MLchartDataset catalogue

Transition coordinate

Term · Chemistry · MLC-T-CHM-012231

A specific vibrational mode or combination of modes that describes the motion of atoms along the reaction pathway from reactants to the transition state. It represents the direction of steepest descent from the transition state on the potential energy surface towards both reactants and products. The transition coordinate has an imaginary frequency at the transition state.

Table 1. Record
IdentifierMLC-T-CHM-012231
FieldChemistry
SubjectOrganic and Biomolecular Chemistry
ReferencesPAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1174 (https://doi.org/10.1351/pac199466051077)
See alsoReaction coordinate; Transition state
Record as JSON
{
  "id": "MLC-T-CHM-012231",
  "term": "Transition coordinate",
  "field": "Chemistry",
  "definition": "A specific vibrational mode or combination of modes that describes the motion of atoms along the reaction pathway from reactants to the transition state. It represents the direction of steepest descent from the transition state on the potential energy surface towards both reactants and products. The transition coordinate has an imaginary frequency at the transition state.",
  "subject": "Organic and Biomolecular Chemistry",
  "see_also": [
    "reaction coordinate",
    "transition state"
  ],
  "references": [
    "PAC, 1994, 66, 1077. 'Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)' on page 1174 (https://doi.org/10.1351/pac199466051077)"
  ],
  "url": "https://mlchart.com/terminology/chemistry/transition-coordinate/"
}

Record 13,040 of 13,676 in Chemistry terminology (MLC-0109). Request the full dataset.