MLchartDataset catalogue

Metallocenes

Term · Chemistry · MLC-T-CHM-007255

Organometallic compounds characterized by a transition metal atom sandwiched between two parallel cyclopentadienyl ligands. The ligands are bound to the metal through pi-bonds involving all five carbon atoms of each ring. Ferrocene, with the formula Fe(C5H5)2, is the archetypal metallocene and exhibits an 18-electron configuration, contributing to its high stability.

Table 1. Record
IdentifierMLC-T-CHM-007255
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1349 (https://doi.org/10.1351/pac199567081307)
See alsoCoordination; Ligands
Record as JSON
{
  "id": "MLC-T-CHM-007255",
  "term": "Metallocenes",
  "field": "Chemistry",
  "definition": "Organometallic compounds characterized by a transition metal atom sandwiched between two parallel cyclopentadienyl ligands. The ligands are bound to the metal through pi-bonds involving all five carbon atoms of each ring. Ferrocene, with the formula Fe(C5H5)2, is the archetypal metallocene and exhibits an 18-electron configuration, contributing to its high stability.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "coordination",
    "ligands"
  ],
  "references": [
    "PAC, 1995, 67, 1307. 'Glossary of class names of organic compounds and reactivity intermediates based on structure (IUPAC Recommendations 1995)' on page 1349 (https://doi.org/10.1351/pac199567081307)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/metallocenes/"
}

Record 7,687 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.