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Semiquinones

Term · Chemistry · MLC-T-CHM-010735

Radical anions formed by the one-electron reduction of a quinone or, alternatively, by the one-electron oxidation of a hydroquinone. These species contain an unpaired electron and are intermediates in many biological electron-transfer processes, including photosynthesis and cellular respiration. They are characteristically more stable than many other organic radicals due to resonance delocalization of the unpaired electron and negative charge.

Table 1. Record
IdentifierMLC-T-CHM-010735
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1365 (https://doi.org/10.1351/pac199567081307)
See alsoQuinones
Record as JSON
{
  "id": "MLC-T-CHM-010735",
  "term": "Semiquinones",
  "field": "Chemistry",
  "definition": "Radical anions formed by the one-electron reduction of a quinone or, alternatively, by the one-electron oxidation of a hydroquinone. These species contain an unpaired electron and are intermediates in many biological electron-transfer processes, including photosynthesis and cellular respiration. They are characteristically more stable than many other organic radicals due to resonance delocalization of the unpaired electron and negative charge.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "quinones"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1365 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/semiquinones/"
}

Record 11,427 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.