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Concentrated solution

Term · Chemistry · MLC-T-CHM-002357

A polymer solution at a concentration where the domains occupied by individual macromolecules overlap so completely that they can no longer be told apart. Chain entanglement then governs viscosity and viscoelasticity, and the upper limit is the bulk amorphous polymer. For a high-molar-mass polymer the overlap concentration is low, often only a few percent by mass.

Table 1. Record
IdentifierMLC-T-CHM-002357
FieldChemistry
SubjectPolymer
ReferencesPAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 90 (https://doi.org/10.1515/pac-2013-0201)
Record as JSON
{
  "id": "MLC-T-CHM-002357",
  "term": "Concentrated solution",
  "field": "Chemistry",
  "definition": "A polymer solution at a concentration where the domains occupied by individual macromolecules overlap so completely that they can no longer be told apart. Chain entanglement then governs viscosity and viscoelasticity, and the upper limit is the bulk amorphous polymer. For a high-molar-mass polymer the overlap concentration is low, often only a few percent by mass.",
  "subject": "Polymer",
  "references": [
    "PAC, 2015, 87, 71. 'Definitions of terms relating to individual macromolecules, macromolecular assemblies, polymer solutions, and amorphous bulk polymers (IUPAC Recommendations 2014)' on page 90 (https://doi.org/10.1515/pac-2013-0201)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/concentrated-solution/"
}

Record 2,512 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.