Quinomethanes
Term · Chemistry · MLC-T-CHM-009785
Compounds formally derived from quinones by replacing one or both carbonyl oxygens with methylidene groups, giving either a methylidenecyclohexadienone (a quinone methide) or a dimethylidenecyclohexadiene (a quinodimethane). Both are non-aromatic six-membered rings with two ring double bonds and exocyclic double bonds at the 1,2 or 1,4 positions, and they are generally reactive intermediates that regain aromaticity by adding a nucleophile or by dimerizing. The para-quinodimethane p-xylylene polymerizes into the parylene coatings.
| Identifier | MLC-T-CHM-009785 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1362 (https://doi.org/10.1351/pac199567081307) |
| See also | Quinones; Triplet state |
Record as JSON
{
"id": "MLC-T-CHM-009785",
"term": "Quinomethanes",
"field": "Chemistry",
"definition": "Compounds formally derived from quinones by replacing one or both carbonyl oxygens with methylidene groups, giving either a methylidenecyclohexadienone (a quinone methide) or a dimethylidenecyclohexadiene (a quinodimethane). Both are non-aromatic six-membered rings with two ring double bonds and exocyclic double bonds at the 1,2 or 1,4 positions, and they are generally reactive intermediates that regain aromaticity by adding a nucleophile or by dimerizing. The para-quinodimethane p-xylylene polymerizes into the parylene coatings.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"quinones",
"triplet state"
],
"references": [
"PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1362 (https://doi.org/10.1351/pac199567081307)"
],
"url": "https://mlchart.com/terminology/chemistry/quinomethanes/"
}
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