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Phosphoranyl radicals

Term · Chemistry · MLC-T-CHM-008785

Radical species in which the unpaired electron is formally localized on a phosphorus atom, which is bonded to four other atoms. These radicals are typically formed as intermediates in reactions involving phosphorus compounds. Their stability and reactivity depend on the nature of the substituents around the phosphorus center.

Table 1. Record
IdentifierMLC-T-CHM-008785
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1359 (https://doi.org/10.1351/pac199567081307)
See alsoValence
Record as JSON
{
  "id": "MLC-T-CHM-008785",
  "term": "Phosphoranyl radicals",
  "field": "Chemistry",
  "definition": "Radical species in which the unpaired electron is formally localized on a phosphorus atom, which is bonded to four other atoms. These radicals are typically formed as intermediates in reactions involving phosphorus compounds. Their stability and reactivity depend on the nature of the substituents around the phosphorus center.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "valence"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1359 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/phosphoranyl-radicals/"
}

Record 9,329 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.