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Silyl radicals

Term · Chemistry · MLC-T-CHM-013558

Molecular entities containing an unpaired electron localized primarily on a silicon atom. These highly reactive species are analogous to carbon-centered radicals but exhibit distinct reactivity due to the larger size and different electronegativity of silicon. Silyl radicals are often involved in radical chain reactions and polymerization processes.

Table 1. Record
IdentifierMLC-T-CHM-013558
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1366 (https://doi.org/10.1351/pac199567081307)
See alsoRadical
Record as JSON
{
  "id": "MLC-T-CHM-013558",
  "term": "Silyl radicals",
  "field": "Chemistry",
  "definition": "Molecular entities containing an unpaired electron localized primarily on a silicon atom. These highly reactive species are analogous to carbon-centered radicals but exhibit distinct reactivity due to the larger size and different electronegativity of silicon. Silyl radicals are often involved in radical chain reactions and polymerization processes.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "radical"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1366 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/silyl-radicals/"
}

Record 11,574 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.