MLchartDataset catalogue

Semi-dilute solution

Term · Chemistry · MLC-T-CHM-013542

A polymer solution with a concentration above the overlap concentration, where the coils of neighbouring chains begin to interpenetrate, but still well below the concentrated, melt-like state. The chains are screened into blobs, and properties such as osmotic pressure and correlation length follow scaling laws in concentration. Within this regime, entanglement effects appear only above a higher crossover concentration.

Table 1. Record
IdentifierMLC-T-CHM-013542
FieldChemistry
SubjectPolymer
ReferencesPAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 89 (https://doi.org/10.1515/pac-2013-0201)
Record as JSON
{
  "id": "MLC-T-CHM-013542",
  "term": "Semi-dilute solution",
  "field": "Chemistry",
  "definition": "A polymer solution with a concentration above the overlap concentration, where the coils of neighbouring chains begin to interpenetrate, but still well below the concentrated, melt-like state. The chains are screened into blobs, and properties such as osmotic pressure and correlation length follow scaling laws in concentration. Within this regime, entanglement effects appear only above a higher crossover concentration.",
  "subject": "Polymer",
  "references": [
    "PAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 89 (https://doi.org/10.1515/pac-2013-0201)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/semi-dilute-solution/"
}

Record 11,418 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.