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Sandwich compounds

Term · Chemistry · MLC-T-CHM-010510

Organometallic compounds where a metal atom is 'sandwiched' between two planar organic ligands, typically aromatic rings. The metal forms coordinate bonds with the pi-electron systems of both ligands. Ferrocene, with an iron atom between two cyclopentadienyl rings, is a classic example of this structural motif.

Table 1. Record
IdentifierMLC-T-CHM-010510
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1364 (https://doi.org/10.1351/pac199567081307)
See alsoMetallocenes
Record as JSON
{
  "id": "MLC-T-CHM-010510",
  "term": "Sandwich compounds",
  "field": "Chemistry",
  "definition": "Organometallic compounds where a metal atom is 'sandwiched' between two planar organic ligands, typically aromatic rings. The metal forms coordinate bonds with the pi-electron systems of both ligands. Ferrocene, with an iron atom between two cyclopentadienyl rings, is a classic example of this structural motif.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "metallocenes"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1364 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/sandwich-compounds/"
}

Record 11,181 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.