterionic resonance hybrids between a quinonoid structure and a benzenoid structure bearing a diazonio group. Upon photolysis or thermolysis, they extrude dinitrogen gas to form highly reactive ketocarbenes, a property used in photoresist technology.

Table 1. Record
IdentifierMLC-T-CHM-009786
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1362 (https://doi.org/10.1351/pac199567081307)
See alsoDiazooxides
Record as JSON
{
  "id": "MLC-T-CHM-009786",
  "term": "Quinone diazides",
  "field": "Chemistry",
  "definition": "A class of compounds also known as diazooxides, which are formally derived from quinones by the replacement of one or both of the ring carbonyl oxygen atoms with a diazonio group. These molecules exist as zwitterionic resonance hybrids between a quinonoid structure and a benzenoid structure bearing a diazonio group. Upon photolysis or thermolysis, they extrude dinitrogen gas to form highly reactive ketocarbenes, a property used in photoresist technology.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "diazooxides"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1362 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/quinone-diazides/"
}

Record 10,400 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.