Radical
Term · Chemistry · MLC-T-CHM-013472
A molecular entity, such as an atom or molecule, that possesses one or more unpaired valence electrons. This unpaired electron makes the species paramagnetic and generally highly reactive, causing it to act as a transient intermediate in many chemical reactions. The presence of the unpaired electron is indicated in chemical formulas by a superscript dot, as in •CH3 for the methyl radical or Cl• for a chlorine atom.
| Identifier | MLC-T-CHM-013472 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| Synonyms | free radical |
| References | PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1155 (https://doi.org/10.1351/pac199466051077); PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1362 (https://doi.org/10.1351/pac199567081307) |
| See also | Paramagnetic; Biradical; Chemical species; Group; Isolobal; Molecular entity; Spin density; Substituent atom |
Record as JSON
{
"id": "MLC-T-CHM-013472",
"term": "Radical",
"field": "Chemistry",
"definition": "A molecular entity, such as an atom or molecule, that possesses one or more unpaired valence electrons. This unpaired electron makes the species paramagnetic and generally highly reactive, causing it to act as a transient intermediate in many chemical reactions. The presence of the unpaired electron is indicated in chemical formulas by a superscript dot, as in •CH3 for the methyl radical or Cl• for a chlorine atom.",
"synonyms": [
"free radical"
],
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"paramagnetic",
"biradical",
"chemical species",
"group",
"isolobal",
"molecular entity",
"spin density",
"substituent atom"
],
"references": [
"PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1155 (https://doi.org/10.1351/pac199466051077)",
"PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1362 (https://doi.org/10.1351/pac199567081307)"
],
"url": "https://mlchart.com/terminology/chemistry/radical/"
}
Record 10,470 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.