Dexter excitation transfer
Term · Chemistry · MLC-T-CHM-003114
A mechanism of electronic excitation energy transfer between a donor and an acceptor molecule that requires direct orbital overlap between the two species. This short-range process involves a simultaneous exchange of electrons between the donor and acceptor. The rate of Dexter transfer decreases exponentially with increasing donor-acceptor distance, typically effective within 10 Å.
| Identifier | MLC-T-CHM-003114 |
|---|---|
| Field | Chemistry |
| Subject | Organic and Biomolecular Chemistry |
| Synonyms | electron exchange excitation transfer |
| References | PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2235 (https://doi.org/10.1351/pac199668122223) |
| See also | Excitation transfer; Radiative energy transfer; Order of reaction; Spectral overlap; Triplet-triplet energy transfer |
Record as JSON
{
"id": "MLC-T-CHM-003114",
"term": "Dexter excitation transfer",
"field": "Chemistry",
"definition": "A mechanism of electronic excitation energy transfer between a donor and an acceptor molecule that requires direct orbital overlap between the two species. This short-range process involves a simultaneous exchange of electrons between the donor and acceptor. The rate of Dexter transfer decreases exponentially with increasing donor-acceptor distance, typically effective within 10 Å.",
"synonyms": [
"electron exchange excitation transfer"
],
"subject": "Organic and Biomolecular Chemistry",
"see_also": [
"excitation transfer",
"radiative energy transfer",
"order of reaction",
"spectral overlap",
"triplet-triplet energy transfer"
],
"references": [
"PAC, 1996, 68, 2223. 'Glossary of terms used in photochemistry (IUPAC Recommendations 1996)' on page 2235 (https://doi.org/10.1351/pac199668122223)"
],
"url": "https://mlchart.com/terminology/chemistry/dexter-excitation-transfer/"
}
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