Spectral overlap
Term · Chemistry · MLC-T-CHM-011131
The extent to which the emission spectrum of a light-emitting chemical entity (the donor) overlaps with the absorption spectrum of another chemical entity (the acceptor). This overlap is a necessary condition for resonance energy transfer between the donor and acceptor pair. The degree of overlap is quantified by the spectral overlap integral, J(λ), which is a key parameter in the calculation of Förster resonance energy transfer (FRET) efficiency.
| Identifier | MLC-T-CHM-011131 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| References | PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2275 (https://doi.org/10.1351/pac199668122223) |
| See also | Dexter excitation transfer; Förster excitation transfer; Absorption spectrum; Emission spectrum; Energy transfer; Ground state; Molar absorption coefficient; Oscillator strength; Photon exitance; Radiative energy transfer; Order of reaction |
Record as JSON
{
"id": "MLC-T-CHM-011131",
"term": "Spectral overlap",
"field": "Chemistry",
"definition": "The extent to which the emission spectrum of a light-emitting chemical entity (the donor) overlaps with the absorption spectrum of another chemical entity (the acceptor). This overlap is a necessary condition for resonance energy transfer between the donor and acceptor pair. The degree of overlap is quantified by the spectral overlap integral, J(λ), which is a key parameter in the calculation of Förster resonance energy transfer (FRET) efficiency.",
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"Dexter excitation transfer",
"Förster excitation transfer",
"absorption spectrum",
"emission spectrum",
"energy transfer",
"ground state",
"molar absorption coefficient",
"oscillator strength",
"photon exitance",
"radiative energy transfer",
"order of reaction"
],
"references": [
"PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2275 (https://doi.org/10.1351/pac199668122223)"
],
"url": "https://mlchart.com/terminology/chemistry/spectral-overlap/"
}
Record 11,863 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.